INAAP P&E area flume site 54 phase II RCRA facility investigation report Oct 2002

Description:	The revised final report for the propellant and explosives (P&E) area flume site 54 at Indiana Army Ammunition Plant of Phase II RCRA facility investigation prepared for U.S. Army Corps of Engineers in October 2002.The United States federal government began acquiring land in Charlestown, Indiana in 1940 to build a smokeless powder ordnance plant to supply the US military during World War II. Indiana Ordnance Works (IOW) Plant 1 and Hoosier Ordnance Plant (HOP) began production in 1941. In 1944, IOW Plant 2 construction began. On 30 Nov 1945 at the end of WWII, the three plants were combined and renamed Indiana Arsenal. Between 1 Nov 1961 and 1 Aug 1963, the plant was designated Indiana Ordnance Plant. After this time, it became Indiana Army Ammunition Plant (INAAP). Production of ordnance continued at the plant until 1992. After that time, the land and facilities were leased to private industry. A large portion of the land became Charlestown State Park. In October 2016, all the land and facilities were officially sold by the government. This item is part of a larger collection of items from INAAP that are kept at Charlestown Library. R E V I S E D F I N A L R E P O R TP & E AREA FLUME – SITE 54INDIANA ARMY AMMUNITION PLANTPHASE II RCRA FACILITY INVESTIGATIONPrepared forU.S. Army Corps of EngineersLouisville DistrictOctober 2002Prepared by12120 Shamrock Plaza, Suite 300Omaha, Nebraska 68154TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA iExecutive Summary ..........................................................................................................................ES-1Section 1 Site Location and Description....................................................................................... 1-11.1 Operational History and Waste Characteristics ....................................... 1-21.2 Previous Investigations ............................................................................ 1-21.3 Report Organization................................................................................. 1-3Section 2 Field Activities Summary .............................................................................................. 2-12.1 Soil and Sediment Sampling.................................................................... 2-12.1.1 Soil ............................................................................................... 2-12.1.1.1 Surface Soil Sampling................................................... 2-12.1.1.2 Soil Boring Sampling.................................................... 2-12.1.2 Sediment ...................................................................................... 2-22.2 Surface Water Sampling .......................................................................... 2-32.3 Spring Sampling....................................................................................... 2-42.4 Groundwater Sampling ............................................................................ 2-42.5 Field Screening Results............................................................................ 2-42.6 IDW Disposition ...................................................................................... 2-4Section 3 Physical Investigation Results ..................................................................................... 3-13.1 Topography and Surface Features ........................................................... 3-13.2 Local Surficial Geology........................................................................... 3-13.2.1 Flume Sections I and II ................................................................ 3-13.2.2 Flume Section III ......................................................................... 3-13.3 Shallow Hydrogeology and Surface Water Hydrology ........................... 3-13.3.1 Flume Section I............................................................................ 3-23.3.2 Flume Section II........................................................................... 3-23.3.3 Flume Section III ......................................................................... 3-23.4 Jenny Lind Run Surface Water and Springs ............................................ 3-2Section 4 Data Quality Review and Validation ............................................................................. 4-14.1 Phase I RI................................................................................................. 4-14.2 Phase II RFI ............................................................................................. 4-1TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA iiSection 5 Chemical Investigation Results .................................................................................... 5-1Section 6 Contamination Assessment.......................................................................................... 6-16.1 Potential Sources of Contamination from Historical ManufacturingProcesses .................................................................................................. 6-16.1.1 Production of Diphenylamine and Dimethylamine ..................... 6-16.1.2 Production of Nitrocellulose and Smokeless Powder.................. 6-26.2 Near Surface Soils and Sediments ........................................................... 6-36.2.1 VOCs............................................................................................ 6-36.2.2 SVOCs ......................................................................................... 6-36.2.3 Pesticides/PCBs ........................................................................... 6-46.2.4 Nitroaromatics/Nitramines........................................................... 6-46.2.5 Metals and Cyanide...................................................................... 6-56.3 Subsurface Soils....................................................................................... 6-56.3.1 VOCs............................................................................................ 6-56.3.2 SVOCs ......................................................................................... 6-66.3.3 Pesticides...................................................................................... 6-66.3.4 Nitroaromatics/Nitramines........................................................... 6-66.3.5 Metals........................................................................................... 6-66.4 Surface Water........................................................................................... 6-76.4.1 VOCs............................................................................................ 6-76.4.2 SVOCs ......................................................................................... 6-76.4.3 Pesticides...................................................................................... 6-76.4.4 Metals........................................................................................... 6-76.5 Springs ..................................................................................................... 6-86.5.1 VOCs............................................................................................ 6-86.5.2 SVOCs ......................................................................................... 6-86.5.3 Pesticides...................................................................................... 6-86.5.4 Metals........................................................................................... 6-86.6 Groundwater ............................................................................................ 6-96.6.1 Metals........................................................................................... 6-9Section 7 Human Health Risk Evaluation ..................................................................................... 7-1TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA iii7.1 Introduction.............................................................................................. 7-17.1.1 Purpose......................................................................................... 7-17.2 Risk Screening Process ............................................................................ 7-27.2.1 Identification of Contaminants of Potential Concern(COPCs)....................................................................................... 7-27.3 Exposure Assessment............................................................................... 7-37.3.1 Exposure Point Concentrations.................................................... 7-47.3.1.1 95% Upper Confidence Limit (UCL) ........................... 7-47.3.1.2 Deer Tissue Concentration............................................ 7-57.3.2 Receptors...................................................................................... 7-77.3.3 Exposure Pathways ...................................................................... 7-77.3.4 Exposure Assumptions ................................................................ 7-97.4 Toxicity Assessment .............................................................................. 7-127.4.1 Toxicity Assessment of Noncarcinogenic Effects ..................... 7-127.4.2 Toxicity Assessment of Carcinogenic Effects ........................... 7-147.4.3 Source of the Critical Toxicity Values....................................... 7-157.5 Risk Characterization............................................................................. 7-167.5.1 Qualitative Assessment of Exposure to Aluminum ................... 7-187.5.2 Qualitative Assessment of Exposure to Manganese .................. 7-197.5.3 Qualitative Assessment of Mercury........................................... 7-197.6 Uncertainty Analysis.............................................................................. 7-207.6.1 Data Collection and Evaluation ................................................. 7-217.6.1.1 Data Collection ........................................................... 7-217.6.1.2 Data Evaluation........................................................... 7-217.6.1.3 Exposure Point Concentrations................................... 7-227.6.2 Exposure Assessment................................................................. 7-227.6.3 Toxicity Assessment .................................................................. 7-237.6.4 Risk Characterization................................................................. 7-24Section 8 Ecological Risk Evaluation ........................................................................................... 8-18.1 Introduction.............................................................................................. 8-1TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA iv8.1.1 Purpose......................................................................................... 8-28.1.2 Background.................................................................................. 8-28.1.3 Technical Approach ..................................................................... 8-38.2 Screening Level Ecological Risk Screen ................................................. 8-48.2.1 Habitat Assessment and Applicable Media ................................. 8-48.2.2 Identification of Chemicals of Potential Ecological Concern(COPECs) .................................................................................... 8-48.2.2.1 Environmental Screening Values for Surface Water andChemicals of Potential Ecological Concern ................................ 8-78.2.2.2 Environmental Screening Values for Sediment-AssociatedOrganisms and Chemicals of Potential Ecological Concern ....... 8-98.2.2.3 Environmental Screening Values for Soil-AssociatedOrganisms and Chemicals of Potential Ecological Concern ..... 8-108.2.2.4 Environmental Screening Values for Higher Vertebratesand Chemicals of Potential ecological Concern ........................ 8-108.3 Tier II Ecological Risk Assessment....................................................... 8-168.3.1 Problem Formulation ................................................................. 8-168.3.1.1 Relevant Ecological Issues and Environmental Setting8-168.3.1.2 Summary and Assessment Endpoints ......................... 8-238.3.1.3 Exposure Assessment.................................................. 8-248.3.1.4 Toxicity (Effects) Assessment .................................... 8-308.3.2 Analysis Plan ............................................................................. 8-348.3.2.1 Measurement Endpoints and Receptors of Concern... 8-348.3.2.2 Toxicity Reference Values for Risk Characterization 8-468.4 Risk Characterization............................................................................. 8-488.4.1 Primary Producers and Assessment Endpoint Number One...... 8-498.4.2 Decomposers and Detritivores - Assessment EndpointNumber Two .............................................................................. 8-508.4.3 Water Column Invertebrates and Aquatic Vertebrates -Assessment Endpoint Number Three and MeasurementEndpoints 1 and 2....................................................................... 8-518.4.4 Terrestrial and Semiaquatic Herbivores – AssessmentEndpoint Number 3 and Measurement Endpoints 3 and 4 ........ 8-528.4.5 Terrestrial and Semiaquatic Omnivores and AssessmentEndpoint Number 4.................................................................... 8-52TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA v8.4.6 Terrestrial and Semiaquatic First-Order Carnivores andAssessment Endpoint Number 5................................................ 8-558.4.7 Terrestrial and Semiaquatic 2nd Order Carnivores andAssessment Endpoint Number 6................................................ 8-578.4.8 Cave Resources - Assessment Endpoint Number 7................... 8-578.4.9 Risk Characterization Summary and Ecological Significance .. 8-578.5 Uncertainty Analysis.............................................................................. 8-60Section 9 Summary and Recommendations ................................................................................ 9-19.1 Summary.................................................................................................. 9-19.1.1 Physical Characteristics ............................................................... 9-19.1.2 Contamination Assessment.......................................................... 9-19.1.2.1 Near Surface Soil and Sediment ................................... 9-29.1.2.2 Subsurface Soil Samples............................................... 9-29.1.2.3 Surface Water Samples ................................................. 9-29.1.2.4 Spring Samples ............................................................. 9-29.1.2.5 Groundwater Samples................................................... 9-29.1.3 Human Health Risk Screen/Assessment...................................... 9-29.1.3.1 Soil/Sediment................................................................ 9-39.1.3.2 Groundwater/Surface Water ......................................... 9-39.1.4 Ecological Risk Screen / Assessment .......................................... 9-39.2 Recommendations.................................................................................... 9-4Section 10 References.................................................................................................................... 10-1TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA viTable 2-1 Summary of Phase I RI Samples for Chemical AnalysisTable 2-2 Summary of Phase II RFI Samples for Chemical AnalysisTable 2-3 Summary of Field Screening For Soil and Sediment SamplesTable 5-1 Summary of Chemicals Detected in Soil and Sediment SamplesTable 5-2 Summary of Chemicals Detected in Surface Water and GroundwaterSamplesTable 5-3 Summary of Chemicals Detected in Spring SamplesTable 7-1 Comparison of Total Soil Concentrations to Screening LevelsTable 7-2 Comparison of Maximum Surface Soil and Sediment Concentrations toScreening LevelsTable 7-3 Comparison of Surface Water, Springs, and Groundwater Concentrations toScreening LevelsTable 7-4 Total Soil/Sediment Exposure Point ConcentrationTable 7-5 Surface Soil/Sediment Exposure Point ConcentrationsTable 7-6 Deer Tissue ConcentrationsTable 7-7 Parameters Used To Evaluate Potential Exposure Human Health RiskAssessmentTable 7-8 Critical Toxicity Values for Chemicals of Potential ConcernTable 7-9 USEPA Weight-Of-Evidence Carcinogenic Classification of ChemicalsTable 7-10 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Total Soil/Sediment – Excavation WorkerTable 7-11 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Surface Soil/Sediment – Site WorkerTable 7-12 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Surface Soil/Sediment and Game Ingestion - HunterTable 7-13 Summary of Non-Carcinogenic Health Hazards and CarcinogenicRisks Associated with Total Soil/Sediment – Child RecreatorTable 8-1 Comparison of Maximum Surface Water Concentrations to EcologicalScreening Values (ESVs)Table 8-2 Comparison of Maximum Sediment Concentrations to Ecological ScreeningValues (ESVs)Table 8-3 Comparison of Maximum Soil Concentrations to Ecological ScreeningValues (ESVs)TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA viiTable 8-4 Comparison of Potential Dietary (Foodweb) Concentrations Based onMaximum Water/Soil/Sediment Concentrations to Ecological ScreeningValuesTable 8-5 Comparison of Predicted Air Concentrations within Caves Based onMaximum Surface Water Concentrations to Ecological Screening ValuesTable 8-6 Chemicals Selected as Chemicals of Potential Ecological Concern forDirect Ecological ExposuresTable 8-7 Chemicals Selected as Chemicals of Potential Ecological Concern forIndirect (Food Web) ExposuresTable 8-8 Summary of Chemicals of Potential Ecological Concern and MeasurementEndpoints for the Ecological Risk AssessmentTable 8-9 Physical and Behavioral Characteristics of Representative Species Used asReceptors of ConcernTable 8-10 Assumed Dietary Compositions for the Representative Receptors ofConcern (ROCs)Table 8-11 Toxicity Reference Values (TRVs) for Direct Exposure to Chemicals ofPotential Ecological Concern in WaterTable 8-12 Toxicity Reference Values for Direct Exposure to Chemicals of PotentialEcological Concern in SedimentTable 8-13 Toxicity Reference Values for Direct Exposures to Chemicals of PotentialEcological Concern in SoilTable 8-14 Oral Toxicity Reference Values Selected for Indirect Exposures (Foodweb)to Chemicals of Potential Ecological ConcernTable 8-15 Ecological Hazard Quotient Results for Terrestrial Plants - AssessmentEndpoint #1 - Measurement Endpoints #1Table 8-16 Ecological Hazard Quotient Results for Aquatic Plants and AlgaeAssessment Endpoint #1 - Measurement Endpoints # 2 & 3Table 8-17 Ecological Hazard Quotients Results for Soil Microbial Activity andInvertebrate Detritivores Assessment Endpoint #2 - Measurement Endpoints# 1 & 2Table 8-18 Ecological Hazard Quotient Results for Sediment-Associated InvertebrateDetritivores Assessment Endpoint #2 - Measurement Endpoints #3, 4, 5,& 6Table 8-19 Ecological Hazard Quotient Results for Aquatic (Water Column)Invertebrates and Vertebrates (Amphibians) - Assessment Endpoint #3 -Measurement Endpoints #1, 2, & 3Table 8-20 Ecological Hazard Quotient Results for Representative HerbivoresAssessment Endpoint #3 - Measurement Endpoints #4 & 5TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev2 (revised final).doc\17-Sep-02 /OMA viiiTable 8-21 Ecological Hazard Quotient Results for Representative OmnivoresAssessment Endpoint #4 - Measurement Endpoints #1, 2 & 3Table 8-22 Ecological Hazard Quotient Results for Representative 1st-Order CarnivoresAssessment Endpoint #5 - Measurement Endpoints #1, 2 & 3Table 8-23 Ecological Hazard Quotient Results for Representative Top PredatorsAssessment Endpoint #6 – Measurement Endpoints #1 & 2TABLE OF CONTENTSList of FiguresQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA ixFigure 1-1 Site Location MapFigure 1-2 Surface Features MapFigure 2-1 Sample Location MapFigure 3-1 Simplified Boring LogFigure 6-1 Concentrations of Chemicals Detected in SoilFigure 6-2 Concentrations of Chemicals Detected in SedimentFigure 6-3 Concentrations of Chemicals Detected in Surface Water andGroundwaterFigure 8-1 Ecological Evaluation ProcessFigure 8-2 Conceptual Ecological Exposure (Direct & Foodweb) ModelFigure 9-1 Human Health COPCs and Ecological COPECs Detected in Soil,Sediment, Surface Water, and GroundwaterTABLE OF CONTENTSList of AppendicesQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xAppendix A Data Quality Review and ValidationAppendix B Human Health Risk Statistics and CalculationsAppendix C Ecological Risk Statistics and CalculationsAppendix D Daily Quality Control ReportsAppendix E Boring and Trench Logs; Topographic Survey DataAppendix F Geotechnical DataAppendix G Sample Collection Field SheetsAppendix H Summary of Analytical DataNote: Information contained in the Appendixes is included in CD-ROM format. The CD-ROMmay be found at the back of this binder.TABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xiACHe AcetylcholinesteraseADI Acceptable Daily IntakeADNTs Amino-dinitrotoluenesATP Adenosine TriphosphateAE Assessment EndpointAEC U.S. Army Environmental CenterAET Apparent Effect LevelsALAD Alpha-aminolevulinic Acid DehydrogeuaseAPCB Jefferson County Air Pollution Control BoardAQUIRE Aquatic Information Retrieval System.AST Aboveground Storage TankASTER Assessment Tools for the Evaluation of RiskATSDR Agency for Toxic Substances and Disease Registrybgs Below Ground SurfaceBA BioavailabilityBCFs Bioconcentration FactorsBRAC Base Re-Alignment and ClosureBSAFs Biota-Sediment Accumulation FactorsBTEX Benzene, Toluene, Ethylbenzene, XylenesBTFs Biota Transfer FactorsBtu British Thermal UnitBW Body WeightCERCLA Comprehensive Environmental Response, Compensation, and Liability ActCDI Chronic Daily IntakeCLP Contract Laboratory ProgramCMS Corrective Measures StudyCOC Chemicals of ConcernCOI Chemical of InterestCOPC Chemicals of Potential ConcernCOPEC Chemicals of Potential Ecological ConcernCRDL Contract Required Detection LimitCRQL Contract Required Quantitation LimitsTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xiiCSP Charlestown State ParkCTE Central Tendency ExposureCTV Critical Toxicity ValueDAF Dilution Attenuation FactorDBT Dibutyl phthalateDDD dichlorodiphenyldiehlorethaneDDE 4, 4 DDEDDT 1, 1’ (2,2,2-Trichloroethylidene)bis[4-chlorobenzene]DERP Defense Environmental Restoration ProgramDNA Deoxyribonucleic acidDOD Department of DefenseDQCR Data Quality Control ReportsDQO Data Quality ObjectivesDS Direct Push SoilDW Direct Push WaterEECs Environmental Exposure ConcentrationsEEQ Environment Exposure QuotientEM ElectromagneticEPA U.S. Environmental Protection AgencyEPC Exposure Point ConcentrationEQP Equilibrium-PartitioningERA Ecological Risk AssessmentERAGs Ecological Risk Assessment Guidance for SuperfundERL Effects – Range - LowERM Effects – Range – MediumERT Emergency Response TeamESV Ecological Screening ValueFC Fraction IngestedFSP Field Sampling PlanGABA Gamma-aminobutyric AcidGOCO Government-Owned, Contractor-Operatedgpm gallons per minuteTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xiiiGPR Ground Penetrating RadarHEAST Health Effects Assessment Summary TablesHHRA Human Health Risk AssessmentHI Hazard IndexHLSC Human Life Cycle Safe ConcentrationHMW High Molecular WeightHOP Hoosier Ordnance PlantHQ Hazard QuotientHSA hollow-stem augerHSDB Hazardous Substance DatabaseICI ICI Americas, Inc.ID inner diameterIDEM Indiana Department of Environmental ManagementIDL Instrument Detection LimitIDNR Indiana Department Natural ResourcesIEUBK Integrated Exposure Uptake BiokineticINAAP Indiana Army Ammunition PlantIOW Indiana Ordnance Works Plant 1IRIS Integrated Risk Information SystemIWPCB Indiana Water Pollution Control BoardIWQC Indiana Water Quality CriteriaIOWP Indiana Ordnance Works Plant 2J/UJ Qualified EstimatedKg KilogramL/day Liter per dayLAP Load, Assemble, and PackLC LeachateLMW Low Molecular WeightLOAEL Lowest to Observed Adverse Effects LevelLOEC Lowest Observation Effect concentrationsLOQ Limits of QuantitationMATC Maximum Acceptable Toxicant ConcentrationTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xivMCL Maximum Contaminant LevelME Measurement Endpointmg/day milligrams per daymg/kg milligram per kilogrammg/m3 milligram per cubic meterMS/MSD Matrix Spike/Matrix Spike DuplicateMSL Mean Sea LevelMW Monitoring WellNCEA National Center for Environmental AssessmentNOAEL No Observable Adverse Effects LevelNOD Notice of DeficiencyNPDES National Pollutant Discharge Elimination SystemOD outside diameterORNL Oak Ridge National LaboratoryP&E Propellants and ExplosivesPA Preliminary AssessmentPAH Polycyclic Aromatic HydrocarbonPCB Polychlorinated BiphenylPEL Probable – Effects – LevelPpm parts per millionPRG Preliminary Remediation GoalsPVC Polyvinyl ChlorideQA Quality AssuranceQAPP Quality Assurance Project PlanQC Quality Control“R” RejectedRAGS Risk Assessment Guidance for SuperfundRBC Risk-Based ConcentrationRCRA Resource Conservation and Recovery ActRDA Recommended Daily AllowanceRfD Reference DoseRFD-I Reference Inhalation DoseTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xvRFI RCRA Facility InvestigationRI Remedial InvestigationRISC Risk Integrated System of ClosureRME Recommended Maximum ExposureRNA Ribonucleic acidROC Receptor of ConcernSAP Sampling and Analysis PlanSARA Superfund Amendments and Reauthorization ActSB Soil BoringSCEM Site Conceptual Exposure ModelSCFS Sample Collection Field SheetsSD SedimentSF-SH Slope Factor-Sulfhydryl ligandsSOP Standard Operating ProcedureSP SpringSS Shallow SoilSVOC Semivolatile Organic ChemicalsSW Surface WaterSWQC Surface Water Quality CriteriaTAL Target Analyte ListTCL Target Compound ListTCLP Toxicity Characteristic Leaching ProcedureTDS Total Dissolved SolidsTEL Threshold – Effects – LevelTNT TrinitrotouleneToxNet Toxicity Data NetworkTPH Total Petroleum HydrocarbonsTRV Toxicity Reference ValueTSS Total Suspended Solids“U” Qualified Nondetectμg/kg microgram per kilogramμg/L microgram per LiterTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA xviμg/m3 microgram per cubic meterUCL Upper Confidence LimitURSGWC URS Greiner Woodward ClydeUSACE U.S. Army Corps of EngineersUSATHAMA U.S. Army Toxic and Hazardous Materials AgencyUSCS Unified Soil Classification SystemUSDA U.S. Department of AgricultureUSEPA U.S. Environmental Protection AgencyUSGS U.S. Geologic SurveyUST Underground Storage TankUTL Upper Tolerance LimitVOC Volatile Organic ChemicalsW-C Woodward-ClydeExecutive Summary P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA ES-1The following includes the results of the Phase II RCRA Facility Investigation (RFI) completedat the Propellants and Explosives (P&E) Area Flume (Site 54) at the Indiana Army AmmunitionPlant (INAAP). The report also summarizes the results of the previously completed Phase IRemedial Investigation (RI).INAAP currently encompasses approximately 9,790 acres in south-central Clark County,Indiana. Its southern boundary is approximately 6 miles north of Jeffersonville, Indiana and 10miles from the Louisville, Kentucky metropolitan area, which lies to the south across the OhioRiver. INAAP is a Government-Owned, Contractor-Operated (GOCO), inactive militaryindustrial installation. The Army intends to transfer the property to the Local Reuse Authorityfor commercial development or to the State of Indiana for inclusion in the state park system. TheP&E Area Flume is one of 90 sites identified at INAAP.The Plant was originally constructed as three separate facilities: The Indiana Ordnance WorksPlant 1, the Hoosier Ordnance Plant, and the Indiana Works Plant 2. The three facilities wereconsolidated into the Indiana Arsenal in 1945. The Indiana Arsenal was redesignated as theIndiana Ordnance Plant in 1961; in August 1963, it was redesignated again as the Indiana ArmyAmmunition Plant.Topography at the INAAP can be described as a middle-aged karst topography. Karsttopography is produced by the dissolution of limestone, gypsum, or other readily soluble rocks,commonly along joints, fractures, bedding planes, or other such features. The dissolutionprocess results in the formation of sinkholes, caves, and underground drainage. Numeroussinkholes and springs are found throughout much of INAAP.Approximately 96 percent of INAAP’s land surface drains directly into the Ohio River via sevendrainage basins. The remaining 4 percent reaching the Ohio River indirectly through thePheasant Run basin.Groundwater at INAAP is present in the bedrock formations of the upland areas and in theterrace/floodplain sand and gravel deposits located within the Ohio River valley. Thegroundwater present in the floodplain aquifer along the Ohio River is a major water supplysource. Groundwater is not usually found in the thin soil layer covering the bedrock surface inthe upland areas. When present, shallow groundwater typically mingles with surface water byflowing in and out of karst features.The Phase I and II investigations at the P&E Area Flume included the completion of six soilborings, the collection and analysis of 40 surface and subsurface soil samples, 21 collocatedsurface water/sediment samples, ten additional sediment samples, ten spring samples, and twogroundwater samples. Chemical analyses included VOCs, SVOCs, metals,nitroaromatic/nitramine compounds, pesticides/PCBs, pH, and various wet chemistry parameters.The P&E Area Flume carried process wastewater, sewage treatment effluent and storm waterrunoff from the P & E Area to a discharge point approximately 200 to 300 feet upgradient of theProcess Waste Settling Basin (Site 6). It is primarily a wooden structure that is 4 feet by 6 feetwith one section that consists of a rectangular concrete sewer. Parts of the flume are in theExecutive Summary P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA ES-2ground and others are elevated as much as 5 feet above ground. The flume parallels thestreambed of Jenny Lind Run.The shallow stratigraphy in the area of the flume’s first two sections consists of clay fill andresidual soils over limestone bedrock. The soils directly beneath the flume’s third sectiontypically consist of clay fill or colluvium, underlain by residual soil. Colluvium and residual soildirectly beneath and to the side of the flume ranged from less than 2 feet thick to about 7 feetthick and was underlain by limestone bedrock. Nitrocellulose fibers and propellant were foundon the ground surface in the area of Soil Borings 54SB03 and 54SB04, along the sides of theflume.Groundwater was encountered in three of the soil borings at approximate depths ranging from1.5 to 7.9 feet bgs. All three borings were located north of 14th Street.Many of the karst features within Jenny Lind Run were present at the time of the P&E Area’soperation. Any process wastewater discharged directly into Jenny Lind Run and any wastewaterthat may have leaked from the flume within Jenny Lind Run could have directly entered thesubsurface through these karst features.A contamination assessment was completed for near surface soil and sediment, subsurface soil,surface water, springs, and groundwater. Elevated levels five SVOCs and twonitroaromatic/nitramine compounds were detected in near surface soil and sediment samples.Elevated levels of two SVOCs and one nitroaromatic/nitramine compound were detected insubsurface soil samples. Elevated levels of target compounds were not detected in surface water,spring or groundwater samples. Several metals results exceeded background concentrations forall media sampled.Future land use may include transfer of part of the property to the Indiana Department of NaturalResources. Therefore a human health risk assessment evaluated the on-site worker, excavationworker, hunter, and child recreator scenarios. The results indicate that the potential primarycarcinogenic risk drivers are incidental ingestion of 2,4-dinitrotoluene and 2,6-dinitrotoluenefrom soil/sediment. The cancer risks ranged from 3 x 10-8 to 6 x 10-7 for the RecommendedMaximum Exposure (RME) and 7 x 10-10 to 5 x 10-8 for Central Tendency Exposure (CTE). Theprimary non-carcinogenic risk drivers were ingestion of mercury and methyl mercury fromsoil/sediment and deer tissue, respectively. Hazard indices ranged from 0.014 to 0.4 for RMEand 0.0007 to 0.07 for CTE. The cancer risk did not exceed the IDEM target level of 1 x 10-5and the cumulative Hazard Index did not exceed the target level of 1.0 indicating that no adversehealth effects or risks would be anticipated.Part of the P&E Area Flume is expected to become part of the existing state park system.Several pathways were evaluated as part of a ecological risk assessment. However, the keyecological risk drivers are considered to be those chemicals of ecological concern that appear tohave a potential adverse impact on the more wide-ranging transient receptors of concern whomay receive additional exposures(s) to other areas of potential contamination. These chemicalsof concern have a potential for adverse effects beyond the administrative boundaries of the P&EArea Flume. They include carnivores exposed to mercury, PAHs, DDT and endrin as well assilver in water possibly reaching cave resources.Executive Summary P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA ES-3Data of sufficient quality and quantity has been collected to characterize the P&E Area Flume.Physical and chemical investigation results indicate that there are potential ecological concernswhile human health concerns are less significant. Based on the results of the Phase I RI andPhase II RFI a Corrective Measures Study has been recommended to evaluate variousalternatives to reduce ecological and human exposures to acceptable levels.Site Location and DescriptionSECTIONONE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 1-1The Propellants and Explosives(P&E) Area Flume, located in thewest-central portion of IndianaArmy Ammunition Plant (INAAP)(see Figure 1-1), carried processwastewater, sewage (sanitary waste)treatment plant effluent, and stormwater from the P&E Area to theProcess Waste Settling Basin (Site6). The flume begins at the outfallof the P&E Sewage Treatment Plant(Site 10), parallels the streambed ofJenny Lind Run, and empties ontothe ground at the upstream end ofthe Process Waste Settling Basin (Site 6). The structure measures approximately 9,700 feet long,by 6 feet wide, by 4 feet deep and is constructed mainly of wood, with the exception of aconcrete subterranean section. Much of the wood shows signs of a creosote treatment.The P&E Flume was built to replace standard vitrified clay sewer lines that were repeatedlydamaged by collapse (sinkhole formation). The flume was designed to span limited collapsefeatures until repairs could be made, while avoiding service interruptions and wastewaterdischarges to the ground surface.Sections of the P&E Area FlumeThe P&E Area Flume can be divided into three primary sections: Sections I, II, and III (seeFigure 1-2). These divisions are distinguished as follows:· Section I: extends from the P&E Sewage Treatment Plant (Site 10) to the serviceroad located just north of Building 214-57 (see Figure 1-2). This section of theflume is a wood box culvert, set in the ground, with its top at ground level.Several tile lines, approximately 4 inches in diameter, empty into this section ofthe flume. These tile lines drain the area surrounding the flume. It is unknownhow far out from the flume these lines extend. The approximate length of SectionI is 1,515 feet.· Section II: runs underground from a location just north of Building 214-57 to alocation just east of Building 235-6, where it resurfaces within Jenny Lind Run.This section of the flume is essentially a rectangular concrete sewer. Theapproximate length of Section II is 1,457 feet.· Section III: begins at a location just east of Building 235-6 within Jenny LindRun, crosses under 14th Street and Walnut Street to the south, and ends roughly200 to 300 feet west of the Process Waste Settling Basin (Site 6). This thirdsection of the flume consists of creosote-treated wood that rests just above groundSite Location and DescriptionSECTIONONE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\22-May-02 /OMA 1-2north of 14th Street, but is elevated up to 5 feet above ground surface south of14th Street. The approximate length of Section III is 6,723 feet.The flume has not been in use for process wastewater or treatment plant effluent since INAAPlast operated. Large sections along the entire length of the flume were observed to be indisrepair, with pieces of wood completely missing from the sides and base of the flume, andpartially rotten. Storm water run off in the beginning of the flume disappears into varioussubterranean cavities within the first 500 ft of the flume, and subsequent sections appearincapable of containing any water or effluent.1.1 OPERATIONAL HISTORY AND WASTE CHARACTERISTICSThe P&E Flume (referenced as Building 620) was constructed in 1953 (according to an INAAPbuilding list). Prior to the flume’s construction, the associated industrial and sanitary wastewateroutfalls discharged directly to caves or the Jenny Lind Run drainage basin.Wastes reportedly discharged to the flume included acidic wastes from Buildings 706-2 and 706-3 (Sites 70 and 32, respectively), wastewater from the ammonium nitrate plant, and coolingwater from the south power plant. The flume is reportedly “thought to have carried some ofevery possible contaminant originating in the P&E Area” (USATHAMA 1980).Wastewater leaking from the flume would have infiltrated, evaporated, or flowed to thestreambed of Jenny Lind Run. Leaks or breaks in the flume could potentially have releasedcontaminants produced in the P&E Area to the surrounding soil, surface water, and groundwater.Although the flume was not designed to carry waste propellant, propellant was observed withinor near the flume at the following locations:· Within the flume at the end of Section I· Within the flume, approximately 400 feet north of 14th Street· On the ground beneath and along the edge of the flume, approximately 50 feetnorthwest of 14th Street· On the ground beneath the flume, several hundred feet south of Walnut Street· On the ground at the end of the flume· In the streambed of Jenny Lind Run at the end of the flume near the upstream endof the Process Waste Settling Basin (Site 6)1.2 PREVIOUS INVESTIGATIONSThis report compiles the results of the Phase I Remedial Investigation (RI) (W-C 1998) and theresults of the Phase II Resource Conservation and Recovery Act (RCRA) Facility Investigation(RFI) for Site 54. Prior to the Phase I RI, no investigations of the P&E Flume were completed.Site Location and DescriptionSECTIONONE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\22-May-02 /OMA 1-31.3 REPORT ORGANIZATIONThe remaining portion of this report is organized as follows:· Section 2 – Field Activities Summary· Section 3 – Physical Investigation Results: reviews site topography, localsurficial geology, and shallow hydrogeology· Section 4 – Data Quality Review and Validation: summarizes the results of the100 percent quality control (QC) review and the ten percent full validation· Section 5 – Chemical Investigation Results: identifies the chemical analyses usedand field duplicate samples collected; summarizes the sample detections bysample identification number and matrix type in tabular form· Section 6 – Contamination Assessment: uses text and figures to assess chemicalspresent at the site in elevated concentrations, based on matrix and chemical group· Section 7 – Human Health Risk Evaluation: examines the chemicals present invarious matrices at the site to determine if they pose a threat to human health· Section 8 – Ecological Health Risk Evaluation: examines the chemicals presentin various matrices at the site to determine if they pose a threat to the environment· Section 9 – Summary and Recommendations: includes corrective measure studyobjectives· Section 10 – ReferencesFor additional information regarding the rationale for and the objectives of the Phase II RFI,refer to the Field Sampling Plan (URSGWC 2001).Field Activities SummarySECTIONTWO P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 2-1Field activities for this site included shallow soil, subsurface soil, sediment, surface water, andspring sampling. The locations of the sampling points are provided on Figure 2-1. Samplelocation, identification, depth, matrix, and chemical analysis are presented in Tables 2-1 forsamples collected in 1996 and Table 2-2 for samples collected in 2000. All field activities werecompleted in accordance with applicable Standard Operating Procedures (SOPs) (W-C 1995,URSGWC 2000b). Any deviations from the SOPs are noted on the Sample Collection FieldSheets (SCFS), provided in Appendix G.2.1 SOIL AND SEDIMENT SAMPLING2.1.1 Soil2.1.1.1 Surface Soil SamplingTwenty-two near surface soil samples (54SS01 through 54SS22) were collected adjacent to theflume in locations where the flume was a significant distance from the Jenny Lind Runstreambed. Shallow soil samples were collected from the following locations (see Figure 1-2)using a stainless steel hand auger:· Beneath the flume in places where it is elevated· Adjacent to the flume in areas where the flume rests on the ground· From areas where the flume was positioned approximately 15 feet from the JennyLind Run streambed· Where washouts extending from the flume to the streambed were observed2.1.1.2 Soil Boring SamplingSix soil borings were completed at Site 54. One soil boring was drilled using hollow stem augers(4 ¼-inch inner diameter, 8-inch outer diameter) and a 3-inch diameter stainless steel split spoon.· Boring 54SB01 was completed adjacent to the flume, near Building 214-57, at thejunction of Sections I and II. The flume is set in the ground at the location of thisboring, so any wastewater leaking from the flume would likely infiltrate into theunderlying soil. The boring was drilled to auger refusal at a depth of 8.5 feet bgs.Three soil samples from multiple depths were retained for chemical analysis. Thethird sample was collected at the soil-bedrock interface, at a depth lower than thebase of the flume.The other five borings were completed using a stainless steel hand auger at the followinglocations:· Boring 54SB02 was completed near the point where the P&E Area Flume crossesfrom the east side of Jenny Lind Run to the west side. Auger refusal was reachedat 1.3 feet bgs and two samples were retained for chemical analysis.Field Activities SummarySECTIONTWO P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 2-2· Borings 54SB03 and 54SB04 were completed along the flume at locations wherepropellant had been observed. Auger refusal was reached at 8.0 feet bgs in boring54SB03 and four samples at various depths were retained for chemical analysis;auger refusal was reached at 6.9 feet bgs in boring 54SB04 and three sampleswere retained at various depths for chemical analysis.· Boring 54SB05 was completed adjacent to the junction of Sections II and III ofthe flume. Auger refusal was reached at 6.0 feet bgs and three samples wereretained at various depths for chemical analysis.· Boring 54SB06 was completed adjacent to downstream from an overflowstructure. Auger refusal was reached at 5.8 feet bgs and three samples wereretained at various depths for chemical analysis.The boring locations are shown on Figure 2-1 and the boring logs are included in Appendix E.2.1.2 SedimentThirty-one sediment samples were collected from the area of the P&E Flume and from thestreambed in Jenny Lind Run. Twenty-one of these samples were collocated with surface watersamples (see Section 2.2); water was not present at the other ten sediment sample locations at thetime of collection. At the time of the site visits, the flume was in a state of disrepair andincapable of transporting liquids. The site reconnaissance indicated little sediment wascontained within the flume itself. Therefore, sediment samples were collected from the JennyLind Run, located adjacent to and down slope from the flume.The following 25 sediment samples were collected from the streambed in Jenny Lind Run:· 54SD01 through 54SD11 (collocated with the respective surface water samples54SW01 through 54SW11);· 54SD15 (collocated with 54SW15);· 54SD16 through 54SD18;· 54SD19 (collocated with 54SW19);· 54SD20;· 54SD21;· 54SD22 through 54SD24 (collocated with 54SW22 through 54SW24);· 54SD25;· 54SD26;· 54SD30; and,· 54SD31.Field Activities SummarySECTIONTWO P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 2-3The following six sediment samples were collected from within the flume:· 54SD12 through 54SD14 (collocated with the respective surface water samples54SW12 through 54SW14);· 54SD27 (planned collocated with 54SW27, but separated by approximately 50feet due to safety issues associated with the sinkhole that the flume spans at thislocation);· 54SD28 (collocated with 54SW28); and,· 54SD29.Samples were collected directly upstream and downstream of points of stream insurgence andresurgence (points where the stream disappeared into and reappeared from collapse features),where applicable. Sediment sampling locations are shown on Figure 2-1.2.2 SURFACE WATER SAMPLINGTwenty-one surface water samples were collected from locations collocated with sedimentsamples (see Section 2.1.2) using laboratory-prepared glass containers as sampling equipment.Surface water and sediment samples were collected from the Jenny Lind Run, located adjacent toand down slope from the flume.The following 16 surface water samples were collected from the streambed in Jenny Lind Run:· 54SW01 through 54SW11 (collocated with the respective sediment samples54SD01 through 54SD11);· 54SW15 (collocated with 54SD15);· 54SW19 (collocated with 54SD19); and,· 54SW22 through 54SW24 (collocated with 54SD22 through 54SD24).The following five surface water samples were collected from within the flume:· 54SW12 through 54SW14 (collocated with the respective sediment samples54SD12 through 54SD14);· 54SW27 (planned collocated with 54SD27, but separated by approximately 50feet due to safety issues associated with the sinkhole that the flume spans at thislocation); and,· 54SW28 (collocated with 54SD28).Samples were collected directly upstream and downstream of points of stream insurgence andresurgence where applicable. Surface water sampling locations are shown on Figure 2-1.Field Activities SummarySECTIONTWO P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\22-May-02 /OMA 2-42.3 SPRING SAMPLINGSprings SP04, SP34, SP35, SP41 were sampled as close to the sources as possible usinglaboratory-prepared glass containers as sampling equipment. Springs SP04, SP34, and SP35were each sampled during three rounds. Sample 4101SP00 was collected from Spring SP41 inDecember 2001; this is the only time this spring has been sampled. (The third and fourth digitsin the spring sample numbers represent the sampling round for an individual spring.) Springlocations are shown on Figure 2-1.2.4 GROUNDWATER SAMPLINGGroundwater samples 5404GW07 and 5405GW06 were collected from the correspondingborings (54SB04 and 54SB05) using disposable TeflonÒ bailers inserted into the completedboreholes. Boring locations are shown on Figure 2-1.2.5 FIELD SCREENING RESULTSField screening was completed during both investigations using headspace analysis. Recoveredsoil from each boring and sediment sample was field screened using a photoionization detector(PID) to verify the presence or absence of organic vapors. Headspace results are presented inTable 2-3.2.6 IDW DISPOSITIONInvestigation-derived wastes (IDW) including soil cuttings, development and purge water,decontamination fluids, and personal protective equipment (PPE) were containerized inaccordance with the Sitewide Work Plan (URSGWC 2000a). Disposal of the IDW containershas been documented in the “IDW Disposition Technical Memorandum” (URS 2001).TABLE 2-1SUMMARY OF PHASE I RI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMEParametersSampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix VOCs1 SVOCs2 Pest/PCB3Nitroaromatics /Nitramines4 Metals5 Nitrate/Nitrite6 Comments54SB01 5401SB02 0.0-2.0 Soil X X X X X X5401SB06 4.0-6.0 Soil X X X X X X5401SB08 6.0-8.0 Soil X X X X X X54SS01 5401SS02 0.0-2.0 Soil X X X X X X54SS02 5402SS02 0.0-2.0 Soil X X X X X X54SS03 5403SS02 0.0-1.0 Soil X X X X X X54SS04 5404SS02 0.0-1.0 Soil X X X X X X54SS05 5405SS02 0.0-0.8 Soil X X X X X X54SS06 5406SS02 0.0-2.0 Soil X X X X X X54SS07 5407SS02 0.0-0.4 Soil X X X X X X54SS08 5408SS02 0.0-0.8 Soil X X X X X X54SS09 5409SS02 0.0-1.5 Soil X X X X X X54SS10 5410SS02 0.0-1.5 Soil X X X X X X54SS11 5411SS02 0.0-2.0 Soil X X X X X X54SS11 5482SS02 0.0-2.0 Soil X X X X X X Duplicate (5411SS02)54SS12 5412SS02 0.0-2.0 Soil X X X X X X MS/MSD54SS13 5413SS02 0.0-1.5 Soil X X X X X X54SS14 5414SS02 0.0-2.0 Soil X X X X X X54SS15 5415SS02 0.0-2.0 Soil X X X X X X54SS16 5416SS02 0.0-1.8 Soil X X X X X X54SS17 5417SS02 0.0-2.0 Soil X X X X X X54SS18 5418SS02 0.0-2.0 Soil X X X X X X54SS19 5419SS02 0.0-2.0 Soil X X X X X X54SW/SD01 5401SW00 - Surface Water X X X X X X MS/MSD5401SD00 0.0-2.0 Sediment X X X X X X MS/MSD54SW/SD02 5402SW00 - Surface Water X X X X X X5402SD00 0.0-0.9 Sediment X X X X X X54SW/SD03 5403SW00 - Surface Water X X X X X X5403SD00 0.0-1.0 Sediment X X X X X X54SW/SD04 5404SW00 - Surface Water X X X X X X5404SD00 0.0-0.8 Sediment X X X X X XQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 1 of 3 5/21/02TABLE 2-1SUMMARY OF PHASE I RI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMEParametersSampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix VOCs1 SVOCs2 Pest/PCB3Nitroaromatics /Nitramines4 Metals5 Nitrate/Nitrite6 Comments54SW/SD05 5405SW00 - Surface Water X X X X X X5405SD00 0.0-0.75 Sediment X X X X X X5445SW00 - Surface Water X X X X X X Duplicate (5405SW00)54SW/SD06 5406SW00 - Surface Water X X X X X X5406SD00 0.0-0.6 Sediment X X X X X X54SW/SD07 5407SW00 - Surface Water X X X X X X5407SD00 0.0-0.4 Sediment X X X X X X54SW/SD08 5408SW00 - Surface Water X X X X X X5408SD00 0.0-1.2 Sediment X X X X X X5425SD00 0.0-1.2 Sediment X X X X X X Duplicate (5408SD00)54SW/SD09 5409SW00 - Surface Water X X X X X X5409SD00 0.0-0.4 Sediment X X X X X X54SW/SD10 5410SW00 - Surface Water X X X X X X5410SD00 0.0-0.5 Sediment X X X X X X54SW/SD11 5411SW00 - Surface Water X X X X X X5411SD00 0.0-2.0 Sediment X X X X X X54SW/SD12 5412SW00 - Surface Water X X X X X X5412SD00 0.0-0.2 Sediment X X X X X X54SW/SD13 5413SW00 - Surface Water X X X X X X5413SD00 0.0-0.5 Sediment X X X X X X54SW/SD14 5414SW00 - Surface Water X X X X X X5414SD00 0.0-0.2 Sediment X X X X X X54SW/SD15 5415SW00 - Surface Water X X X X X X5415SD00 0.0-2.0 Sediment X X X X X X54SD16 5416SD00 0.0-0.5 Sediment X X X X X X54SD17 5417SD00 0.0-1.9 Sediment X X X X X XQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 2 of 3 5/21/02TABLE 2-1SUMMARY OF PHASE I RI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMEParametersSampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix VOCs1 SVOCs2 Pest/PCB3Nitroaromatics /Nitramines4 Metals5 Nitrate/Nitrite6 Comments54SD18 5418SD00 0.0-2.0 Sediment X X X X X X04SP 0401SP00 - Spring X X X X X X04SP 0402SP00 - Spring X X X X X X34SP 3401SP00 - Spring X X X X X X34SP 3402SP00 - Spring X X X X X X35SP 3501SP00 - Spring X X X X X X35SP 3502SP00 - Spring X X X X X XNotes: Abbreviations:Samples were collected in 1996. bgs = below ground surfaceAll samples analyzed for chemical analysis were shipped EMAX Laboratory, Inc, of Torrance, California.1 TCL Volatile Organic Compounds: Preparation Method 5030 / Analysis Method 8260A. (original sample listed immediately above)2 ft = feet3 TCL Pesticides and PCBs: Preparation Methods 3520 (aqueous) and 3550 (soil/sediment) / Analysis Method 8080. MS/MSD = Matrix Spike/ Matrix Spike Duplicate4 Nitroaromatics/nitramines were prepared and analyzed as identified in Method 8330. NA = Not Applicable5 TAL Metals: Preparation Methods 3010/3020 (aqueous) and 3050B (soil) / Analysis Methods 6010/7000. SB = Soil Boring6 Nitrate/Nitrite was prepared and analyzed as identified in Method 300. SD = SedimentSW = Surface WaterTCL Semivolatile Organic Compounds: Preparation Methods 3520 (aqueous) and 3550 (soil/sediment) / Analysis Method 8270.Surface soil samples collected (from 0.0 to 2.0 ft bgs) during the Phase I RI use 02 for the depth indicator portion of the Sample Identification.Duplicate = Quality Control DuplicateQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 3 of 3 5/21/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMESampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix SVOCs1 Pests/PCBs2Nitroaromatics/Nitramines3 Metals4 pH5 Comments54SB02 5402SB00 0.0-0.5 Soil X X X X X54SB02 5402SB02 1.0-1.3 Soil X X X X X54SB03 5403SB00 0.0-0.5 Soil X X X X X54SB03 5403SB01 0.5-1.0 Soil X X X X X54SB03 5403SB04 2.0-4.0 Soil X X X X X54SB03 5403SB08 6.0-8.0 Soil X X X X X54SB04 5404SB00 0.0-0.5 Soil X X X X X54SB04 5404SB03 0.5-2.5 Soil X X X X X54SB04 5404SB07 6.0-6.8 Soil X X X X X54SB04 5404GW07 6.8 Groundwater X X X X X54SB05 5405SB00 0.0-0.5 Soil X X X X X54SB05 5405SB03 1.0-3.0 Soil X X X X X MS/MSD54SB05 5405SB06 4.0-6.0 Soil X X X X X54SB05 5405GW06 6.0 Groundwater X X X X X54SB06 5406SB00 0.0-0.5 Soil X X X X X54SB06 5406SB04 2.0-4.0 Soil X X X X X54SB06 5406SB06 4.0-5.8 Soil X X X X X54SW/SD19 5419SW00 - Surface Water X X X X X5419SW05 - Surface Water X X X X X Duplicate (5419SW00)5419SD00 0.0-0.5 Sediment X X X X X5419SD05 0.0-0.5 Sediment X X X X X Duplicate (5419SD00)54SD20 5420SD00 0.0-0.5 Sediment X X X X X54SD21 5421SD00 0.0-0.5 Sediment X X X X X54SW/SD22 5422SW00 - Surface Water X X X X X5422SD00 0.0-0.5 Sediment X X X X X54SW/SD23 5423SW00 - Surface Water X X X X X5423SD00 0.0-0.2 Sediment X X X X XParametersQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 1 of 3 5/21/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMESampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix SVOCs1 Pests/PCBs2Nitroaromatics/Nitramines3 Metals4 pH5 CommentsParameters54SW/SD24 5424SW00 - Surface Water X X X X X5424SD00 0.0-0.2 Sediment X X X X X54SD25 5425SD00 0.0-0.2 Sediment X X X X X54SD26 5426SD01 0.5-0.9 Sediment X X X X X54SW/SD27 5427SW00 - Surface Water X X X X X5427SD00 0.0-0.2 Sediment X X X X X5427SD05 0.0-0.2 Sediment X X X X X Duplicate (5427SD00)54SW/SD28 5428SW00 - Surface Water X X X X X5428SD00 0.0-0.2 Sediment X X X X X54SD29 5429SD00 0.0-0.2 Sediment X X X X X54SD30 5430SD00 0.0-0.2 Sediment X X X X X54SD31 5431SD00 0.0-0.2 Sediment X X X X X54SS20 5420SS00 0.0-1.0 Surface Soil X X X X X MS/MSD54SS21 5421SS00 0.0-1.0 Surface Soil X X X X X54SS22 5422SS00 0.0-1.0 Surface Soil X X X X X5422SS05 0.0-1.0 Surface Soil X X X X X Duplicate (5422SS00)04SP 0403SP00 - Spring X X X X X MS/MSD34SP 3403SP00 - Spring X X X X X35SP 3503SP00 - Spring X X X X X41SP 4101SP00 - Spring X X X X XQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 2 of 3 5/21/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 54 - P&E AREA FLUMESampleLocationSampleIdentificationSampleDepth (ft bgs)SampleMatrix SVOCs1 Pests/PCBs2Nitroaromatics/Nitramines3 Metals4 pH5 CommentsParametersNotes: Abbreviations:Samples were collected in 2000. bgs = below ground surface1234 SW = Surface Water5All samples analyzed for chemical analysis were shipped EMAX Laboratory, Inc, of Torrance,California.Surface soil samples collected (from 0.0 to 2.0 ft bgs) during the Phase II RFI use 00 for the depthindicator portion of the Sample Identification.TCL Semivolatile Organic Compounds: Preparation Methods 3520C (aqueous) and 3550B(soil/sediment) / Analysis Method 8270C.GW = GroundwaterMS/MSD = Matrix Spike/ Matrix Spike DuplicateSB = Soil BoringSD = SedimentSP = SpringSS = Surface SoilDS = Direct Push - SoilDuplicate = Quality Control DuplicateTCL Pesticides and PCBs: Preparation Methods 3520C (aqueous) and 3550B (soil/sediment) /Analysis Methods 8081A (Pesticides) and 8082 (PCBs).TAL Metals: Preparation Method 3010A (aqueous) and 3050B (soil) / Analysis MethodsNitroaromatics/nitramines were prepared and analyzed as identified in Method 8330.pH (EPA Method 150.1)(original sample identification in parentheses)ft = feetQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 3 of 3 5/21/02TABLE 2-3SUMMARY OF FIELD SCREENING RESULTS FOR SOILAND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEBoring Number Sample Depth (ft bgs) Concentration (ppm)154SB01 0.0-2.0 14.0-6.0 ND6.0-8.0 ND54SB02 0.0-0.5 NA1.0-1.3 NA54SB03 0.0-0.5 NA0.5-1.0 NA6.0-8.0 NA54SB04 2.0-4.0 NA0.0-0.5 NA0.5-2.5 NA6.0-6.8 NA2.0-4.0 NA54SB05 0.0-0.5 NA1.0-3.0 NA4.0-6.0 NA54SB06 0.0-0.5 NA4.0-5.8 NA54SD01 0.0-2.0 ND54SD02 0.0-0.9 ND54SD03 0.0-1.0 ND54SD04 0.0-0.8 ND54SD05 0.0-0.8 ND54SD06 0.0-0.6 ND54SD07 0.0-0.4 ND54SD08 0.0-1.7 ND54SD09 0.0-0.4 ND54SD10 0.0-0.5 ND54SD11 0.0-2.0 ND54SD12 0.0-0.2 ND54SD13 0.0-0.5 ND54SD14 0.0-0.2 ND54SD15 0.0-2.0 ND54SD16 0.0-0.5 NDQ:\4599\fl010d00\Site 54\Draft\Section 1-10\Tables_Rev1 Page 1 of 3 5/21/02TABLE 2-3SUMMARY OF FIELD SCREENING RESULTS FOR SOILAND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEBoring Number Sample Depth (ft bgs) Concentration (ppm)154SD17 0.0-1.9 ND54SD18 0.0.-2.0 ND54SD19 0.0-0.5 NA54SD20 0.0-0.5 NA54SD21 0.0-0.5 NA54SD23 0.0-0.2 NA54SD24 0.0-0.5 NA54SD25 0.0-0.5 NA54SD26 0.5-0.9 NA54SD27 0.0-0.2 NA54SD28 0.0-0.2 NA54SD29 0.0-0.2 NA54SS01 0.0-2.0 ND54SS02 0.0-2.0 ND54SS03 0.0-1.0 ND54SS04 0.0-1.0 ND54SS05 0.0-0.8 ND54SS06 0.0-2.0 ND54SS07 0.0-0.4 ND54SS08 0.0-0.8 ND54SS09 0.0-1.5 ND54SS10 0.0-1.5 ND54SS11 0.0-2.0 ND54SS12 0.0-2.0 ND54SS13 0.0-1.5 ND54SS14 0.0-2.0 ND54SS15 0.0-2.0 ND54SS16 0.0-1.8 NDQ:\4599\fl010d00\Site 54\Draft\Section 1-10\Tables_Rev1 Page 2 of 3 5/21/02TABLE 2-3SUMMARY OF FIELD SCREENING RESULTS FOR SOILAND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEBoring Number Sample Depth (ft bgs) Concentration (ppm)154SS17 0.0-2.0 ND54SS18 0.0-2.0 ND54SS19 0.0-2.0 ND54SS20 0.0-0.5 NA54SS22 0.0-0.5 NANotes:1 Measured response above background using a photoionization detectorAbbreviations:ft = Feetbgs = Below Ground Surfaceppm = Part Per MillionSS = Shallow Soil SampleSB = Soil BoringND = Not DetectedNA = Not Available Due to Insufficient Sample RecoveryQ:\4599\fl010d00\Site 54\Draft\Section 1-10\Tables_Rev1 Page 3 of 3 5/21/02Physical Investigation ResultsSECTIONTHREE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 3-13.1 TOPOGRAPHY AND SURFACE FEATURESThe topography through which the P&E Area Flume passes varies from relatively flat, grass-coveredareas with few or no trees to steep-sided, forested valleys with occasional areas of denseunderbrush. The topography surrounding Section I of the flume consists of grass-covered, flat togently sloping terrain. Sloped surfaces drain to the flume. The ground overlying Section II ismostly grass-covered and flat to gently sloping. Section III of the flume is surrounded byheavily forested ground and parallels the streambed in Jenny Lind Run. Surface water drains tothe streambed. Valley walls in this area of the Jenny Lind Run are relatively steep with smallbedrock outcrops occurring throughout. Total approximate relief within the Jenny Lind Run,along Section III of the flume, exceeds 80 feet.3.2 LOCAL SURFICIAL GEOLOGYThe local surficial geology of this site has been interpreted based on six soil borings, 22 shallowsoil samples, 31 sediment samples and field observations. Simplified boring logs are presentedon Figure 3-1. Elevations in feet above Mean Sea Level (MSL) in Figure 3-1 are based on theNorth America Vertical Datum of 1988.3.2.1 Flume Sections I and IIThe shallow stratigraphy in the area of the flume’s first two sections consists of clay fill andresidual soils over limestone bedrock. Fill material was encountered in Soil Boring 54SB01,completed next to the flume, near the junction of Sections I and II. This fill was described asmedium stiff to stiff, dry to moist, reddish-brown, plastic clay (USCS symbol CH) and loose,moist, clayey sand (USCS symbol SC) overlying bedrock.3.2.2 Flume Section IIISection III of the flume, which starts east of Building 235-6, lies within the Jenny Lind Run.Five soil borings were completed along this section. A boring log was not completed for boring54SB02 since refusal was encountered at less than two feet bgs.The soils directly beneath the flume typically consist of soft, moist, brown, low plastic silty clay(USCS symbol CL) fill or colluvium, underlain by medium stiff, moist, reddish-brown, low tomedium plastic, silty clay (USCS symbol CL) residual soil. Colluvium and residual soil directlybeneath and to the side of the flume ranged from less than 2 feet thick to about 7 feet thick andwas underlain by limestone bedrock. Nitrocellulose fines and propellant were found on theground surface in the area of Soil Borings 54SB03 and 54SB04, along the sides of the flume.3.3 SHALLOW HYDROGEOLOGY AND SURFACE WATER HYDROLOGYGroundwater was encountered in three of the soil borings (54SB03, 54SB04, and 54SB05) atapproximate depths ranging from 1.5 to 7.9 feet bgs. All three borings were located north of 14thPhysical Investigation ResultsSECTIONTHREE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 3-2Street. Surface water was observed flowing from caves and springs and into caves or swallets atseveral locations within the streambed of Jenny Lind Run and elsewhere along the flume.3.3.1 Flume Section IDuring field sampling activities, a sinkhole was observed directly beneath Section I of the flume.The sinkhole was observed approximately 300 feet south of 10th Street, southwest of Building233. A barbed wire fence surrounded it to restrict access. Water was leaking from the flumeinto the sinkhole. The sinkhole appeared to be approximately 12 to 15 feet deep with verticallimestone walls.3.3.2 Flume Section IIBecause the flume is underground for the length of Section II, neither surface water norgroundwater was observed in the area of Section II.3.3.3 Flume Section IIISection III begins at an open brick-lined junction box. This junction box receives process wasteand sewage treatment plant effluent which then emptied into the P & E Area flume. Water wasobserved flowing from Spring 4 in Jenny Lind Run downstream of the junction box. Water fromthis spring disappeared into a small cave opening about 30 feet downstream of the spring.Water was also observed flowing underneath the flume on the downstream side of a railroadembankment where the flume emerges to become an aboveground structure. This flowcompletely disappeared into the ground within about 100 feet of the flume’s emergence. Surfacewater runoff along the south side of the flume, below the point of this first disappearance, wasobserved disappearing into another swallet, approximately 400 feet north of where 14th Streetcrosses Jenny Lind Run and the flume, at the time of the Phase I RI sampling (1995-1996).Surface water was not observed in this area during the Phase II RFI investigation.3.4 JENNY LIND RUN SURFACE WATER AND SPRINGSSurface water disappeared into a 3-foot-diameter swallet after flowing through a culvert in JennyLind Run where it passes beneath 14th Street. The swallet is located about 50 feet south of 14thStreet. A lead-lined culvert measuring approximately 8-feet in diameter is located 30 feetdownstream of this swallet. This culvert was presumably lined with lead to prevent itsdissolution by acidic wastewater.Stream flow in Jenny Lind Run resumes on the downstream side of the lead-lined culvert afterrain events. Water from a spring (SP41) located to the east of the stream bank flows into thestreambed approximately 30 yards below the lead-lined culvert. All stream flow disappears intoa swallet approximately 20 yards below this spring. Flow resumes further downstream due tosurface water runoff and flow from several small springs located along the edges of the stream.There is generally no flow along this section of the streambed during dry conditions.Physical Investigation ResultsSECTIONTHREE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 3-3Several large and small springs feed Jenny Lind Run just north of Walnut Street, the next road tocross Jenny Lind Run south of 14th Street. Most of these springs appear to be ephemeral,although there is usually some stream flow in this portion of Jenny Lind Run year round.Springs SP34 and SP35 appear to flow continuously but at very limited volumes during dryconditions.A cave and several small swallets capture the entire stream flow in Jenny Lind Run,approximately 100 yards south of Walnut Street. In stream flow reappears from a cave in thestreambed of Jenny Lind Run, near the end of the flume.Many of the karst features within Jenny Lind Run were present at the time of the P&E Area’soperation. Any process wastewater discharged directly into Jenny Lind Run and any wastewaterthat may have leaked from the flume within Jenny Lind Run could have directly entered thesubsurface through these karst features.Data Quality Review and ValidationSECTIONFOUR P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 4-14.1 PHASE I RIAll chemical data were reviewed following procedures identified in the INAPP Site WideQuality Assurance Project Plan (W-C 1995c). No data were rejected. Reporting limits wereelevated due to soil moisture content, which ranged from 18 percent to 27 percent. See the PhaseI RI report, for a more detailed discussion of data review issues.4.2 PHASE II RFIAll chemical data were reviewed following procedures identified in the INAPP Site WideQuality Assurance Project Plan (URSGWC 2000b). Hexachlorocyclopentadiene results forsamples 54-19-SW-00, 54-22-SW-00, 54-23-SW-00 and 54-24-SW-00 were qualified rejected(R) based on quality control (QC) parameters outside evaluation criteria. Also 2,4-dinitrotolueneand calcium results for samples 54-20-SS-00 and 54-05-SB-03 and mercury for sample 54-05-SB-03 were rejected (R) due to QC parameters outside evaluation criteria. Select analytical datafor P&E Area Flume (Site 54) samples collected during the Phase II RFI were qualifiedestimated (J/UJ) based on LCS, surrogate, MS/MSD, laboratory duplicate and field duplicatedata outside evaluation criteria. Additionally, acetone and methylene chloride data for P&EArea Flume samples were qualified non-detect (U) based on the presence of the compounds inthe method blank samples or based on professional judgement (common laboratorycontaminants). A complete summary of the data reviews is presented in Appendix A.Acceptable levels of accuracy and precision were achieved for the Phase II RFI P&E Area Flumesample data. The analytical data collected for the P&E Area Flume samples were determined tobe acceptable for their intended use, including estimated data (J/UJ), with the exception of thehexachlorocyclopentadiene, 2,4-dinitrotoluene, calcium, and mercury results qualified rejected(R).Chemical Investigation ResultsSECTIONFIVE P&E Area Flume, Site 54Q:\4599\fl010d00\Site 54\Final\Sections 1-10\Sections 1-10 Text_Rev1.doc\21-May-02 /OMA 5-1All samples collected from the P&E Area Flume were analyzed for Target Compound List(TCL) semivolatile organic compound (SVOCs), pesticides/polychlorinated biphenyls (PCBs),nitroaromatic/nitramine compounds, Target Analyte List (TAL) metals, and cyanide. Thesamples collected as part of the Phase I RI were also analyzed for TCL VOCs and nitrate/nitrite.The samples collected as part of the Phase II RFI were also analyzed for pH. Field duplicatesamples collected from this site included:Field Duplicate Associated Sample5482SS02 5411SS025425SD00 5408SD005445SW00 5405SW005422SS05 5422SS005419SD05 5419SD005427SD05 5427SD005419SW05 5419SW00Field duplicate sample results are presented in Appendix H.Summaries of the chemical investigation results can be found as follows:· Surface and subsurface soil, sediment, surface water, and groundwater samplescollected from this site and the analyses each sample underwent are summarizedin Tables 2-1 and 2-2.· Chemicals detected, maximum concentration, and frequency of detects for soiland sediment samples collected from the P&E Area Flume are summarized inTable 5-1.· Chemicals detected, maximum concentration, and frequency of detects for surfacewater, spring, and groundwater samples collected from P&E Area Flume aresummarized in Table 5-2.· Appendix H contains all analytical results.TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD ID 5401SB02 5401SB06 5401SB08 5401SD00 5401SS02 5402SB00DATE COLLECTED February 15, 1996 February 15, 1996 February 15, 1996 February 22, 1996 February 21, 1996 January 10, 2001Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40 16 < 12 U 9 J 10 J 39Methylene Chloride 10 J 5 / 40 < 12 U < 12 U < 12 U < 13 U < 14 UToluene 42 J 13 / 40 < 12 U 1 J 1 J < 13 U < 14 USEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 71 < 400 U < 410 U < 400 U 1600 290 J < 460 U2,6-Dinitrotoluene 1300 4 / 71 < 400 U < 410 U < 400 U < 430 U < 480 U < 460 U2-Methylnaphthalene 120 J 4 / 71 < 400 U < 410 U < 400 U < 430 U 27 J < 460 U4-Methylphenol 60 J 1 / 71 < 400 U < 410 U < 400 U < 430 U < 480 U < 460 UAcenaphthene 2600 11 / 71 < 400 U < 410 U < 400 U < 430 U 78 J < 460 UAcenaphthylene 140 J 13 / 71 < 400 U < 410 U < 400 U < 430 U 65 J < 460 UAnthracene 650 J 22 / 71 < 400 U < 410 U < 400 U < 430 U 290 J < 460 UBenzo(a)anthracene 22000 J 35 / 71 25 J < 410 U 12 J < 430 U 960 1100 460Benzo(a)pyrene 16000 J 26 / 71 19 J < 410 U < 400 U < 430 U 560 880 460Benzo(b)Fluoranthene 42000 37 / 71 55 J < 410 U < 400 U < 430 U 1300 1800 460Benzo(g,h,i)perylene 11000 22 / 71 < 400 U < 410 U < 400 U < 430 U 300 J 390 460 JBenzo(k)Fluoranthene 15000 J 30 / 71 < 400 U < 410 U 8 J < 430 U 490 640 460Bis(2-ethylhexyl) phthalate 500 13 / 71 < 400 U < 410 U < 400 U 140 J < 480 U < 460 UButylbenzyl phthalate 570 12 / 71 < 400 U < 410 U 10 J < 430 U 14 J < 460 UCarbazole 3400 20 / 71 < 400 U < 410 U < 400 U < 430 U 180 J < 460 UChrysene 48000 34 / 71 20 J < 410 U < 400 U < 430 U 1400 1300 460Di-n-butyl phthalate 27000 43 / 71 430 < 410 U < 400 U 2000 1300 < 460 UDibenz(a,h)anthracene 860 J 4 / 71 < 400 U < 410 U < 400 U < 430 U < 480 U < 460 UDibenzofuran 1800 8 / 71 < 400 U < 410 U < 400 U < 430 U 98 J < 460 UFluoranthene 80000 J 38 / 71 45 J < 410 U < 400 U < 430 U 3700 1500 460Fluorene 2300 11 / 71 < 400 U < 410 U < 400 U < 430 U 220 J < 460 UIndeno(1,2,3-c,d)pyrene 12000 J 26 / 71 < 400 U < 410 U < 400 U < 430 U 280 J 500 460N-Nitrosodiphenylamine 13000 20 / 71 < 400 U < 410 U < 400 U 310 J 150 J < 460 UNaphthalene 1200 6 / 71 < 400 U < 410 U < 400 U < 430 U 24 J < 460 UNitrobenzene 42 J 1 / 71 < 400 U < 410 U < 400 U < 430 U < 480 U < 460 UPhenanthrene 29000 31 / 71 24 J < 410 U < 400 U < 430 U 2100 260 460 JQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 1 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD ID 5401SB02 5401SB06 5401SB08 5401SD00 5401SS02 5402SB00DATE COLLECTED February 15, 1996 February 15, 1996 February 15, 1996 February 22, 1996 February 21, 1996 January 10, 2001Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualPyrene 91000 J 37 / 71 39 J < 410 U < 400 U < 430 U 2500 1700 460PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 71 < 4 UJ < 4.1 U < 4 UJ < 4.3 U < 4.8 U < 5.5 U4,4-DDE 190 29 / 71 < 4 UJ < 4.1 U 0.43 J < 4.3 U < 4.8 U < 5.5 U4,4-DDT 650 J 36 / 71 < 4 UJ < 4.1 UJ < 4 UJ < 4.3 U 1.1 J 1.8 5.5 JAldrin 5.8 3 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U < 2.5 U < 5.5 Ualpha-Benzenehexachloride 0.9 J 5 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U < 2.5 UJ < 2.8 Ualpha-Chlordane 73 J 27 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U 0.57 J < 2.8 Ubeta-Hexachlorocyclohexane 36 J 6 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U < 2.5 UJ < 5.5 UDieldrin 77 J 25 / 71 < 4 UJ < 4.1 U < 4 UJ < 4.3 U < 4.8 U < 5.5 UEndosulfan I 200 J 4 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U < 2.5 U < 2.8 UEndosulfan II 35 J 27 / 71 < 4 UJ < 4.1 U < 4 UJ 2.5 J 4.9 < 5.5 UEndosulfan sulfate 200 J 9 / 71 < 4 UJ < 4.1 UJ < 4 UJ < 4.3 U < 4.8 U 2.6 5.5 JEndrin 170 J 25 / 71 < 4 UJ < 4.1 U < 4 UJ < 4.3 U < 4.8 UJ < 5.5 UEndrin aldehyde 120 J 20 / 71 < 4 UJ < 4.1 U < 4 UJ < 4.3 U < 4.8 U 4.3 5.5 JEndrin ketone 310 J 6 / 71 < 4 UJ < 4.1 U < 4 UJ < 4.3 U < 4.8 U < 5.5 Ugamma-Chlordane 530 J 15 / 71 < 2 UJ 0.35 J < 2.1 UJ < 2.2 U < 2.5 U < 2.8 UHeptachlor 14 J 6 / 71 < 2 UJ < 2.1 U < 2.1 UJ < 2.2 U < 2.5 U < 2.8 UHeptachlor epoxide 5.5 J 5 / 71 < 2 UJ 0.42 J < 2.1 UJ < 2.2 U < 2.5 U < 2.8 UMethoxychlor 1300 J 39 / 71 < 20 UJ < 21 UJ < 21 UJ 28 J < 25 U 20 28 JPOLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71 < 40 UJ < 41 U < 40 UJ < 43 U < 48 U < 55 UPCB 1260 1300 3 / 71 < 40 UJ < 41 U < 40 UJ < 43 U < 48 U < 55 UNITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 70 < 480 U < 492 U < 485 U < 525 U < 581 U 380 400 J2,6-Dinitrotoluene 1100 1 / 71 < 480 U < 492 U < 485 U < 525 U < 581 U < 400 U2-Nitrotoluene 160 J 1 / 71 < 480 U < 492 U < 485 U < 525 U < 581 U < 400 U3-Nitrotoluene 820 4 / 71 < 480 U < 492 U < 485 U < 525 U < 581 U < 400 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 2 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD ID 5401SB02 5401SB06 5401SB08 5401SD00 5401SS02 5402SB00DATE COLLECTED February 15, 1996 February 15, 1996 February 15, 1996 February 22, 1996 February 21, 1996 January 10, 2001Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual4-Nitrotoluene 810 2 / 71 < 480 U < 492 U < 485 U < 525 U < 581 U < 400 UTetryl 320 J 1 / 71 < 480 U < 492 U < 485 U < 525 U < 581 U < 400 UMETALS (mg/kg)Aluminum 31500 71 / 71 10300 15100 13700 7670 J 8190 10700 27.6Antimony 15.1 J 7 / 71 < 9.6 U < 9.8 U < 9.7 U < 10.5 UJ < 11.6 UJ 7.63 13.8 JArsenic 30.4 J 70 / 70 9.9 J 10.6 J 12.6 J 21.1 J 10.8 16.3 1.38Barium 1280 71 / 71 110 113 87 457 J 174 236 1.38Beryllium 1.79 70 / 71 0.79 J 0.91 J 0.73 J 1.7 0.94 J 1.56 1.38Cadmium 2.4 17 / 71 < 0.96 U < 0.98 U < 0.97 U 1.1 J < 1.2 U < 0.69 UCalcium 184000 70 / 70 19500 5320 9830 16000 29800 5460 138Chromium 91.5 71 / 71 19.5 18.4 16.8 46.8 14.1 91.5 1.38Cobalt 95 J 71 / 71 17.8 15.1 13.4 47 J 11.2 J 27.4 2.76Copper 149 71 / 71 15.3 20 20 18.3 19.9 18.3 2.76Iron 59400 71 / 71 22900 27600 22800 49400 21400 38800 27.6Lead 1140 71 / 71 41.5 J 21.5 J 19.3 J 99.2 42.7 40.6 1.38Magnesium 6710 71 / 71 1700 1880 3880 1170 J 1340 J 1110 138Manganese 16100 71 / 71 1850 1360 1010 6520 J 1010 3770 1.38Mercury 430 56 / 70 < 0.1 U < 0.1 U 0.45 1 0.67 0.276 0.138Nickel 96.6 71 / 71 17 18.5 17.6 35.4 16.6 41 2.76Potassium 2240 69 / 71 760 J 933 J 1010 J 421 J 686 J 658 690 JSelenium 2.5 13 / 71 < 1.2 U < 1.2 U < 1.2 U < 1.3 U < 1.5 U < 1.38 USilver 1.4 J 2 / 71 < 1.9 U < 2 U < 1.9 U < 2.1 UJ < 2.3 UJ < 1.38 USodium 2180 64 / 71 138 J 142 J 140 J 506 J < 145 U 37 138 JThallium 12.6 47 / 71 4.8 3.4 3.5 12.4 4.5 3.06 2.76Vanadium 73.9 71 / 71 30.2 35.2 31.1 51.8 22.8 41.9 1.38Zinc 721 71 / 71 87.3 52.3 54.6 117 76.8 83.1 2.76OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40 < 0.29 U < 0.3 U < 0.3 U < 0.32 U < 0.36 UNotes:ND = Not DetectedRL = Reporting LimitQual = QualifierQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 3 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD ID 5401SB02 5401SB06 5401SB08 5401SD00 5401SS02 5402SB00DATE COLLECTED February 15, 1996 February 15, 1996 February 15, 1996 February 22, 1996 February 21, 1996 January 10, 2001Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Q:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 4 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715402SB02 5402SD00 5402SS02 5403SB00 5403SB01 5403SB04January 10, 2001 February 22, 1996 February 21, 1996 January 12, 2001 January 12, 2001 January 12, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 13 U < 13 U< 13 U < 13 U< 13 U < 13 UJ< 430 U < 420 U < 430 U < 4400 U 230 410 J < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U 51 J < 4400 U 180 410 J < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U 24 J < 4400 U 440 410 < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U 24 J < 4400 U < 410 U < 400 U< 430 U 94 J < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U 270 410 J < 400 U< 430 U 1300 < 430 U < 4400 U 1900 410 < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U 52 J < 4400 U 370 410 J < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U 150 410 J < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 U< 430 U < 420 U < 430 U < 4400 U < 410 U < 400 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 5 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyPyrene 91000 J 37 / 71PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 714,4-DDE 190 29 / 714,4-DDT 650 J 36 / 71Aldrin 5.8 3 / 71alpha-Benzenehexachloride 0.9 J 5 / 71alpha-Chlordane 73 J 27 / 71beta-Hexachlorocyclohexane 36 J 6 / 71Dieldrin 77 J 25 / 71Endosulfan I 200 J 4 / 71Endosulfan II 35 J 27 / 71Endosulfan sulfate 200 J 9 / 71Endrin 170 J 25 / 71Endrin aldehyde 120 J 20 / 71Endrin ketone 310 J 6 / 71gamma-Chlordane 530 J 15 / 71Heptachlor 14 J 6 / 71Heptachlor epoxide 5.5 J 5 / 71Methoxychlor 1300 J 39 / 71POLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71PCB 1260 1300 3 / 71NITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 702,6-Dinitrotoluene 1100 1 / 712-Nitrotoluene 160 J 1 / 713-Nitrotoluene 820 4 / 715402SB02 5402SD00 5402SS02 5403SB00 5403SB01 5403SB04January 10, 2001 February 22, 1996 February 21, 1996 January 12, 2001 January 12, 2001 January 12, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 430 U < 420 U 42 J < 4400 U 280 410 J < 400 U< 5.3 U 0.52 J < 4.3 UJ 25 16 J < 5 U < 4.9 U< 5.3 U 0.59 J 0.55 J 11 16 J 3.8 5 J < 4.9 U< 5.3 U < 4.2 U < 4.3 UJ 74 16 16 5 < 4.9 U< 5.3 U < 2.2 U < 2.2 UJ < 16 U < 5 U < 4.9 U< 2.6 U < 2.2 U < 2.2 UJ < 7.9 U 0.71 2.5 J < 2.5 U< 2.6 U < 2.2 U < 2.2 UJ 6.6 7.9 J < 2.5 U < 2.5 U< 5.3 U < 2.2 U < 2.2 UJ < 16 U < 5 U < 4.9 U< 5.3 U 0.27 J 0.74 J 25 16 J 3.8 5 J < 4.9 U< 2.6 U < 2.2 U < 2.2 UJ < 7.9 U < 2.5 U < 2.5 U< 5.3 U < 4.2 U < 4.3 UJ 5.1 16 J < 5 U < 4.9 U< 5.3 U < 4.2 U < 4.3 UJ < 16 UJ < 5 U < 4.9 U< 5.3 U < 4.2 U < 4.3 UJ 5.5 16 J < 5 U < 4.9 U< 5.3 U < 4.2 U < 4.3 UJ 9.2 16 J 3.1 5 J < 4.9 U< 5.3 U < 4.2 U < 4.3 UJ < 16 U < 5 U < 4.9 U< 2.6 U < 2.2 U < 2.2 UJ < 7.9 U 1.6 2.5 J < 2.5 U< 2.6 U < 2.2 U < 2.2 UJ < 7.9 U < 2.5 U < 2.5 U< 2.6 U < 2.2 U < 2.2 UJ < 7.9 U < 2.5 U < 2.5 U< 26 U < 22 UJ < 22 UJ 120 79 J 15 25 J < 25 U< 53 U < 42 U < 43 UJ < 160 U < 50 U < 49 U< 53 U < 42 U < 43 UJ < 160 U < 50 U < 49 U160 400 J < 515 U < 519 U 530 400 3800 400 < 400 U< 400 U < 515 U < 519 U < 400 U < 400 U < 400 U< 400 U < 515 U < 519 U < 400 U < 400 U < 400 U< 400 U < 515 U < 519 U < 400 U < 400 U < 400 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 6 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum Frequency4-Nitrotoluene 810 2 / 71Tetryl 320 J 1 / 71METALS (mg/kg)Aluminum 31500 71 / 71Antimony 15.1 J 7 / 71Arsenic 30.4 J 70 / 70Barium 1280 71 / 71Beryllium 1.79 70 / 71Cadmium 2.4 17 / 71Calcium 184000 70 / 70Chromium 91.5 71 / 71Cobalt 95 J 71 / 71Copper 149 71 / 71Iron 59400 71 / 71Lead 1140 71 / 71Magnesium 6710 71 / 71Manganese 16100 71 / 71Mercury 430 56 / 70Nickel 96.6 71 / 71Potassium 2240 69 / 71Selenium 2.5 13 / 71Silver 1.4 J 2 / 71Sodium 2180 64 / 71Thallium 12.6 47 / 71Vanadium 73.9 71 / 71Zinc 721 71 / 71OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40Notes:ND = Not DetectedRL = Reporting LimitQual = Qualifier5402SB02 5402SD00 5402SS02 5403SB00 5403SB01 5403SB04January 10, 2001 February 22, 1996 February 21, 1996 January 12, 2001 January 12, 2001 January 12, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 400 U < 515 U < 519 U < 400 U < 400 U < 400 U< 400 U < 515 U < 519 U < 400 U < 400 U < 400 U17000 26.3 8440 J 6540 7310 26.4 12000 24.9 19800 24.5< 13.2 U < 10.3 UJ < 10.4 UJ < 13.2 U 4.65 12.4 J 5.95 12.3 J11.1 1.32 13 J 7.3 10.4 1.32 7.62 1.24 9.5 1.23171 1.32 240 J 134 67.2 1.32 74.3 1.24 91.7 1.230.93 1.32 J 1.3 0.75 J 0.444 1.32 J 0.703 1.24 J 0.583 1.23 J< 0.658 U 1.1 J < 1 U 0.83 0.66 < 0.622 U < 0.613 U4910 132 20600 1560 176000 132 21000 124 1850 12331.8 1.32 43.5 11 21.9 1.32 15.7 1.24 18.6 1.2315.5 2.63 27.5 J 11.2 J 7.7 2.64 4.14 2.49 10.9 2.4518.9 2.63 14.6 11.7 34.5 2.64 22.9 2.49 15.1 2.4524600 26.3 30600 13900 15000 26.4 20000 24.9 24500 24.521 1.32 47.2 15.4 398 1.32 104 1.24 18.2 1.231270 132 939 J 710 J 3380 132 1400 124 2110 1231670 1.32 4780 J 1630 1270 1.32 285 1.24 830 1.230.063 0.132 J < 0.11 U < 0.11 U 10.7 2.64 2.94 0.622 0.105 0.123 J20.6 2.63 24.7 15.5 18.4 2.64 14 2.49 16.5 2.451370 658 623 J 595 J 795 660 723 622 1290 613< 1.32 U < 1.3 U 1.4 < 1.32 U 0.868 1.24 J 0.597 1.23 J< 1.32 U < 2.1 UJ < 2.1 UJ < 1.32 U < 1.24 U 0.62 1.23 J59.9 132 J 1160 J < 130 U 90.9 132 J 55.2 124 J 47.3 123 J1.42 2.63 J 4.7 < 1.8 U 1.74 2.64 J < 2.49 U 0.715 2.45 J37.7 1.32 40.3 17.1 18 1.32 24.5 1.24 36 1.2380.9 2.63 60.6 49.8 207 2.64 91.6 2.49 67.2 2.45< 0.31 UJ < 0.32 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 7 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.5402SB02 5402SD00 5402SS02 5403SB00 5403SB01 5403SB04January 10, 2001 February 22, 1996 February 21, 1996 January 12, 2001 January 12, 2001 January 12, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 8 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715403SB08 5403SD00 5403SS02 5404SB00 5404SB03 5404SB07January 12, 2001 February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual23 13< 14 U < 13 U< 14 U 6 J< 400 U < 460 U 1400 < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U 18 J < 5000 U < 880 U < 440 U< 400 U < 460 U 50 J < 5000 U < 880 U < 440 U< 400 U < 460 U 190 J < 5000 U < 880 U < 440 U< 400 U < 460 U 770 < 5000 U < 880 U < 440 U< 400 U < 460 U 430 J < 5000 U < 880 U < 440 U< 400 U < 460 U 1200 < 5000 U < 880 U < 440 U< 400 U < 460 U 290 J < 5000 U < 880 U < 440 U< 400 U < 460 U 430 < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U 20 J < 5000 U < 880 U < 440 U< 400 U < 460 U 110 J < 5000 U < 880 U < 440 U< 400 U < 460 U 860 < 5000 U < 880 U < 440 U< 400 U 160 J 3600 7100 5000 3700 880 < 440 U< 400 U < 460 U 43 J < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U 1700 < 5000 U < 880 U < 440 U< 400 U < 460 U 21 J < 5000 U < 880 U < 440 U< 400 U < 460 U 230 J < 5000 U < 880 U < 440 U< 400 U < 460 U 270 J < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U < 430 U < 5000 U < 880 U < 440 U< 400 U < 460 U 580 < 5000 U < 880 U < 440 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 9 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyPyrene 91000 J 37 / 71PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 714,4-DDE 190 29 / 714,4-DDT 650 J 36 / 71Aldrin 5.8 3 / 71alpha-Benzenehexachloride 0.9 J 5 / 71alpha-Chlordane 73 J 27 / 71beta-Hexachlorocyclohexane 36 J 6 / 71Dieldrin 77 J 25 / 71Endosulfan I 200 J 4 / 71Endosulfan II 35 J 27 / 71Endosulfan sulfate 200 J 9 / 71Endrin 170 J 25 / 71Endrin aldehyde 120 J 20 / 71Endrin ketone 310 J 6 / 71gamma-Chlordane 530 J 15 / 71Heptachlor 14 J 6 / 71Heptachlor epoxide 5.5 J 5 / 71Methoxychlor 1300 J 39 / 71POLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71PCB 1260 1300 3 / 71NITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 702,6-Dinitrotoluene 1100 1 / 712-Nitrotoluene 160 J 1 / 713-Nitrotoluene 820 4 / 715403SB08 5403SD00 5403SS02 5404SB00 5404SB03 5404SB07January 12, 2001 February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 400 U < 460 U 1200 < 5000 U < 880 U < 440 U< 4.9 U < 4.6 U < 4.3 U 30 60 J 3.8 5.3 J < 5.3 U< 4.9 U < 4.6 U 2 J 43 60 J 7.4 5.3 < 5.3 U< 4.9 U 0.64 J 5 J < 60 U < 5.3 U < 5.3 U< 4.9 U < 2.4 U < 2.2 U < 60 U < 5.3 U < 5.3 U< 2.4 U < 2.4 U 0.6 J < 30 U 0.86 2.7 J < 2.7 U< 2.4 U < 2.4 U 0.69 J < 30 U < 2.7 U < 2.7 U< 4.9 U 1.6 J < 2.2 UJ 36 60 J 4.6 5.3 J < 5.3 U< 4.9 U < 4.6 U 1.3 J 51 60 J 5.3 5.3 < 5.3 U< 2.4 U < 2.4 U < 2.2 U < 30 U < 2.7 U < 2.7 U< 4.9 U < 4.6 U 6 J 28 60 J 4.3 5.3 J < 5.3 U< 4.9 U < 4.6 U < 4.3 U < 60 U < 5.3 U < 5.3 U< 4.9 U < 4.6 U < 4.3 UJ 54 60 J 3.7 5.3 J < 5.3 U< 4.9 U < 4.6 U < 4.3 U 16 60 J 8.6 5.3 < 5.3 U< 4.9 U < 4.6 U < 4.3 U < 60 U < 5.3 U < 5.3 U< 2.4 U < 2.4 U < 2.2 U 23 30 J 3.8 2.7 < 2.7 U< 2.4 U < 2.4 U < 2.2 U < 30 U 2.6 2.7 J < 2.7 U< 2.4 U < 2.4 U < 2.2 U < 30 U < 2.7 U < 2.7 U< 24 U < 24 UJ < 22 U 210 300 J 13 27 J < 27 U< 49 U < 46 U < 43 U < 600 U < 53 U < 53 U< 49 U < 46 U < 43 U < 600 U < 53 U < 53 U< 400 U < 562 U 620 140 400 J 590 400 < 400 U< 400 U < 562 U < 521 U < 400 U < 400 U < 400 U< 400 U < 562 U < 521 U < 400 U < 400 U < 400 U< 400 U < 562 U < 521 U < 400 U < 400 U < 400 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 10 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum Frequency4-Nitrotoluene 810 2 / 71Tetryl 320 J 1 / 71METALS (mg/kg)Aluminum 31500 71 / 71Antimony 15.1 J 7 / 71Arsenic 30.4 J 70 / 70Barium 1280 71 / 71Beryllium 1.79 70 / 71Cadmium 2.4 17 / 71Calcium 184000 70 / 70Chromium 91.5 71 / 71Cobalt 95 J 71 / 71Copper 149 71 / 71Iron 59400 71 / 71Lead 1140 71 / 71Magnesium 6710 71 / 71Manganese 16100 71 / 71Mercury 430 56 / 70Nickel 96.6 71 / 71Potassium 2240 69 / 71Selenium 2.5 13 / 71Silver 1.4 J 2 / 71Sodium 2180 64 / 71Thallium 12.6 47 / 71Vanadium 73.9 71 / 71Zinc 721 71 / 71OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40Notes:ND = Not DetectedRL = Reporting LimitQual = Qualifier5403SB08 5403SD00 5403SS02 5404SB00 5404SB03 5404SB07January 12, 2001 February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 400 U < 562 U < 521 U < 400 U < 400 U < 400 U< 400 U < 562 U < 521 U < 400 U < 400 U < 400 U19900 24.3 8120 J 13900 14300 30.1 17200 26.6 20100 26.65.02 12.1 J < 11.2 UJ < 10.4 UJ < 15 U < 13.3 U < 13.3 U11.9 1.21 8.7 J 12.4 9.24 1.5 10.9 1.33 17.3 1.3387 1.21 138 J 274 147 1.5 113 1.33 1280 1.331.39 1.21 0.83 J 1.2 J 0.797 1.5 J 0.847 1.33 J 1.37 1.33< 0.607 U < 1.1 U < 1 U < 0.752 U < 0.664 U 1.27 0.6642400 121 3120 19700 36900 150 51300 133 4200 13336.7 1.21 13.1 27.1 26.1 1.5 31.8 1.33 34.2 1.3313.1 2.43 9.8 J 18.6 13.3 3.01 9.19 2.66 34.6 2.6621.6 2.43 12.8 27.8 47.1 3.01 27.9 2.66 24.5 2.6626800 24.3 17400 32200 20800 30.1 24200 26.6 36500 26.629.5 1.21 21.5 49.2 363 1.5 654 1.33 30 1.331380 121 993 J 2870 3210 150 2480 133 1720 133915 1.21 1640 J 3390 2150 1.5 892 1.33 16100 13.30.248 0.121 < 0.12 U 0.74 47.7 7.52 1.42 0.133 0.102 0.133 J37.7 2.43 15.2 36 26.1 3.01 18.9 2.66 80.1 2.66982 607 746 J 1140 J 919 752 926 664 1480 6640.532 1.21 J < 1.4 U < 1.3 U < 1.5 U < 1.33 U < 1.33 U< 1.21 U < 2.2 UJ < 2.1 UJ < 1.5 U < 1.33 U < 1.33 U45.3 121 J 703 J < 130 U 67.4 150 J 62.9 133 J 61.2 133 J0.742 2.43 J 2.3 J 7.1 < 3.01 U < 2.66 U < 2.66 U36.4 1.21 21.3 39.7 27 1.5 30.6 1.33 44.4 1.3398.2 2.43 55.6 123 267 3.01 138 2.66 176 2.66< 0.34 UJ < 0.32 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 11 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.5403SB08 5403SD00 5403SS02 5404SB00 5404SB03 5404SB07January 12, 2001 February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 12 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715404SD00 5404SS02 5405SB00 5405SB03 5405SB06 5405SD00February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual10 J 22 17< 13 U < 14 U < 13 U< 13 U 3 J < 13 U< 430 U 190 J 6800 9100 J 17000 4500 < 430 U < 420 U< 430 U < 440 U < 9100 U 1300 450 < 430 U < 420 U< 430 U < 440 U < 9100 U < 450 U < 430 U < 420 U< 430 U < 440 U < 9100 U < 450 U < 430 U < 420 U< 430 U 110 J < 9100 U < 450 U < 430 U < 420 U< 430 U 37 J < 9100 U < 450 U < 430 U < 420 U110 J 310 J < 9100 U < 450 U < 430 U < 420 U630 1800 < 9100 U < 450 U < 430 U < 420 U590 900 < 9100 U < 450 U < 430 U < 420 U950 1800 < 9100 U 310 450 J < 430 U < 420 U370 J 400 J < 9100 U < 450 U < 430 U < 420 U320 J 870 < 9100 U < 450 U < 430 U < 420 U82 J < 440 U < 9100 U < 450 U < 430 U < 420 U< 430 U 23 J < 9100 U < 450 U < 430 U < 420 U< 430 U 180 J < 9100 U < 450 U < 430 U < 420 U780 2100 < 9100 U 270 450 J < 430 U < 420 U530 410 J 20000 9100 27000 4500 290 430 J 150 J140 J < 440 U < 9100 U < 450 U < 430 U < 420 U< 430 U 74 J < 9100 U < 450 U < 430 U < 420 U680 4000 < 9100 U 420 450 J < 430 U < 420 U< 430 U 190 J < 9100 U < 450 U < 430 U < 420 U330 J 390 J < 9100 U < 450 U < 430 U < 420 U< 430 U < 440 U < 9100 U 2700 450 < 430 U < 420 U< 430 U < 440 U < 9100 U < 450 U < 430 U < 420 U< 430 U < 440 U < 9100 U < 450 U < 430 U < 420 U100 J 2300 < 9100 U < 450 U < 430 U < 420 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 13 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyPyrene 91000 J 37 / 71PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 714,4-DDE 190 29 / 714,4-DDT 650 J 36 / 71Aldrin 5.8 3 / 71alpha-Benzenehexachloride 0.9 J 5 / 71alpha-Chlordane 73 J 27 / 71beta-Hexachlorocyclohexane 36 J 6 / 71Dieldrin 77 J 25 / 71Endosulfan I 200 J 4 / 71Endosulfan II 35 J 27 / 71Endosulfan sulfate 200 J 9 / 71Endrin 170 J 25 / 71Endrin aldehyde 120 J 20 / 71Endrin ketone 310 J 6 / 71gamma-Chlordane 530 J 15 / 71Heptachlor 14 J 6 / 71Heptachlor epoxide 5.5 J 5 / 71Methoxychlor 1300 J 39 / 71POLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71PCB 1260 1300 3 / 71NITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 702,6-Dinitrotoluene 1100 1 / 712-Nitrotoluene 160 J 1 / 713-Nitrotoluene 820 4 / 715404SD00 5404SS02 5405SB00 5405SB03 5405SB06 5405SD00February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual620 2900 < 9100 U 300 450 J < 430 U < 420 U< 4.3 U < 4.5 U 55 55 14 5.4 J < 5.2 U < 4.2 U< 4.3 U 0.91 J 55 55 37 5.4 J < 5.2 U 0.38 J3.2 J 2.1 J 210 55 J < 5.4 UJ < 5.2 U < 4.2 U< 2.2 U < 2.3 U < 55 U < 5.4 UJ < 5.2 U < 2.2 U< 2.2 U < 2.3 UJ < 27 U < 2.7 UJ < 2.6 U < 2.2 U< 2.2 U 0.54 J < 27 U 27 2.7 J < 2.6 U < 2.2 U< 2.2 U < 2.3 UJ < 55 U 2.8 5.4 J < 5.2 U < 2.2 U< 4.3 U 0.86 J 36 55 J 3.5 5.4 J < 5.2 U < 4.2 U< 2.2 U < 2.3 U < 27 U < 2.7 UJ < 2.6 U < 2.2 U6.7 < 4.5 U < 55 U < 5.4 UJ < 5.2 U < 4.2 U< 4.3 U < 4.5 U < 55 U < 5.4 UJ < 5.2 U < 4.2 U6.9 < 4.5 UJ < 55 U 20 5.4 J < 5.2 U < 4.2 U< 4.3 U < 4.5 U 49 55 J 3.4 5.4 J < 5.2 U < 4.2 U< 4.3 U < 4.5 U < 55 U < 5.4 UJ < 5.2 U < 4.2 U< 2.2 U < 2.3 U 24 27 J < 2.7 UJ < 2.6 U < 2.2 U< 2.2 U < 2.3 U < 27 U 1 2.7 J < 2.6 U < 2.2 U< 2.2 U < 2.3 U < 27 U 5.5 2.7 J < 2.6 U < 2.2 U74 J 50 110 270 J 21 27 J < 26 U < 22 UJ< 43 U < 45 U < 550 U < 54 UJ < 52 U < 42 U< 43 U < 45 U < 550 U < 54 UJ < 52 U < 42 U< 526 U < 538 U 2000 400 5300 400 < 400 U < 512 U< 526 U < 538 U 1100 400 < 400 U < 400 U < 512 U< 526 U < 538 U < 400 U < 400 U < 400 U < 512 U< 526 U < 538 U < 400 U < 400 U < 400 U < 512 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 14 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum Frequency4-Nitrotoluene 810 2 / 71Tetryl 320 J 1 / 71METALS (mg/kg)Aluminum 31500 71 / 71Antimony 15.1 J 7 / 71Arsenic 30.4 J 70 / 70Barium 1280 71 / 71Beryllium 1.79 70 / 71Cadmium 2.4 17 / 71Calcium 184000 70 / 70Chromium 91.5 71 / 71Cobalt 95 J 71 / 71Copper 149 71 / 71Iron 59400 71 / 71Lead 1140 71 / 71Magnesium 6710 71 / 71Manganese 16100 71 / 71Mercury 430 56 / 70Nickel 96.6 71 / 71Potassium 2240 69 / 71Selenium 2.5 13 / 71Silver 1.4 J 2 / 71Sodium 2180 64 / 71Thallium 12.6 47 / 71Vanadium 73.9 71 / 71Zinc 721 71 / 71OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40Notes:ND = Not DetectedRL = Reporting LimitQual = Qualifier5404SD00 5404SS02 5405SB00 5405SB03 5405SB06 5405SD00February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 526 U < 538 U < 400 U < 400 U < 400 U < 512 U< 526 U < 538 U < 400 U < 400 U < 400 U < 512 U8360 J 6370 13300 27.5 16700 27.2 20900 26.2 9450 J< 10.5 UJ 15.1 J < 13.7 U < 13.6 U < 13.1 U < 10.2 UJ24.7 J 9.3 11.2 1.37 14 1.36 7.17 1.31 19.5 J197 J 346 178 1.37 198 1.36 J 193 1.31 285 J1.6 0.81 J 0.793 1.37 J 1.28 1.36 J 0.956 1.31 J 1.31.1 J < 1.1 U < 0.687 U < 0.679 U < 0.656 U < 1 U6500 7350 43900 137 R 2380 131 511052.5 16.4 35.4 1.37 36.7 1.36 19.9 1.31 43.926.3 J 12.7 J 12.6 2.75 21.7 2.72 J 10.5 2.62 27.7 J22.2 15 44.1 2.75 29.7 2.72 13.3 2.62 16.149200 17000 24700 27.5 32100 27.2 19100 26.2 3470072.2 59.1 619 1.37 185 1.36 J 19 1.31 51.9925 J 883 J 3080 137 1380 136 1830 131 841 J3110 J 2790 2010 1.37 2260 1.36 J 1120 1.31 5390 J0.33 0.33 42 13.7 R 0.148 0.131 0.1926.8 16.2 24.5 2.75 26.2 2.72 18.7 2.62 25.2570 J 616 J 988 687 845 679 1690 656 644 J< 1.3 U < 1.3 U < 1.37 U < 1.36 U < 1.31 U < 1.3 U< 2.1 UJ < 2.2 UJ < 1.37 U < 1.36 U < 1.31 U < 2 UJ607 J < 134 U 80.4 137 J 64.3 136 J 75.2 131 J 578 J10.2 3 < 2.75 U < 2.72 U < 2.62 U 852 19 32.1 1.37 40.4 1.36 34.4 1.31 41.6124 73.7 250 2.75 166 2.72 58.9 2.62 72.70.62 J < 0.33 U < 0.32 UJQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 15 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.5404SD00 5404SS02 5405SB00 5405SB03 5405SB06 5405SD00February 22, 1996 February 21, 1996 January 14, 2001 January 14, 2001 January 14, 2001 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 16 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715405SS02 5406SB00 5406SB04 5406SB06 5406SD00 5406SS02February 21, 1996 January 16, 2001 January 16, 2001 January 16, 2001 February 23, 1996 February 21, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual17 66 29< 13 U < 13 U 3 J< 13 U < 13 U 1 J64 J < 450 U < 410 U < 430 U 8300 J < 430 U< 420 U < 450 U < 410 U < 430 U 560 < 430 U< 420 U < 450 U < 410 U < 430 U 68 J < 430 U< 420 U < 450 U < 410 U < 430 U 60 J < 430 U34 J < 450 U < 410 U < 430 U 17 J < 430 U61 J < 450 U < 410 U < 430 U 23 J 19 J320 J < 450 U < 410 U < 430 U 73 J 45 J1500 < 450 U < 410 U < 430 U 810 310 J750 < 450 U < 410 U < 430 U 430 250 J1700 < 450 U < 410 U < 430 U 770 610370 J < 450 U < 410 U < 430 U 200 160 J730 < 450 U < 410 U < 430 U 400 J 200 J< 420 U < 450 U < 410 U < 430 U < 420 U < 430 U12 J < 450 U < 410 U < 430 U 570 13 J180 J < 450 U < 410 U < 430 U 85 J 28 J1800 < 450 U < 410 U < 430 U 590 J 410 J510 520 450 4500 410 < 430 U 5100 < 430 U< 420 U < 450 U < 410 U < 430 U < 420 U < 430 U15 J < 450 U < 410 U < 430 U < 420 U < 430 U2700 < 450 U < 410 U < 430 U 1200 53056 J < 450 U < 410 U < 430 U 27 J < 430 U360 J < 450 U < 410 U < 430 U 210 J 170 J22 J < 450 U < 410 U < 430 U 1300 < 430 U< 420 U < 450 U < 410 U < 430 U 41 J < 430 U< 420 U < 450 U < 410 U < 430 U 42 J < 430 U930 < 450 U < 410 U < 430 U 360 J 92 JQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 17 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyPyrene 91000 J 37 / 71PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 714,4-DDE 190 29 / 714,4-DDT 650 J 36 / 71Aldrin 5.8 3 / 71alpha-Benzenehexachloride 0.9 J 5 / 71alpha-Chlordane 73 J 27 / 71beta-Hexachlorocyclohexane 36 J 6 / 71Dieldrin 77 J 25 / 71Endosulfan I 200 J 4 / 71Endosulfan II 35 J 27 / 71Endosulfan sulfate 200 J 9 / 71Endrin 170 J 25 / 71Endrin aldehyde 120 J 20 / 71Endrin ketone 310 J 6 / 71gamma-Chlordane 530 J 15 / 71Heptachlor 14 J 6 / 71Heptachlor epoxide 5.5 J 5 / 71Methoxychlor 1300 J 39 / 71POLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71PCB 1260 1300 3 / 71NITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 702,6-Dinitrotoluene 1100 1 / 712-Nitrotoluene 160 J 1 / 713-Nitrotoluene 820 4 / 715405SS02 5406SB00 5406SB04 5406SB06 5406SD00 5406SS02February 21, 1996 January 16, 2001 January 16, 2001 January 16, 2001 February 23, 1996 February 21, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual2200 < 450 U < 410 U < 430 U 990 430< 4.2 U < 5.5 UJ < 5 U < 5.3 U < 4.2 U < 4.3 U< 4.2 U 20 5.5 J 5.6 5 < 5.3 U < 4.2 U < 4.3 U17 J 19 5.5 J 41 5 < 5.3 U 1.4 J 1.4 J< 2.2 U < 5.5 UJ < 5 U < 5.3 U < 2.2 U < 2.2 U< 2.2 UJ < 2.7 UJ < 2.5 U < 2.6 U < 2.2 U < 2.2 UJ2 J 7.5 2.7 J < 2.5 U < 2.6 U 0.42 J 0.69 J< 2.2 UJ 1.2 5.5 J < 5 U < 5.3 U < 2.2 U < 2.2 UJ2.4 J 3.3 5.5 J 12 5 < 5.3 U < 4.2 U < 4.3 U< 2.2 U < 2.7 UJ < 2.5 U < 2.6 U < 2.2 U < 2.2 U< 4.2 U 5.2 5.5 J 0.75 5 J < 5.3 U 2.6 J < 4.3 U< 4.2 U < 5.5 UJ 1.6 5 J < 5.3 U 9 < 4.3 U< 4.2 UJ < 5.5 UJ < 5 U < 5.3 U 3.3 J < 4.3 UJ< 4.2 U 8.9 5.5 J 4.6 5 J < 5.3 U < 4.2 U < 4.3 U< 4.2 U 13 5.5 J < 5 U < 5.3 U < 4.2 U < 4.3 U< 2.2 U 7.6 2.7 J 6.7 2.5 < 2.6 U < 2.2 U < 2.2 U< 2.2 U < 2.7 UJ < 2.5 U < 2.6 U < 2.2 U < 2.2 U< 2.2 U < 2.7 UJ 1.6 2.5 J < 2.6 U < 2.2 U < 2.2 U370 J 13.6 27 J < 25 U < 26 U 31 28 J< 42 U 160 55 < 50 U < 53 U < 42 U < 43 U< 42 U 97 55 240 50 < 53 U < 42 U < 43 U< 508 U 460 400 < 400 U 340 400 J < 512 U < 517 U< 508 U < 400 U < 400 U < 400 U < 512 U < 517 U< 508 U < 400 U < 400 U < 400 U < 512 U < 517 U< 508 U < 400 U < 400 U < 400 U < 512 U < 517 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 18 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum Frequency4-Nitrotoluene 810 2 / 71Tetryl 320 J 1 / 71METALS (mg/kg)Aluminum 31500 71 / 71Antimony 15.1 J 7 / 71Arsenic 30.4 J 70 / 70Barium 1280 71 / 71Beryllium 1.79 70 / 71Cadmium 2.4 17 / 71Calcium 184000 70 / 70Chromium 91.5 71 / 71Cobalt 95 J 71 / 71Copper 149 71 / 71Iron 59400 71 / 71Lead 1140 71 / 71Magnesium 6710 71 / 71Manganese 16100 71 / 71Mercury 430 56 / 70Nickel 96.6 71 / 71Potassium 2240 69 / 71Selenium 2.5 13 / 71Silver 1.4 J 2 / 71Sodium 2180 64 / 71Thallium 12.6 47 / 71Vanadium 73.9 71 / 71Zinc 721 71 / 71OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40Notes:ND = Not DetectedRL = Reporting LimitQual = Qualifier5405SS02 5406SB00 5406SB04 5406SB06 5406SD00 5406SS02February 21, 1996 January 16, 2001 January 16, 2001 January 16, 2001 February 23, 1996 February 21, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 508 U < 400 U < 400 U < 400 U < 512 U < 517 U< 508 U < 400 U < 400 U < 400 U < 512 U < 517 U9010 4270 27.4 24800 24.9 31500 26.3 5740 8440< 10.2 UJ < 13.7 U < 12.5 U < 13.2 U < 10.2 UJ < 10.3 UJ10.3 9.7 1.37 13.7 1.25 30.3 1.32 17.7 8.1222 102 1.37 106 1.25 106 1.32 243 1710.94 J 0.136 1.37 J 0.968 1.25 J 1.79 1.32 1.2 J 0.84 J< 1 U < 0.686 U < 0.623 U < 0.658 U < 1 U < 1 U4870 472 137 986 125 3770 132 8420 311011.9 7.29 1.37 21 1.25 34.4 1.32 47.6 12.319.2 1.3 2.74 J 29.3 2.49 11.5 2.63 23.4 1318.3 9.6 2.74 27.1 2.49 77.6 2.63 11.8 15.419700 16400 27.4 30000 24.9 59400 26.3 38100 1750041.6 120 1.37 32.6 1.25 36.1 1.32 51.6 20.91130 J 267 137 1140 125 1690 132 760 J 1090 J3270 69.8 1.37 1680 1.25 767 1.32 3050 19400.25 0.875 0.137 < 0.125 U 0.252 0.132 0.17 < 0.11 U19.8 4.67 2.74 27.6 2.49 96.6 2.63 19.6 17.4883 J 1040 686 1400 623 2240 658 309 J 946 J< 1.3 U < 1.37 U < 1.25 U < 1.32 U < 1.3 U < 1.3 U< 2 UJ < 1.37 U < 1.25 U < 1.32 U < 2 UJ < 2.1 UJ< 127 U < 137 U 34.2 125 J 50.8 132 J 376 J < 129 U2.2 J < 2.74 U < 2.49 U 1.83 2.63 J 3.8 3.323.7 25.8 1.37 44.1 1.25 73.9 1.32 42.4 2173.6 32.7 2.74 88.7 2.49 112 2.63 81.7 68.5< 0.31 U 0.8 J < 0.31 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 19 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.5405SS02 5406SB00 5406SB04 5406SB06 5406SD00 5406SS02February 21, 1996 January 16, 2001 January 16, 2001 January 16, 2001 February 23, 1996 February 21, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 20 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715407SD00 5407SS02 5408SD00 5408SS02 5409SD00 5409SS02February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual13 J 11 J 48 < 13 U 14 J 15< 14 U < 13 U < 13 U < 13 U < 14 U < 12 U< 14 U < 13 U < 13 U 4 J < 14 U 8 J< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U 63 J < 420 U < 470 U < 410 U< 450 U < 440 U 100 J 170 J 35 J < 410 U< 450 U 230 J 600 820 200 J < 410 U< 450 U < 440 U 380 J 360 J 46 J < 410 U< 450 U 330 J 540 740 220 J 75 J< 450 U < 440 U 250 J < 420 U < 470 U < 410 U< 450 U 88 J 340 J 260 J < 470 U 26 J< 450 U 91 J < 420 U 84 J < 470 U < 410 U< 450 U < 440 U 12 J < 420 U < 470 U < 410 U< 450 U < 440 U 44 J 84 J < 470 U < 410 U< 450 U 240 J 420 790 170 J < 410 U< 860 U 180 J < 420 U 1800 3000 160 J< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U 330 J 1000 1500 330 J < 410 U< 450 U < 440 U 20 J < 420 U < 470 U < 410 U< 450 U < 440 U 220 J 160 J < 470 U < 410 U< 450 U < 440 U 30 J < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U < 420 U < 420 U < 470 U < 410 U< 450 U < 440 U 400 J 650 160 J < 410 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 21 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyPyrene 91000 J 37 / 71PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 270 J 16 / 714,4-DDE 190 29 / 714,4-DDT 650 J 36 / 71Aldrin 5.8 3 / 71alpha-Benzenehexachloride 0.9 J 5 / 71alpha-Chlordane 73 J 27 / 71beta-Hexachlorocyclohexane 36 J 6 / 71Dieldrin 77 J 25 / 71Endosulfan I 200 J 4 / 71Endosulfan II 35 J 27 / 71Endosulfan sulfate 200 J 9 / 71Endrin 170 J 25 / 71Endrin aldehyde 120 J 20 / 71Endrin ketone 310 J 6 / 71gamma-Chlordane 530 J 15 / 71Heptachlor 14 J 6 / 71Heptachlor epoxide 5.5 J 5 / 71Methoxychlor 1300 J 39 / 71POLYCHLORINATEDBIPHENYLS (PCB) (μg/kg)PCB 1254 1300 2 / 71PCB 1260 1300 3 / 71NITROAROMATICS /NITRAMINES (μg/kg)2,4-Dinitrotoluene 5300 26 / 702,6-Dinitrotoluene 1100 1 / 712-Nitrotoluene 160 J 1 / 713-Nitrotoluene 820 4 / 715407SD00 5407SS02 5408SD00 5408SS02 5409SD00 5409SS02February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 450 U 300 J 870 1200 260 J < 410 U< 4.5 U < 4.4 U < 4.2 U < 4.2 U 0.58 J < 4.1 U< 4.5 U < 4.4 U < 4.2 U < 4.2 U 0.76 J < 4.1 U< 4.5 U < 4.4 U 1.3 J 0.8 J 1.2 J < 4.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U1.6 J 0.55 J 0.49 J < 2.2 U < 2.4 U < 2.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 4.5 U 0.61 J < 4.2 U < 4.2 U < 4.7 U < 4.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 4.5 U < 4.4 U < 4.2 U < 4.2 U < 4.7 U 3.3 J< 4.5 U < 4.4 U < 4.2 U < 4.2 U < 4.7 U < 4.1 U< 4.5 U < 4.4 U 7.9 3.7 J < 4.7 U 5.4 J< 4.5 U < 4.4 U < 4.2 U < 4.2 U < 4.7 U < 4.1 U< 4.5 U < 4.4 U < 4.2 U < 4.2 U < 4.7 U < 4.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 2.3 U < 2.3 U < 2.2 U < 2.2 U < 2.4 U < 2.1 U< 23 U 68 J 45 13 J < 24 U 40 J< 45 U < 44 U < 42 U < 42 U < 47 U < 41 U< 45 U < 44 U < 42 U < 42 U < 47 U < 41 U< 550 U < 535 U 820 < 504 U < 571 U < 501 U< 550 U < 535 U < 504 U < 504 U < 571 U < 501 U< 550 U < 535 U < 504 U < 504 U < 571 U < 501 U< 550 U < 535 U < 504 U < 504 U < 571 U < 501 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 22 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum Frequency4-Nitrotoluene 810 2 / 71Tetryl 320 J 1 / 71METALS (mg/kg)Aluminum 31500 71 / 71Antimony 15.1 J 7 / 71Arsenic 30.4 J 70 / 70Barium 1280 71 / 71Beryllium 1.79 70 / 71Cadmium 2.4 17 / 71Calcium 184000 70 / 70Chromium 91.5 71 / 71Cobalt 95 J 71 / 71Copper 149 71 / 71Iron 59400 71 / 71Lead 1140 71 / 71Magnesium 6710 71 / 71Manganese 16100 71 / 71Mercury 430 56 / 70Nickel 96.6 71 / 71Potassium 2240 69 / 71Selenium 2.5 13 / 71Silver 1.4 J 2 / 71Sodium 2180 64 / 71Thallium 12.6 47 / 71Vanadium 73.9 71 / 71Zinc 721 71 / 71OTHER PARAMETERS (mg/kg)Cyanide 1.5 J 6 / 40Notes:ND = Not DetectedRL = Reporting LimitQual = Qualifier5407SD00 5407SS02 5408SD00 5408SS02 5409SD00 5409SS02February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 550 U < 535 U < 504 U < 504 U < 571 U < 501 U< 550 U < 535 U < 504 U < 504 U < 571 U < 501 U6330 16700 J 6750 22300 J 11600 13300 J< 11 UJ < 10.7 UJ < 10.1 UJ < 10.1 UJ < 11.4 UJ < 10 UJ13.9 13.6 J 16.1 13.4 J 7.9 9.6 J488 214 J 144 150 J 113 114 J1.4 J 1.2 J 1.4 1.4 1.2 J 0.79 J1.6 1.5 1.1 J < 1 U < 1.1 U < 1 U3900 16900 3320 3850 3420 755033.8 24.2 54.5 29 19 17.220 9.5 J 30.8 12.8 J 12 J 11.3 J11.7 23.9 14.9 19.7 18.8 14.530300 27500 43100 29900 25900 2180027.3 25.1 91.2 23.4 18.9 34.9788 J 3650 519 J 2730 934 J 20403220 1470 J 2560 969 J 1890 1260 J0.18 < 0.11 U 0.37 < 0.11 U 0.15 1.723.5 24.5 17.1 30.8 26.5 20.8477 J 1560 < 302 U 2070 596 J 1360< 1.4 U < 1.3 U < 1.3 U < 1.3 U < 1.4 U < 1.3 U< 2.2 UJ < 2.1 UJ < 2 UJ < 2 UJ < 2.3 UJ < 2 UJ1230 J 1060 J 706 J 406 J 692 J 488 J3.6 5.6 4.3 8.1 2.1 J 3.528.5 32.4 50.1 41.5 30.5 30.764.6 75.3 165 76.2 90.6 89.3< 0.34 UJ < 0.33 UJ < 0.31 UJ < 0.31 U < 0.35 UJ < 0.31 UQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 23 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range. Use diluted sample result ifavailable.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Analytical data for samples collected prior to October 2000was obtained from the Army Environmental Center database.Frequency indicates the number of times a given analyte wasdetected in the samples.The maximum detected concentrations for each analyte areunderlined and appear in boldface font.This table combines data from the Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.5407SD00 5407SS02 5408SD00 5408SS02 5409SD00 5409SS02February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 54\Final\Section 1-10\Tables_Rev1 Page 24 of 48 5/21/02TABLE 5-1SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 54 - P&E AREA FLUMEFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)Acetone 66 31 / 40Methylene Chloride 10 J 5 / 40Toluene 42 J 13 / 40SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 17000 18 / 712,6-Dinitrotoluene 1300 4 / 712-Methylnaphthalene 120 J 4 / 714-Methylphenol 60 J 1 / 71Acenaphthene 2600 11 / 71Acenaphthylene 140 J 13 / 71Anthracene 650 J 22 / 71Benzo(a)anthracene 22000 J 35 / 71Benzo(a)pyrene 16000 J 26 / 71Benzo(b)Fluoranthene 42000 37 / 71Benzo(g,h,i)perylene 11000 22 / 71Benzo(k)Fluoranthene 15000 J 30 / 71Bis(2-ethylhexyl) phthalate 500 13 / 71Butylbenzyl phthalate 570 12 / 71Carbazole 3400 20 / 71Chrysene 48000 34 / 71Di-n-butyl phthalate 27000 43 / 71Dibenz(a,h)anthracene 860 J 4 / 71Dibenzofuran 1800 8 / 71Fluoranthene 80000 J 38 / 71Fluorene 2300 11 / 71Indeno(1,2,3-c,d)pyrene 12000 J 26 / 71N-Nitrosodiphenylamine 13000 20 / 71Naphthalene 1200 6 / 71Nitrobenzene 42 J 1 / 71Phenanthrene 29000 31 / 715410SD00 5410SS02 5411SD00 5411SS02 5412SD00 5412SS02February 23, 1996 February 22, 1996 February 23, 1996 February 22, 1996 February 24, 1996 February 23, 1996Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual41 19 34 < 13 U 12 J 22< 14 U < 13 U < 12 U < 13 U < 12 U < 13 U< 14 U 1 J < 12 U 42 J < 12 U < 13 U< 450 U < 430 U < 400 U < 420 U < 390 U 280 J< 450 U < 430 U < 400 U < 420 U < 390 U < 430 U< 450 U < 430 U < 400 U < 420 U 120 J < 430 U< 450 U < 430 U < 400 U < 420 U < 390 U < 430 U< 450 U < 430 U < 400 U < 420 U 2600 66 J56 J < 430 U < 400 U < 420 U < 390 U 140 J42 J < 430 U < 400 U < 420 U 640 530340 J < 430 U < 400 U 130 J 1200 2400250 J < 430 U < 400 U < 420 U 770 1400400 J < 430 U < 400 U 190 J 1400 3200190 J < 430 U < 400 U < 420 U 200 J 610200 J < 430 U < 400 U 71 J 460 1300< 450 U 100 J < 400 U 91 J 160 J < 430 U14 J < 430 U < 400 U < 420 U < 390 U 42 J20 J < 430 U < 400 U < 420 U 450 360 J280 J < 430 U < 400 U 230 J 1100 2700< 450 U 200 J 3400 810 J 3500 3800< 450 U < 430 U < 400 U < 420 U < 390 U < 430 U< 450 U < 430 U < 400 U < 420 U 1800 34 J580 < 430 U < 400 U 300 J 3500 4000< 450 U < 430 U < 400 U < 420 U 2300 96 J170 J < 430 U < 400 U < 420 U 240 J 62036 J < 430 U < 400 U < 420 U 120 J 84 J< 450 U <
Origin:	2002-09-25
Source:	http://indianamemory.contentdm.oclc.org/cdm/ref/collection/p15078coll17/id/33745
Collection:	Clark County Collections
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Geography:	Charlestown, Clark County, Indiana 38.4357546,-85.6577676
Subjects:	Maps Indiana Ordnance Works (U.S.) Hoosier Ordnance Plant Indiana Arsenal Indiana Army Ammunition Plant Explosives Industry--Indiana Gunpowder, Smokeless Ordnance manufacture Black powder manufacture Facility One ICI Americas Inc Clark County (Ind.) Charlestown (Ind.) United States. Army Ordnance and Ordnance Stores INAAP

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