INAAP north ash settling basin site 3 report Oct 2002

Description:	The revised final report for the north ash settling basin site 3 at Indiana Army Ammunition Plant of Phase II RCRA facility investigation prepared for U.S. Army Corps of Engineers in October 2002.The United States federal government began acquiring land in Charlestown, Indiana in 1940 to build a smokeless powder ordnance plant to supply the US military during World War II. Indiana Ordnance Works (IOW) Plant 1 and Hoosier Ordnance Plant (HOP) began production in 1941. In 1944, IOW Plant 2 construction began. On 30 Nov 1945 at the end of WWII, the three plants were combined and renamed Indiana Arsenal. Between 1 Nov 1961 and 1 Aug 1963, the plant was designated Indiana Ordnance Plant. After this time, it became Indiana Army Ammunition Plant (INAAP). Production of ordnance continued at the plant until 1992. After that time, the land and facilities were leased to private industry. A large portion of the land became Charlestown State Park. In October 2016, all the land and facilities were officially sold by the government. This item is part of a larger collection of items from INAAP that are kept at Charlestown Library. R E V I S E D F I N A L R E P O R TNORTH ASH SETTLING BASIN –SITE 3INDIANA ARMY AMMUNITION PLANTPHASE II RCRA FACILITY INVESTIGATIONPrepared forU.S. Army Corps of EngineersLouisville DistrictOctober 2002Prepared by12120 Shamrock Plaza, Suite 300Omaha, Nebraska 68154TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA iExecutive Summary ..........................................................................................................................ES-1Section 1 Site Location and Description....................................................................................... 1-11.1 Operational History and Waste Characteristics ....................................... 1-11.2 Previous Investigations ............................................................................ 1-21.3 Report organization.................................................................................. 1-2Section 2 Field Activities Summary .............................................................................................. 2-12.1 Geophysical Survey ................................................................................. 2-12.2 Soil and Sediment Sampling.................................................................... 2-12.2.1 Soil ............................................................................................... 2-12.2.2 Sediment ...................................................................................... 2-22.3 Direct Push Groundwater Sampling ........................................................ 2-32.4 Surface Water Sampling .......................................................................... 2-32.5 Field Screening Results............................................................................ 2-42.6 IDW Disposition ...................................................................................... 2-4Section 3 Physical Investigation Results ..................................................................................... 3-13.1 Topography and Surface Features ........................................................... 3-13.2 Local Surficial Geology........................................................................... 3-13.3 Shallow Hydrogeology ............................................................................ 3-3Section 4 Data Quality Review and Validation ............................................................................. 4-14.1 Phase I RI................................................................................................. 4-14.2 Phase II RFI ............................................................................................. 4-1Section 5 Chemical Investigation Results .................................................................................... 5-1Section 6 Contamination Assessment.......................................................................................... 6-16.1 Potential Sources of Contamination from Historical ManufacturingProcesses .................................................................................................. 6-16.1.1 Production of Diphenylamine and Dimethylamine ..................... 6-16.1.2 Production of Nitrocellulose and Smokeless Powder.................. 6-26.2 Near Surface Soils and Sediments ........................................................... 6-36.2.1 VOCs............................................................................................ 6-36.2.2 SVOCs ......................................................................................... 6-3TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA ii6.2.3 Pesticides...................................................................................... 6-46.2.4 Metals and Cyanide...................................................................... 6-46.3 Subsurface Soils and Sediments .............................................................. 6-46.3.1 VOCs............................................................................................ 6-56.3.2 SVOCs ......................................................................................... 6-56.3.3 Pesticides...................................................................................... 6-56.3.4 Nitroaromatics/Nitramines........................................................... 6-56.3.5 Metals........................................................................................... 6-56.4 Surface Water........................................................................................... 6-66.4.1 VOCs............................................................................................ 6-66.4.2 SVOCs ......................................................................................... 6-66.4.3 Metals........................................................................................... 6-66.5 Groundwater ............................................................................................ 6-76.5.1 VOCs............................................................................................ 6-76.5.2 SVOCs ......................................................................................... 6-76.5.3 Pesticides...................................................................................... 6-76.5.4 Metals........................................................................................... 6-8Section 7 Human Health Risk Evaluation ..................................................................................... 7-17.1 Introduction.............................................................................................. 7-17.1.1 Purpose......................................................................................... 7-17.2 Risk Screening Process ............................................................................ 7-27.2.1 Identification of Contaminants of Potential Concern(COPCs)....................................................................................... 7-27.3 Exposure Assessment............................................................................... 7-37.3.1 Exposure Point Concentrations.................................................... 7-47.3.1.1 95% Upper Confidence Limit (UCL) ........................... 7-47.3.1.2 Deer Tissue Concentration............................................ 7-47.3.2 Receptors...................................................................................... 7-67.3.3 Exposure Pathways ...................................................................... 7-77.3.4 Exposure Assumptions ................................................................ 7-8TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA iii7.4 Toxicity Assessment .............................................................................. 7-117.4.1 Toxicity Assessment of Noncarcinogenic Effects ..................... 7-117.4.2 Toxicity Assessment of Carcinogenic Effects ........................... 7-137.4.3 Source of the Critical Toxicity Values....................................... 7-157.5 Risk Characterization............................................................................. 7-157.5.1 Qualitative Assessment of Exposure to Iron.............................. 7-187.6 Uncertainty Analysis.............................................................................. 7-187.6.1 Data Collection and Evaluation ................................................. 7-197.6.1.1 Data Collection ........................................................... 7-197.6.1.2 Data Evaluation........................................................... 7-197.6.1.3 Exposure Point Concentrations................................... 7-207.6.2 Exposure Assessment................................................................. 7-207.6.3 Toxicity Assessment .................................................................. 7-217.6.4 Risk Characterization................................................................. 7-22Section 8 Ecological Risk Evaluation ........................................................................................... 8-18.1 Introduction.............................................................................................. 8-18.1.1 Purpose......................................................................................... 8-28.1.2 Background.................................................................................. 8-28.1.3 Technical Approach ..................................................................... 8-38.2 Screening Level Ecological Risk Screen ................................................. 8-48.2.1 Habitat Assessment and Applicable Media ................................. 8-48.2.2 Identification of Chemicals of Potential Ecological Concern(COPECs) .................................................................................... 8-58.2.2.1 Environmental Screening Values for Surface Water andChemicals of Potential Ecological Concern ................................ 8-88.2.2.2 Environmental Screening Values for Sediment-AssociatedOrganisms of Chemicals of Potential Ecological Concern.......... 8-98.2.2.3 Environmental Screening Values for Soil-AssociatedOrganisms and Chemicals of Potential Ecological Concern ..... 8-108.2.2.4 Environmental Screening Values for Higher Vertebratesand Chemicals of Potential Ecological Concern........................ 8-118.3 Tier II Ecological Risk Assessment....................................................... 8-16TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA iv8.3.1 Problem Formulation ................................................................. 8-168.3.1.1 Relevant Ecological Issues and Environmental Setting8-178.3.1.2 Summary and Assessment Endpoints ......................... 8-248.3.1.3 Exposure Assessment.................................................. 8-258.3.1.4 Toxicity (Effects) Assessment .................................... 8-298.3.2 Analysis Plan ............................................................................. 8-338.3.2.1 Measurement Endpoints and Receptors of Concern... 8-338.3.2.2 Toxicity Reference Values for Risk Characterization 8-438.4 Risk Characterization............................................................................. 8-458.4.1 Primary Producers and Assessment Endpoint #1 ...................... 8-468.4.2 Decomposers and Detritivores - Assessment Endpoint #2 ........ 8-478.4.3 Water Column Invertebrates and Amphibians - AssessmentEndpoint #3 and Measurement Endpoints #1, 2, and 3. ............ 8-488.4.4 Terrestrial and Semiaquatic Herbivores - AssessmentEndpoint #3 and Measurement Endpoint #3.............................. 8-488.4.5 Terrestrial and Semiaquatic First-Order Carnivores andAssessment Endpoint #5............................................................ 8-498.4.6 Terrestrial and Semiaquatic Second-Order Carnivores andAssessment Endpoint #6............................................................ 8-498.4.7 Cave Resources - Assessment Endpoint #7 ............................... 8-498.4.8 Risk Characterization Summary and Ecological Significance .. 8-498.5 Uncertainty Analysis.............................................................................. 8-50Section 9 Summary and Recommendations ................................................................................ 9-19.1.1 Physical Characteristics ............................................................... 9-19.1.2 Contamination Assessment.......................................................... 9-19.1.2.1 Near Surface Soil and Sediment ................................... 9-19.1.2.2 Subsurface Soil and Sediment Samples........................ 9-29.1.2.3 Surface Water Samples ................................................. 9-29.1.2.4 Groundwater Samples................................................... 9-29.1.3 Human Health Risk Screen/Assessment...................................... 9-29.1.3.1 Soil/Sediment................................................................ 9-29.1.3.2 Groundwater/Surface Water ......................................... 9-39.1.4 Ecological Risk Screen / Assessment .......................................... 9-3TABLE OF CONTENTSSection PageQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA v9.2 Recommendations.................................................................................... 9-3Section 10 References.................................................................................................................... 10-1TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA viTable 2-1 Summary of Phase I RI Samples for Chemical AnalysisTable 2-2 Summary of Phase II RFI Samples for Chemical AnalysisTable 2-3 Summary of Field Screening For Organic Vapors in Soil SamplesTable 5-1 Comparison of Chemicals Detected in TCLP Sample CollectedTable 5-2 Summary of Chemicals Detected in Soil and Sediment SamplesTable 5-3 Summary of Chemicals Detected in Surface Water and GroundwaterSamplesTable 7-1 Comparison of Soil Concentrations to Screening LevelsTable 7-2 Comparison of Maximum Surface Soil and Sediment Concentrations toScreening LevelsTable 7-3 Comparison of Surface Water and Groundwater Concentrations toScreening LevelsTable 7-4 Total Soil/Sediment Exposure Point ConcentrationTable 7-5 Surface Soil/Sediment Exposure Point ConcentrationsTable 7-6 Deer Tissue ConcentrationsTable 7-7 Parameters Used To Evaluate Potential Exposure Human Health RiskAssessmentTable 7-8 Critical Toxicity Values for Chemicals of Potential ConcernTable 7-9 USEPA Weight-Of-Evidence Carcinogenic Classification of ChemicalsTable 7-10 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Total Soil/Sediment – Excavation WorkerTable 7-11 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Total Soil/Sediment – Site WorkerTable 7-12 Summary of Non-Carcinogenic Health Hazards and Carcinogenic RisksAssociated with Surface Soil/Sediment and Game Ingestion – HunterTable 7-13 Summary of Non-Carcinogenic Health Hazards and CarcinogenicRisks Associated with Total Soil/Sediment – Child RecreatorTable 7-14 Comparison of Maximum, Average, and BackgroundConcentrations of Metals in SoilTable 8-1 Comparison of Maximum Surface Water Concentrations to EcologicalScreening Values (ESVs)Table 8-2 Comparison of Maximum Sediment Concentrations to Ecological ScreeningValues (ESVs)Table 8-3 Comparison of Maximum Soil Concentrations to Ecological ScreeningValues (ESVs)TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA viiTable 8-4 Potential Dietary (Foodweb) Concentrations Based on MaximumWater/Soil/Sediment Concentrations to Ecological Screening ValuesTable 8-5 Comparison of Predicted Air Concentrations Within Caves Based onMaximum Surface Water Concentrations to Ecological Screening ValuesTable 8-6 Chemicals Selected As Chemicals of Potential Ecological Concern forDirect Ecological ExposuresTable 8-7 Chemicals Selected As Chemicals of Potential Ecological Concern forIndirect (Food Web) ExposuresTable 8-8 Summary of Chemicals of Potential Ecological Concern and MeasurementEndpoints for the Ecological Risk AssessmentTable 8-9 Physical and Behavioral Characteristics of Representative Species Used asReceptors of ConcernTable 8-10 Assumed Dietary Compositions for the Representative Receptors ofConcern (ROCs)Table 8-11 Toxicity Reference Values for Direct Exposure to Chemicals of PotentialEcological Concern in WaterTable 8-12 Toxicity Reference Values for Direct Exposure to Chemicals of PotentialEcological Concern in SedimentTable 8-13 Toxicity Reference Values for Direct Exposures to Chemicals of PotentialEcological Concern in SoilTable 8-14 Oral Toxicity Reference Values Selected for Indirect Exposures (Foodweb)to Chemicals of Potential Ecological ConcernTable 8-15 Ecological Hazard Quotient Results for Terrestrial Plants - AssessmentEndpoint #1 - Measurement Endpoints #1Table 8-16 Ecological Hazard Quotient Results for Algae Assessment Endpoint #1 -Measurement Endpoints # 2Table 8-17 Ecological Hazard Quotients Results for Soil Microbial Activity andInvertebrate Detritivores Associated Assessment Endpoint #2 -Measurement Endpoints # 5Table 8-18 Ecological Hazard Quotient Results for Sediment-Associated InvertebrateDetritivores Assessment Endpoint #2 - Measurement Endpoints #1, 3, & 4Table 8-19 Ecological Hazard Quotient Results for Aquatic (Water Column)Invertebrates and Vertebrates (Fish and Amphibians) - AssessmentEndpoint #3 - Measurement Endpoints #1 & 2Table 8-20 Ecological Hazard Quotient Results for Representative HerbivoresAssessment Endpoint #3 – Measurement Endpoint #3TABLE OF CONTENTSList of TablesQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev2(revised final).doc\6-Aug-02 /OMA viiiTable 8-21 Ecological Hazard Quotient Results for Representative OmnivoresAssessment Endpoint #4 - Measurement Endpoint #1Table 8-22 Ecological Hazard Quotient Results for Representative First-OrderCarnivores Assessment Endpoint #5 - Measurement Endpoints #1 & 2Table 8-23 Ecological Hazard Quotient Results for Representative Top CarnivoresAssessment Endpoint #6 – Measurement Endpoint #1TABLE OF CONTENTSList of FiguresQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA ixFigure 1-1 Site Location MapFigure 1-2 Surface Features MapFigure 2-1 Sample Location MapFigure 3-1 Electrical Resistivity Transect #1, Array #1Figure 3-2 Electrical Resistivity Transect #1, Array #2Figure 3-3 Electrical Resistivity Transect #2Figure 3-4 Electrical Resistivity Transect #3Figure 3-5 Boring LogsFigure 3-6 Cross Section Location PlanFigure 3-7 Cross SectionsFigure 6-1 Concentrations of Chemicals Detected in SoilFigure 6-2 Concentrations of Chemicals Detected in SedimentFigure 6-3 Concentrations of Chemicals Detected in Surface Water andGroundwaterFigure 8-1 Ecological Evaluation ProcessFigure 8-2 Conceptual Ecological Exposure (Direct & Foodweb) ModelFigure 9-1 Human Health COPCs and Ecological COPECs Detected in Soil,Sediment, Surface Water and GroundwaterTABLE OF CONTENTSList of AppendicesQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xAppendix A Data Quality Review and ValidationAppendix B Human Health Risk Statistics and CalculationsAppendix C Ecological Risk Statistics and CalculationsAppendix D Daily Quality Control ReportsAppendix E Boring and Trench Logs; Topographic Survey DataAppendix F Geotechnical DataAppendix G Sample Collection Field SheetsAppendix H Summary of Analytical DataNote: Information contained in the Appendices is included in CD-ROM format. The CD-ROMmay be found at the back of this binder.TABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xiACHe AcetylcholinesteraseADI Acceptable Daily IntakeADNTs Amino-dinitrotoluenesATP Adenosine TriphosphateAE Assessment EndpointAEC U.S. Army Environmental CenterAET Apparent Effect LevelsALAD Alpha-aminolevulinic Acid DehydrogeuaseAPCB Jefferson County Air Pollution Control BoardAQUIRE Aquatic Information Retrieval System.AST Aboveground Storage TankASTER Assessment Tools for the Evaluation of RiskATSDR Agency for Toxic Substances and Disease Registrybgs Below Ground SurfaceBA BioavailabilityBCFs Bioconcentration FactorsBRAC Base Re-Alignment and ClosureBSAFs Biota-Sediment Accumulation FactorsBTEX Benzene, Toluene, Ethylbenzene, XylenesBTFs Biota Transfer Factorsbtu British Thermal UnitBW Body WeightCERCLA Comprehensive Environmental Response, Compensation, and Liability ActCDI Chronic Daily IntakeCLP Contract Laboratory ProgramCMS Corrective Measures StudyCOC Chemicals of ConcernCOI Chemical of InterestCOPC Chemicals of Potential ConcernCOPEC Chemicals of Potential Ecological ConcernCRDL Contract Required Detection LimitCRQL Contract Required Quantitation LimitsTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xiiCSP Charlestown State ParkCTE Central Tendency ExposureCTV Critical Toxicity ValueDAF Dilution Attenuation FactorDBT Dibutyl phthalateDDD dichlorodiphenyldiehlorethaneDDE 4, 4 DDEDDT 1, 1’ (2,2,2-Trichloroethylidene)bis[4-chlorobenzene]DERP Defense Environmental Restoration ProgramDNA Deoxyribonucleic acidDOD Department of DefenseDQCR Data Quality Control ReportsDQO Data Quality ObjectivesDS Direct Push SoilDW Direct Push WaterEECs Environmental Exposure ConcentrationsEEQ Environment Exposure QuotientEM ElectromagneticEPA U.S. Environmental Protection AgencyEPC Exposure Point ConcentrationEQP Equilibrium-PartitioningERA Ecological Risk AssessmentERAGs Ecological Risk Assessment Guidance for SuperfundERL Effects – Range - LowERM Effects – Range – MediumERT Emergency Response TeamESV Ecological Screening ValueFC Fraction IngestedFSP Field Sampling PlanGABA Gamma-aminobutyric AcidGOCO Government-Owned, Contractor-Operatedgpm gallons per minuteTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xiiiGPR Ground Penetrating RadarHEAST Health Effects Assessment Summary TablesHHRA Human Health Risk AssessmentHI Hazard IndexHLSC Human Life Cycle Safe ConcentrationHMW High Molecular WeightHOP Hoosier Ordnance PlantHQ Hazard QuotientHSA hollow-stem augerHSDB Hazardous Substance DatabaseICI ICI Americas, Inc.ID inner diameterIDEM Indiana Department of Environmental ManagementIDL Instrument Detection LimitIDNR Indiana Department Natural ResourcesIEUBK Integrated Exposure Uptake BiokineticINAAP Indiana Army Ammunition PlantIOW Indiana Ordnance Works Plant 1IRIS Integrated Risk Information SystemIWPCB Indiana Water Pollution Control BoardIWQC Indiana Water Quality CriteriaIOWP Indiana Ordnance Works Plant 2J/UJ Qualified Estimatedkg KilogramL/day Liter per dayLAP Load, Assemble, and PackLC LeachateLMW Low Molecular WeightLOAEL Lowest to Observed Adverse Effects LevelLOEC Lowest Observation Effect concentrationsLOQ Limits of QuantitationMATC Maximum Acceptable Toxicant ConcentrationTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xivMCL Maximum Contaminant LevelME Measurement Endpointmg/day milligrams per daymg/kg milligram per kilogrammg/m3 milligram per cubic meterMS/MSD Matrix Spike/Matrix Spike DuplicateMSL Mean Sea LevelMW Monitoring WellNCEA National Center for Environmental AssessmentNOAEL No Observable Adverse Effects LevelNOD Notice of DeficiencyNPDES National Pollutant Discharge Elimination SystemOD outside diameterORNL Oak Ridge National LaboratoryP&E Propellants and ExplosivesPA Preliminary AssessmentPAH Polynuclear Aromatic HydrocarbonPCB Polychlorinated BiphenylPEL Probable – Effects – Levelppm parts per millionPRG Preliminary Remediation GoalsPVC Polyvinyl ChlorideQA Quality AssuranceQAPP Quality Assurance Project PlanQC Quality Control“R” RejectedRAGS Risk Assessment Guidance for SuperfundRBC Risk-Based ConcentrationRCRA Resource Conservation and Recovery ActRDA Recommended Daily AllowanceRfD Reference DoseRFD-I Reference Inhalation DoseTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xvRFI RCRA Facility InvestigationRI Remedial InvestigationRISC Risk Integrated System of ClosureRME Recommended Maximum ExposureRNA Ribonucleic acidROC Receptor of ConcernSAP Sampling and Analysis PlanSARA Superfund Amendments and Reauthorization ActSB Soil BoringSCEM Site Conceptual Exposure ModelSCFS Sample Collection Field SheetsSD SedimentSF-SH Slope Factor-Sulfhydryl ligandsSOP Standard Operating ProcedureSP SpringSS Shallow SoilSVOC Semivolatile Organic CompoundSW Surface WaterSWQC Surface Water Quality CriteriaTAL Target Analyte ListTCL Target Compound ListTCLP Toxicity Characteristic Leaching ProcedureTDS Total Dissolved SolidsTEL Threshold – Effects – LevelTNT TrinitrotouleneToxNet Toxicity Data NetworkTPH Total Petroleum HydrocarbonsTRV Toxicity Reference ValueTSS Total Suspended Solids“U” Qualified Nondetectμg/kg microgram per kilogramμg/L microgram per LiterTABLE OF CONTENTSAcronym ListQ:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA xviTEL Threshold – Effects – LevelTNT TrinitrotouleneToxNet Toxicity Data NetworkTPH Total Petroleum HydrocarbonsTRV Toxicity Reference ValueTSS Total Suspended Solids“U” Qualified Nondetectμg/kg microgram per kilogramμg/L microgram per Literμg/m3 microgram per cubic meterUCL Upper Confidence LimitURSGWC URS Greiner Woodward ClydeUSACE U.S. Army Corps of EngineersUSATHAMA U.S. Army Toxic and Hazardous Materials AgencyUSCS Unified Soil Classification SystemUSDA U.S. Department of AgricultureUSEPA U.S. Environmental Protection AgencyUSGS U.S. Geologic SurveyUST Underground Storage TankUTL Upper Tolerance LimitVOC Volatile Organic CompoundW-C Woodward-ClydeExecutive Summary North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA ES-1The following includes the results of the Phase II RCRA Facility Investigation (RFI) completedfor the North Ash Settling Basin (Site 3) at the Indiana Army Ammunition Plant (INAAP). Thereport also summarizes the results of the previously completed Phase I Remedial Investigation(RI).INAAP currently encompasses approximately 9,790 acres in south-central Clark County,Indiana. Its southern boundary is approximately 6 miles north of Jeffersonville, Indiana and 10miles from the Louisville, Kentucky metropolitan area, which lies to the south across the OhioRiver. INAAP is a Government-Owned, Contractor-Operated, inactive military industrialinstallation. The Army intends to transfer the property to the Local Reuse Authority forcommercial development or to the State of Indiana for inclusion in the state park system. TheSouth Ash Settling Basin is one of 90 sites identified at INAAP.The Plant was originally constructed as three separate facilities: The Indiana Ordnance WorksPlant 1, the Hoosier Ordnance Plant, and the Indiana Works Plant 2. The three facilities wereconsolidated into the Indiana Arsenal in 1945. The Indiana Arsenal was redesignated as theIndiana Ordnance Plant in 1961; in August 1963 it was redesignated again as the Indiana ArmyAmmunition Plant.Topography at the INAAP can be described as a middle-aged karst topography. Karsttopography is produced by the dissolution of limestone, gypsum, or other readily soluble rocks,commonly along joints, fractures, bedding planes, or other such features. The dissolutionprocess results in the formation of sinkholes, caves, and underground drainage. Numeroussinkholes and springs are found throughout much of INAAP.Approximately 96 percent of INAAP’s land surface drains directly into the Ohio River via sevendrainage basins. The remaining 4 percent reaching the Ohio River indirectly through thePheasant Run basin.Groundwater at INAAP is present in the bedrock formations of the upland areas and in theterrace/floodplain sand and gravel deposits located within the Ohio River valley. Thegroundwater present in the floodplain aquifer along the Ohio River is a major water supplysource. Groundwater is not usually found in the thin soil layer covering the bedrock surface inthe upland areas. When present, shallow groundwater typically mingles with surface water byflowing in and out of karst features.The Phase I and II investigations at the North Ash Settling Basin included the completion of 12soil borings; the collection of and analysis 40 surface and subsurface soil samples, 18 sedimentsamples, 3 collocated surface water/sediment samples, 10 surface water/spring samples, and 12groundwater samples. Chemical analysis included VOCs, SVOCs, pesticides, PCBs, metals,nitroaromatics/nitramines, TPH, and various wet chemistry parameters and geotechnicalanalysis.The North Ash Settling Basin covers approximately 4.6 acres. The site intermittently receivedslurried ash from the north coal-fired power plant between 1941 and 1957. The basin may havereceived wastewater from the P & E Manufacturing Area.Executive Summary North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA ES-2The North Ash Settling Basin is located in an Upland area characterized by karst topographyassociated with shallow limestone bedrock. The area surrounding the basin slopes toward thebasin. The North Ash Settling Basin is located in the Fourteen Mile Creek drainage basin. Astream flows into the southern end of the basin and exits on the northern end through standpipesthat control the water level.The basin is covered with marshy grasses, weeds and scattered trees. The northeast end of thebasin contained standing water to an approximate depth of 2.5 feet during the Phase II RFI.Local surficial geology consists of a thin layer of topsoil and up to 10 feet of ash underlain bycolluvium and residual clay. Bedrock was encountered at depths ranging from 3.5 feet to 15.5feet bgs. Groundwater was encountered in each boring at depths ranging from 0.1 to 4.0 feetbgs.Contamination was evaluated in near surface soil and sediment, subsurface soil, surface water,and groundwater. Concentrations of detected chemicals were compared to calculated, site-specificindustrial closure levels (Level 2) and those exceeding 50% of the value were consideredelevated. Elevated levels of target compounds were not detected in sediment, surface soil,subsurface soil, surface water, or groundwater samples. Several metals results exceededbackground concentrations for all media sampled.Future land use in the North Ash Settling Basin area may be recreational, as part of the existingstate park system. Therefore a human health risk assessment evaluated the on-site worker,excavation worker, hunter, and child recreator scenarios. The results indicate that the potentialprimary carcinogenic risk driver is the ingestion of arsenic in soil. The potential primary non-carcinogenicrisk drivers are the ingestion of arsenic, iron and manganese in soil. The cancerrisks ranged from 2x10-7 to 8x10-6 for the Recommended Maximum Exposure (RME) and 2x10-8to 2x10-6 for Central Tendency Exposure (CTE). Hazard indices ranged 0.02 to 0.7 for RME and0.005 to 0.15 for CTE. The risk did not exceed the IDEM target level of 1x 10-5 and thecumulative Hazard Index did not exceed the target level of 1.0 indicating that no adverse healtheffects or risks would be anticipated.Several pathways were evaluated as part of an ecological risk assessment. The only salient riskpotentials are associated with sediment dwelling organisms. However, there appears to littleevidence for a risk potential to the most significant community, an amphibian nursery, or to theforage base for this community (algae). From a terrestrial standpoint, no significant riskpotential is present. While a potential transport mechanism is present from the basin to caveresources, none appear to be exposed to any significant risk potential. This suggests that thelevels of chemicals present within the North Ash Settling Basin do not warrant furtherinvestigation based on ecological concerns.Data of sufficient quality and quantity has been collected to characterize the North Ash SettlingBasin (Site 3). Physical and chemical investigation results indicate that there are no potentialhuman health or ecological concerns. Based on the results of the human health and ecologicalrisk assessments no further action is recommended for this site.Site Location and DescriptionSECTIONONE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 1-1The North Ash Settling Basin (Site 3) is located in the northern portion of INAAP (see Figure 1-1). The North Ash Settling Basin is borderedby:· North - A wood compostmanufacturing operation andwoodlands which are part of theCharlestown State Park· South - Gravel access road,woodlands, and the P&E Area (Site63)· East - Old Landfill (Site 1)· West - Fields of grass and weeds andwoodlands, which are part of theCharlestown State Park and the Administration Area.The North Ash Settling Basin occupies approximately 4.6-acres of land and is dammed at thenorth-northeast end (see Figure 1-2). A stream flows into the southern end of the basin and exitson the northern end through concrete standpipes that control the water level (ASI 1994).1.1 OPERATIONAL HISTORY AND WASTE CHARACTERISTICSBased on interviews, aerial photographs, a records review, and site reconnaissance, the followingoperational history and waste characteristics were determined:· The North Ash Settling Basin intermittently received slurried ash from the northcoal-fired power plant between 1941 and 1957.· The basin may have received P&E Area wastewater from the production ofnitrobenzene, aniline, diphenylamine, and dimethylaniline.· The basin may also contain nitrocellulose waste (ENSR 1992, 1994).· Army personnel observed that the basin periodically received discharge from theCharlestown sewage treatment plant during maintenance activities at thetreatment facility.· The North Ash Settling Basin is currently inactive for ash disposal.· The site is covered with water occasionally; portions of the site were floodedduring the Phase I Remedial Investigation (RI) and part of the Phase II ResourceConservation and Recovery Act (RCRA) Facility Investigation (RFI)Site Location and DescriptionSECTIONONE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 1-21.2 PREVIOUS INVESTIGATIONSDames & Moore completed a Contamination Survey at the site in 1984 (D&M 1984). Threesediment samples were collected from the basin, and one sediment sample and one water samplewere collected from a location downstream of the basin. Results from the samples collected inthe area of the basin indicated that cadmium, chromium, copper, lead, zinc, phosphate, andsulfate concentrations exceeded background levels. Results from the sediment sample collecteddownstream from the basin indicated that cadmium, chromium, and zinc concentrationsexceeded background levels. The water sample indicated nitrate, lead, and sulfate concentrationsexceeded background levels.However, the analytical methods used then are now obsolete, rendering the analytical datacollected during this survey incomparable to the data collected, following current standards,during the Phase I RI and the Phase II RFI.1.3 REPORT ORGANIZATIONThe remaining portion of this report is organized as follows:· Section 2 – Field Activities Summary· Section 3 – Physical Investigation Results: reviews site topography, local surficialgeology, and shallow hydrogeology· Section 4 – Data Quality Review and Validation: summarizes the results of the 100percent quality control (QC) review and the ten percent full validation· Section 5 – Chemical Investigation Results: identifies the chemical analyses used andfield duplicate samples collected; summarizes the sample detections by sampleidentification number and matrix type in tabular form· Section 6 – Contamination Assessment: presents an evaluation, both in text and onfigures, of chemicals present at the sight in elevated concentrations by matrix andchemical group· Section 7 – Human Health Risk Evaluation: examines the chemicals present invarious matrices at the site to determine if they pose a threat to human health· Section 8 – Ecological Health Risk Evaluation: examines the chemicals present invarious matrices at the site to determine if they pose a threat to the environment· Section 9 – Summary and Recommendations: includes corrective measure studyobjectives· Section 10 – ReferencesFor additional information regarding the rationale for and the objectives of the Phase II RFI,refer to the Sitewide Work Plan (URSGWC 2000a).Field Activities SummarySECTIONTWO North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 2-1Field activities for this site included direct push soil, soil gas and groundwater sampling, andsediment, subsurface soil and surface water sampling. The locations of the sampling points areprovided on Figure 2-1. Sample location, identification, depth, matrix, and chemical analysesare presented in Table 2-1 for samples collected in 1996, and in Table 2-2 for samples collectedin 2000. All field activities were completed in accordance with applicable Standard OperatingProcedures (SOPs) (W-C 1998, URSGWC 2000b). Any deviations from the SOPs are noted onthe Sample Collection Field Sheets (SCFS), provided in Appendix G.2.1 GEOPHYSICAL SURVEYAn electrical resistivity survey was completed as part of the Phase II RFI investigation. Threetransects were positioned across the basin as shown on Figure 2-1. Electrodes were spaced at10-foot intervals. The north-south transect was completed in two arrays due to the length of thebasin and the short electrode spacing. The results of the survey are discussed in Section 3.2.2.2 SOIL AND SEDIMENT SAMPLING2.2.1 SoilTwelve borings were located in areas of suspected contamination based on the geophysicalsurvey data (see Section 2.1), historical information, and site accessibility. Borings 03SB01through 03SB12 were completed at the following locations (see Figure 2-1) using a direct pushsystem and 1.75-inch diameter polyvinyl chloride (PVC) liners:· 03SB01 – Near the south end of Electrical Resistivity Transect #3· 03SB02 – Near the center of Electrical Resistivity Transect #3· 03SB03 – North of the end of Electrical Resistivity Transect #1, Array #2· 03SB04 – Near the center of the south side of the basin· 03SB05 – At the center of the basin near Electrical Resistivity Transect #1, Array #1· 03SB06 – At the northern end of Electrical Resistivity Transect #2· 03SB07 – At the southern end of Electrical Resistivity Transect #2· 03SB08 – Outside the pond on the western end· 03SB09 – On the western edge of the pond· 03SB10 – On the north end of Electrical Resistivity Transect #3· 03SB11 – On the northeast corner of the basin· 03SB12 – Near the intersection of Electrical Resistivity Transect #1, Array #1 andElectrical Resistivity Transect #3Typically, three samples were collected for chemical analysis from each boring.Field Activities SummarySECTIONTWO North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 2-2Ten geotechnical samples were collected from the North Ash Settling Basin during the Phase IIRFI. The analytical results from these geotechnical samples are presented in Table F-1 inAppendix F.2.2.2 SedimentThirteen sediment samples were collected from areas of standing or running water upstream,within, and downstream of the basin. These samples were collocated with the surface watersamples discussed in Section 2.5. The sediment samples were collected at the followinglocations (see Figure 2-1):· 03SD01 and 03SD02 – From beneath flowing water in the stream, down-gradient ofthe dam· 03SD03 – From beneath flowing water at the spring located north of the dam· 03SD04 and 03SD05 – From beneath standing water at the northeastern end of thebasin· 03SD06 through 03SD09 – From beneath standing water in the stream branches thatrun through the center of the basin· 03SD10 – From beneath flowing water in the stream that flows into the south end ofthe basin, at a location between the dirt road and the fence· 03SD11 through 03SD18 – From locations throughout the basin observed to besaturated during the January 1995 site reconnaissance (see Figure 2-1)· 03SD19 – From beneath flowing water in the stream that flows into the south end ofthe basin, at a location between the dirt road and the fence· 03SD20 – From beneath flowing water in the stream, down-gradient of the dam· 03SD21 – From beneath flowing water in the stream at the base of the damHand auger refusal occurred at depths ranging from 0.2 to 1.0 foot below ground surface (bgs)for sediment samples at locations 03SD01 through 03SD10. Therefore, these sediment sampleswere collected at intervals ranging from 0 to 0.2 feet to 0 to 1.0 feet bgs. Sediment samples03SD19 through 03SD21 were collected from 0.0 to 0.2 feet bgs. Sediment samples fromlocations 03SD12, 03SD13, and 03SD15 through 03SD18 were collected from the 3 to 5 feet bgsinterval. Hand auger refusal occurred at 1.5 and 4 feet bgs at sediment sample locations 03SD11and 03SD14, respectively. Therefore, samples from sediment sample locations 03SD11 and03SD14 were collected from 0 to 1.5 feet and 3 to 4 feet bgs, respectively. Sample location,identification, depth, matrix, and chemical analysis are presented in Tables 2-1 and 2-2.An additional basin sediment sample, collected from 3.0 to 5.0 feet bgs at a location adjacent to03SD19, underwent Toxicity Characteristic Leaching Procedure (TCLP) extraction prior tochemical analysis.Field Activities SummarySECTIONTWO North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 2-32.3 DIRECT PUSH GROUNDWATER SAMPLINGGroundwater samples were collected from direct push borings 03SB01 through 03SB12. It wasnot possible to collect a sufficient quantity of groundwater for complete analysis from borings03SB02 and 03SB05 during the initial sampling. Therefore, in order to obtain a sufficientquantity, complete groundwater samples were collected from 03SB02 and 03SB05 over 16-hourand 4-hour periods, respectively. Sufficient quantities of groundwater were not available inborings 03SB06, 03SB08, and 03SB09 either. However, the groundwater at these locations didnot completely recharge, so only partial groundwater samples were collected from borings03SB06, 03SB08, and 03SB09 (see Table 2-2 for details).Ten of the 12 groundwater samples were collected from direct push borings (03SB01 to 03SB10)through slotted, PVC standpipes. The other two groundwater samples were collected from directpush borings (03SB11 and 03SB12) through the exposed screen of a screen point samplerattached to the extension rods. Samples for volatile organic compounds (VOCs) analysis werecollected using a stainless steel minibailer. Prior to the collection of samples for other analyses,at least 500 milliliters (mL) of water were purged from each boring using a peristaltic pump anddesignated high density polyethylene (HDPE) tubing. Samples for other analyses were collectedusing the peristaltic pump and HDPE tubing.Sample identification, depth, matrix, and chemical analysis are presented in Tables 2-1 and -2-2.Boring locations are shown in Figure 2-1.2.4 SURFACE WATER SAMPLINGThirteen surface water samples were collected from areas of standing and running waterupstream, within, and downstream of the basin. These samples were collocated with thesediment samples discussed in Section 2.2. The surface water samples were collected at thefollowing locations (see Figure 2-1):· 03SW01 and 03SW02 – From flowing water in the stream, down-gradient of the dam· 03SW03 – From flowing water at the spring located north of the dam· 03SW04 and 03SW05 – From standing water at the northeastern end of the basin· 03SW06 through 03SW09 – From standing water stream branches that run throughthe center of the basin· 03SW10 – From flowing water in the stream that flows into the south end of thebasin, at a location between the dirt road and the fence· 03SW19 – From flowing water in the stream that flows into the south end of thebasin, at a location between the dirt road and the fence· 03SW20 – From flowing water in the stream, down-gradient of the dam· 03SW21 – From flowing water in the stream at the base of the damField Activities SummarySECTIONTWO North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 2-4Sample location, identification, depth, matrix, and chemical analysis are presented in Tables 2-1and 2-2. Sample locations are shown in Figure 2-1.2.5 FIELD SCREENING RESULTSField screening was completed during the Phase I RI and Phase II RFI using headspace analysis.Recovered soil from each boring and sediment sample was field screened using aphotoionization detector (PID) to verify the presence or absence of organic vapors. Headspaceresults are presented in Table 2-3, and were recorded on the boring logs (see Appendix E) andthe Sample Collection Field Sheets (SCFSs) (see Appendix G).2.6 IDW DISPOSITIONInvestigation-derived wastes (IDW) including soil cuttings, development and purge water,decontamination fluids, and personal protective equipment (PPE) were containerized inaccordance with the Sitewide Work Plan (URSGWC 2000a). Disposal of the IDW containershas been documented in the “IDW Disposition Technical Memorandum” (URS 2001).TABLE 2-1SUMMARY OF PHASE I RI SAMPLING FOR CHEMICAL ANALYSISSITE 3 - NORTH ASH SETTLING BASINSample Sample Sample SampleLocation Identification Depth (ft bgs) Matrix VOCs1 SVOCs2 Pest/PCB3 Metals4 Explosive5 Nitrate/Nitrite6 TCLP7 Comments03SD01 0301SD00 0-0.5 Sediment X X X X X MS/MSD03SD02 0302SD00 0-0.7 Sediment X X X X X03SD03 0303SD00 0-0.5 Sediment X X X X X03SD04 0304SD00 0-0.5 Sediment X X X X X0328SD00 0-0.5 Sediment X X X X X Duplicate (0304SD00)03SD05 0305SD00 0-1.0 Sediment X X X X X03SD06 0306SD00 0-0.8 Sediment X X X X X03SD07 0307SD00 0-0.5 Sediment X X X X X03SD08 0308SD00 0-0.5 Sediment X X X X X03SD09 0308SD00 0-0.4 Sediment X X X X X03SD10 0310SD00 0-0.2 Sediment X X X X X03SD11 0311SD02 0-1.5 Sediment X X X X X03SD12 0312SD05 3.0-5.0 Sediment X X X X X03SD13 0313SD05 3.0-5.0 Sediment X X X X X03SD14 0314SD05 3.0-4.0 Sediment X X X X X X03SD15 0315SD05 3.0-5.0 Sediment X X X X X X03SD16 0316SD05 3.0-5.0 Sediment X X X X X X03SD17 0317SD05 3.0-5.0 Sediment X X X X X X03SD18 0318SD05 3.0-5.0 Sediment X X X X X X03SD19 0319SD05 3.0-5.0 Sediment X02SW01 0301SW00 NA Surface Water X X X X X MS/MSD(spring)ParametersQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 1 of 24/22/02TABLE 2-1SUMMARY OF PHASE I RI SAMPLING FOR CHEMICAL ANALYSISSITE 3 - NORTH ASH SETTLING BASINSample Sample Sample SampleLocation Identification Depth (ft bgs) Matrix VOCs1 SVOCs2 Pest/PCB3 Metals4 Explosive5 Nitrate/Nitrite6 TCLP7 CommentsParameters03SW02 0302SW00 NA Surface Water X X X X X03SW03 0303SW00 NA Surface Water X X X X X03SW04 0304SW00 NA Surface Water X X X X X0320SW00 NA Surface Water X X X X X Duplicate (0304SW00)03SW05 0305SW00 NA Surface Water X X X X X03SW06 0306SW00 NA Surface Water X X X X X03SW07 0307SW00 NA Surface Water X X X X X03SW08 0308SW00 NA Surface Water X X X X X03SW09 0309SW00 NA Surface Water X X X X X03SW10 0310SW00 NA Surface Water X X X X XNotes: Abbreviations:Samples were collected in 1996. bgs = Below Ground Surface1 TCL Volatile Organic Compounds: Preparation Method 5030 / Analysis Method 8260A. MS/MSD = Matrix Spike/Matrix Spike Duplicate2 TCL Semivolatile Organic Compounds: Preparation Methods 3520 (aqueous) and 3550 (soil/sediment) / Analysis Method 8270. NA = Not Applicable3 TCL Pesticides/Polychlorinated Biphenyls: Preparation Method 3520 (aqueous) and 3550 (soil/sediment) Analysis Method 8080. SB = Soil Boring4 TAL Metals: Preparation Methods 3010/3020 (aqueous) and 3050B (soil) / Analysis Methods 6010/7000. SD = Sediment5 Nitroaromatics/Nitramines were prepared and analyzed as identified in Method 8330. SW = Surface Water6 Nitrate/Nitrite was prepared and analyzed as identified in Method 300. ft = feet7 Toxicity Characteristic Leaching Procedure preparation Method 1311.Surface soil samples collected (from 0.0 to 2.0 ft bgs)during the Phase I RI use 02 for the depth indicatorportion of the Sample Identification.All samples to be analyzed for chemical analysis were shipped EMAXLaboratory, Inc, of Torrance, California.Field Duplicate = Quality Control Duplicate (original samplelisted immediately above)Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 2 of 24/22/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 3 - NORTH ASH SETTLING BASINSample Sample Sample Sample ParametersLocation Identification Depth (ft bgs) Matrix VOCs1 SVOCs2 Metals3 Explosives4 Pesticides/PCBs5 Cyanide6 TOC7 TDS/TSS8 Geotech9 Comments03SB01 0301DS00 0.0-1.0 Soil X X X X X X0301DS20 0.0-1.0 Soil X X X X X X Duplicate (0301DS00)0301DS06 4.0-5.3 Soil X X X X X X X0301DS06 5.3-6.0 Soil X0301DS07 6.0-7.2 Soil X X X X X X0301DW07 0.8-7.2 Groundwater X X X X X X X0301DW20 0.8-7.2 Groundwater X X X X X X X Duplicate (0301DW07)03SB02 0302DS00 0.0-1.0 Soil X X X X X X MS/MSD0302DS11 9.0-10.8 Soil X X X X X X X0302DS12 10.8-12.0 Soil X0302DS16 14.0-15.5 Soil X X X X X X0302DW19 1.3-10.0 Groundwater X X X X X X03SB03 0303DS00 0.0-1.0 Soil X X X X X X0303DS07 6.0-7.0 Soil X X X X X X X0303DW07 1.0-7.0 Groundwater X X X X X X03SB04 0304DS00 0.0-1.0 Soil X X X X X X X0304DS03 3.0-4.0 Soil X X X X X X0304DW03 0.1-3.0 Groundwater X X X X X X03SB05 0305DS00 0.0-1.0 Soil X X X X X X0305DS11 9.0-11.0 Soil X X X X X X X0305DS13 11.8-13.0 Soil X0305DS14 13.0-14.2 Soil X X X X X X0305DW14 1.1-10.0 Groundwater X X X X X X03SB06 0306DS00 0.0-1.0 Soil X X X X X X0306DS03 2.1-3.0 Soil X0306DS10 0.0-1.0 Soil X X X X X X Duplicate (0306DS00)0306DS02 1.0-2.0 Soil X X X X X X X0306DS04 3.0-4.1 Soil X X X X X X0306DW04 4.0-4.1 Groundwater X Limited Recovery0306DW05 X03SB07 0307DS00 0.0-1.0 Soil X X X X X X0307DS05 4.0-5.0 Soil X X X X X X X0307DS06 5.0-6.4 Soil XQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 1 of 34/22/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 3 - NORTH ASH SETTLING BASINSample Sample Sample Sample ParametersLocation Identification Depth (ft bgs) Matrix VOCs1 SVOCs2 Metals3 Explosives4 Pesticides/PCBs5 Cyanide6 TOC7 TDS/TSS8 Geotech9 Comments0307DS08 6.5-8.2 Soil X X X X X X0307DW08 0.8-8.2 Groundwater X X X X X X X03SB08 0308DS00 0.0-1.0 Soil X X X X X X MS/MSD0308DS04 2.0-4.0 Soil X X X X X X X0308DS06 4.8-6.0 Soil X0308DS07 6.0-6.8 Soil X X X X X X0308DW07 4.0-6.8 Groundwater X X Limited Recovery03SB09 0309DS00 0.0-1.0 Soil X X X X X X0309DS10 0.0-1.0 Soil X X X X X X Duplicate (0309DS00)0309DS04 2.0-3.6 Soil X X X X X X X0309DW04 2.0-3.6 Groundwater X X X X Limited Recovery03SB10 0310DS00 0.0-1.0 Soil X X X X X X0310DS04 3.0-4.0 Soil X0310DS05 4.0-5.0 Soil X X X X X X0310DW05 1.0-5.0 Groundwater X X X X X X03SB11 0311DS00 0.0-1.0 Soil X X X X X X0311DS06 5.0-6.1 Soil X0311DS08 6.0-8.0 Soil X X X X X X X0311DS11 9.0-10.8 Soil X X X X X X0311DW11 8.8-10.8 Groundwater03SB12 0312DS00 0.0-1.0 Soil X X X X X X0312DS12 10.5-11.7 Soil X0312DS14 12.0-14.0 Soil X X X X X X X0312DS17 15.5-17.0 Soil X X X X X X0312DW17 14.9-16.9 Groundwater X X X X X X03SW/SD19 0319SW00 - Surface Water X X X X X X0319SD00 0.0-0.2 Sediment X X X X X X03SW/SD20 0320SW00 - Surface Water X X X X X X0320SD00 0.0-0.2 Sediment X X X X X X03SW/SD21 0321SW00 - Surface Water X X X X X X0321SD00 0.0-0.2 Sediment X X X X X XQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 2 of 34/22/02TABLE 2-2SUMMARY OF PHASE II RFI SAMPLES FOR CHEMICAL ANALYSISSITE 3 - NORTH ASH SETTLING BASINSample Sample Sample Sample ParametersLocation Identification Depth (ft bgs) Matrix VOCs1 SVOCs2 Metals3 Explosives4 Pesticides/PCBs5 Cyanide6 TOC7 TDS/TSS8 Geotech9 Comments0371SW00 X X X X X XNotes: Abbreviations:Samples were collected in 2000.1 TCL Volatile Organic Compounds: Preparation Methods 5030 (aqueous/sediment) and 5035 (soil) / Analysis Method 8260B. bgs = below ground surface23 TAL Metals: Preparation Method 3010A (aqueous) and 3050B (soil) / Analysis Methods 6010B/7470A (mercury).4 Nitroaromatics/Nitramines were prepared and analyzed as identified in Method 8330. DW = Direct Push - Groundwater56 Cyanide was prepared and analyzed as identified in Method 335.2. SB = Soil Boring7 Total Organic Carbon (TOC) was prepared and analyzed as identified in Method 415.1. SD = Sediment8 Total Dissolved Solids/Total Suspended Solids (TDS/TSS) were prepared and analyzed as identified in Methods 160.1/160.2. SW = Surface Water9 Geotechnical ParametersGeotechnical analytical parameters varied from sample to sample, dependingon depth, soil type, etc. Refer to Appendix F for a complete summary of allgeotechnical analyses.TCL Semivolatile Organic Compounds: Preparation Methods 3520C (aqueous) and 3550B (soil/sediment) / Analysis Method 8270C.Pesticides/PCBs: Preparation Methods 3520C (aqueous) and 3550B (soil/sediment) / Analysis Methods 8081A (Pesticides) and 8082 (PCBs).btoc = below top of casingDS = Direct Push-SoilDuplicate = Quality Control Duplicate (original sample identification inparentheses)MS/MSD = Matrix Spike/ Matrix Spike Duplicateft = feetSurface soil samples collected (from 0.0 to 2.0 ft bgs) during the Phase II RFIuse 00 for the depth indicator portion of the Sample Identification.Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 3 of 34/22/02TABLE 2-3SUMMARY OF FIELD SCREENING FOR ORGANIC VAPORS IN SOIL SAMPLESSITE 3 - NORTH ASH SETTLING BASINBoring Number Sample Depth (ft bgs) Concentration (ppm)103SB01 0.5-1.0 0.44.0-5.3 1.96.0-7.2 1.203SB02 0.5-1.0 1.69.0-10.8 18.214.0-15.5 NA03SB03 0.5-1.0 10.6-7.0 0.803SB04 0.0-0.5 NA3.0-4.0 NA03SB05 0.5-1.0 6.79.0-11.0 2.313.0-14.2 1.403SB06 0.5-1.0 1.31.0-2.0 NA3.0-4.1 NA03SB07 0.5-1.0 14.0-5.0 3.56.5-8.2 003SB08 0.5-1.0 0.32.0-4.0 1.76.0-6.8 0.303SB09 0.5-1.0 1.72.0-3.6 1.103SB10 0.5-1.0 1.54.0-5.0 0.903SB11 0.5-1.0 1.06.0-8.0 3.29.0-10.8 6.503SB12 0.5-1.0 NA12.0-14.0 NA15.5-17.0 NA03SD19 0.0-0.2 203SD20 0.0-0.2 203SD21 0.0-6.0 2Notes:1 Measured response above background using a photoionization detector (PID)2 Headspace not taken - sample collected beneath water.All field screening results are for samples collected during the Phase II RFI (2000). Samplescollected during the Phase I RI (1996) were not field screened.bgs = Below Ground Surfaceft = FeetNA = Not Available Due to Insufficient Sample RecoveryND = Not Detectedppm = Part Per MillionSB = Soil BoringSS = Shallow Soil SampleQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 1 of 1 4/22/02Physical Investigation ResultsSECTIONTHREE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 3-13.1 TOPOGRAPHY AND SURFACE FEATURESThe surface features at the site are shown on Figure 1-2. The North Ash Settling Basin issituated in the Upland area characterized by karst topography associated with shallow limestonebedrock. The basin was built in an incised stream channel that is part of the Fourteen-MileCreek drainage basin. The ground surface surrounding the basin rises up to 15 feet above thesurface of the basin.The basin is covered with marshy grasses and weeds, and with scattered trees on the northeastend of the basin. During the Phase I RI field sampling event and part of the Phase II RFI fieldsampling event, the surface soils at the southwest end of the basin were saturated and thenortheast end of the basin contained standing water to an approximate depth of 2.5 feet.A stream flows into the southern end of the basin and exits at the northern end throughstandpipes that control the water level (ASI 1994). The receiving stream flows north from thebasin and discharges into Lick Creek. Lick Creek discharges into Fourteen-Mile Creek, whichultimately discharges into the Ohio River.A review of a historical 1937 United States Geological Survey (USGS) topographic quadranglemap (USGS 1937a) shows that the North Ash Settling Basin was constructed within an existingdrainage. Based on a comparison between the 1937 map and a 1950 revised USGS topographicmap (USGS 1937b), it appears that the dam at the north end of the pond was constructed duringthe facility’s development.3.2 LOCAL SURFICIAL GEOLOGYThe local surficial geology of this site has been interpreted based on the results of an electricalresistivity survey, 12 soil borings, 21 sediment samples, and the geotechnical analysis of ten soilsamples. Elevations in feet above Mean Sea Level (MSL) in Figure 3-1 are based on the NorthAmerican Vertical Datum of 1988.As part of the electrical resistivity survey completed during the Phase II RFI, three transects werepositioned across the pond basin as shown on Figure 2-1. The results of the survey are presentedin Figures 3-1, 3-2, 3-3, and 3-4. Simplified borings logs are presented in Figure 3-5. Thegeneral stratigraphy is depicted in two geologic cross sections shown in Figures 3-6 and 3-7.These sections were generated from the boring logs using RockWorks99â geologic mappingsoftware.The electrical resistivity of subsurface materials can be affected by a number of differentphysical characteristics. Physical characteristics that act to reduce electrical resistivity includeincreasing water content, increasing salinity of groundwater, increasing clay content, anddecreasing grain size. Additionally, the presence of water-filled voids such as fractures or porespaces and other primary or secondary porosity features lower electrical resistivity.Physical Investigation ResultsSECTIONTHREE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 3-2Conversely, an absence or decrease in water content, a decrease in void space, porosity, orfracturing and an increasing degree of compaction or lithification can act to increase theelectrical resistivity. Typical ranges of electrical resistivities of various materials are as follows:Materials Resistivity(Ohm-Meters)Wet to moist clayey soil and wet clay 1s to 10swet to moist silty clay soil and silty clay Low 10sWet to moist silty and sandy soils 10s to 1000sWell-fractured to slightly fractured rock with moist,soil-filled cracks100sSand and gravel with layers of silt Low 1000sSlightly fractured rock with dry, soil-filled cracks Low 1000sCoarse, dry sand and gravel deposits High 1000sMassively bedded rock High 1000sNote: Adapted from H.R. Burger, 1992, Exploration Geophysics of the Shallow SubsurfaceThe results of Electrical Resistivity Transects #2 and #3 (Figures 3-3 and 3-4, respectively) showthe meandering of the former incised stream channel. In Figure 3-4, the former stream channel isvisible to the northwest of 03SB07, near the edge of the basin, whereas in Figure 3-3 the streamchannel appears to be located near the center of the basin.The surficial geology interpreted from the soil borings typically consisted of a thin topsoil layerfollowed primarily by process waste materials and colluvium overlying residual clay soil orlimestone bedrock (Figures 3-5, 3-6, and 3-7). The process waste materials consisted of ash andwere thicker at the northeastern corner of the pond, near the dam, due to the slope of the bedrocksurface and the incised stream channel (Figure 3-7). The bedrock surface within the basingenerally sloped from southwest to northeast as shown in Figure 3-7. The lowest point of thebedrock surface coincided with the incised stream channel on the eastern end of the basin (Figure3-3). All borings encountered refusal at depths ranging from approximately 3 to more than 15feet bgs, suggesting that bedrock was encountered. The deepest boring completed was 03SB02at 15.5 feet bgs.A thin layer of topsoil was identified at eight of the twelve borings. The topsoil layer wastypically one to two feet thick and contained numerous roots from the grass that covers much ofthe basin. This layer likely formed after the basin was no longer used as an ash settling basin.The thickness of ash deposits as measured during drilling were deepest toward the north-centralpart of the basin, as seen in borings 03SB02 and 03SB12. Measured ash thickness ranged fromless than one foot to approximately 12.5 feet. Thicker ash deposits my exist closer to the damfrom 03SB12, but this area was inaccessible due to standing water.Colluvial deposits identified at the site primarily consisted of silty clays and ranged from a fewto about nine feet thick. They likely represent slope wash from the sides of the basin. ColluvialPhysical Investigation ResultsSECTIONTHREE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 3-3soils were generally encountered below identified ash deposits and above residuum, althoughrefusal occurred directly beneath colluvial soils in four borings (03SB02, 03SB06, 03SB08, and03SB10).Residuum was identified in eight of the twelve borings and was typically only about two feet orless in thickness.In summary, the materials encountered were typically described as follows:· Topsoil - soft to stiff, moist, red-brown to brown to olive gray, low plastic silty clay(USCS Symbol CL)· Ash - loose, dry to wet, brown to gray to black, soft clayey silt to silty sand (USCSSymbol ML to SM)· Colluvium - soft to stiff, moist, light brown to brown, low plastic clay to silty clay(USCS Symbol CL)· Residuum - stiff to hard, moist, reddish-brown to gray grading to brown, low tomedium plastic clay to silty clay with limestone and chert fragments (USCS SymbolCL)3.3 SHALLOW HYDROGEOLOGYGroundwater was encountered at approximate depths ranging from 0.3 to 0.5 feet bgs insediment samples 03SD14 through 03SD18 during the Phase I RI (January 1996) and in all 12 ofthe borings completed during the Phase II RFI (Fall 2000) at depths ranging from 0.1 to 4.0 feetbgs. This water is likely connected hydraulically to standing water in the basin.Distance(Feet)Interpreted Bedrock SurfaceNORTHEAST SOUTHWEST0 160 320 480 540Boring03SB05Refusal = 14.2 ft BGSRelativeElevation(Feet)0102030405060708090100110RelativeElevation(Feet)0102030405060708090100110SITE 3-NORTH ASH SETTLING BASINTRANSECT 1, ARRAY 1INDIANA ARMY AMMUNITION PLANTDRN. BY: TJKCHKD. BY: JJSDATE: 03/26/01REVISIONS: 0PROJECT NO.45-FL99010D.00FIG. NO.3-1Distance(Feet)Interpreted Bedrock SurfaceNORTHEAST SOUTHWEST0 80 160 240 320 400 470RelativeElevation(Feet)0102030405060708090100110RelativeElevation(Feet)0102030405060708090100110SITE 3 - NORTH ASH SETTLING BASINTRANSECT 1, ARRAY 2INDIANA ARMY AMMUNITION PLANTDRN. BY: TJKCHKD. BY: JJSDATE: 03/26/01REVISIONS: 0PROJECT NO.45-FL99010D.00FIG. NO.3-2Distance(Feet)Interpreted Bedrock SurfaceSOUTHEAST NORTHWEST040 80 120 160 200 240 270Boring03SB01Refusal = 7.2 ft BGSBoring03SB02Refusal = 15.5 ft BSGSITE 3 - NORTH ASH SETTLING BASINTRANSECT 2INDIANA ARMY AMMUNITION PLANTDRN. BY: TJKCHKD. BY: JJSDATE: 03/26/01REVISIONS: 0PROJECT NO.45-FL99010D.00FIG. NO.3-3RelativeElevation(Feet)30405060708090100110120RelativeElevation(Feet)30405060708090100110120Distance(Feet)Interpreted Bedrock SurfaceSOUTHEAST NORTHWEST080 160320240Boring03SB07Refusal = 8.2 ft BGSBoring03SB06Refusal = 4.1 ft BGSSITE 3 - NORTH ASH SETTLING BASINTRANSECT 3INDIANA ARMY AMMUNITION PLANTDRN. BY: TJKCHKD. BY: JJSDATE: 03/26/01REVISIONS: 0PROJECT NO.45-FL99010D.00FIG. NO.3-4RelativeElevation(Feet)30405060708090100110120RelativeElevation(Feet)30405060708090100110120Data Quality Review and ValidationSECTIONFOUR North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 4-14.1 PHASE I RIThe results for selenium and lead for sample 03SD18, which underwent TCLP extraction prior toanalysis, were rejected due to outlying QC measurements. Reporting limits for various sampleswere elevated due to soil moisture content that ranged from 15 percent to 47 percent. See thePhase I RI report, for a more detailed discussion of data review issues.4.2 PHASE II RFIAll chemical data were reviewed following procedures identified in the INAPP Site WideQuality Assurance Project Plan (URS 2000). Endrin aldehyde result for sample 03-08-DS-00was qualified rejected (R) based on quality control (QC) parameters outside evaluation criteria.Data for select samples collected at the North Ash Settling Basin were qualified estimated (J/UJ)based on internal standard, surrogate, LCS and/or field duplicate data outside evaluation criteria.Additionally, acetone, methylene chloride and bis(2-ethylhexyl)phthalate data for many sampleswere qualified nondetect (U) based on the presence of the compounds in the trip blank orlaboratory method blank samples or based on professional judgement (common laboratorycontaminants). Acceptable levels of accuracy and precision were achieved for the data. Acomplete summary of the data reviews and validations is presented in Appendix A.The analytical data for samples collected at the North Ash Settling Basin was determined to beacceptable (including estimated data) for the intended use with the exception of select endrinaldehyde data qualified rejected (R).Chemical Investigation ResultsSECTIONFIVE North Ash Settling Basin, Site 3Q:\4599\fl010d00\Site 3\Final\Sections 1-10\Site 3 Text_Rev1.doc\4-Apr-02 /OMA 5-1All samples collected from the North Ash Settling Basin were analyzed for Target CompoundList (TCL) VOCs, TCL semivolatile organic compounds (SVOCs), nitroaromatics/nitramines,and Target Analyte List (TAL) metals and cyanide. Samples collected during the Phase I RIwere additionally analyzed for nitrate/nitrite. Samples collected during the Phase II RFI andsome samples collected during the Phase I RI were additionally analyzed forpesticides/polychlorinated biphenyls (PCBs) and cyanide. Additionally, two groundwatersamples (03SB01 and 03SB07) collected during the Phase II RFI were analyzed for totalsuspended solids (TSS)/total dissolved solids (TDS) and one soil sample from each boring,except 03SB10, was analyzed for Total Organic Carbon (TOC). Field duplicate samplescollected from this site are identified below. Analytical results for field duplicate samples arepresented in Appendix H.Associated Sample Field Duplicate0304SD00 0328SD000301DS00 0301DS200305DS00 0305DS180306DS00 0306DS100309DS00 0309DS100304SW00 0320SW000301DW07 0301DW200371SW00 0321SW00Summaries of the chemical investigation results can be found as follows:· Surface and subsurface soil, sediment, surface water, and groundwater samplescollected from this site and analyses completed for each sample are summarized inTables 2-1 and 2-2.· TCLP analytical results are summarized in Table 5-1.· Chemicals detected, maximum concentration, and frequency of detects for soil andsediment samples collected from the North Ash Settling Basin are summarized inTable 5-2.· Chemicals detected, maximum concentration, and frequency of detects for surfacewater and groundwater samples collected from the North Ash Settling Basin aresummarized in Table 5-3.· Appendix H contains all analytical results.TABLE 5-1COMPARISON OF CHEMICALS DETECTED IN TCLP1 SAMPLE COLLECTEDSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0319SD05LAB SAMPLE NUMBER B093-01COLLECT DATE 2/20/96Result Reporting Limit Data Qualifier TCLP Regulatory Limit 2VOLATILE ORGANICS (μg/L) < 10 U N/A1,1,1-Trichloroethane < 10 U N/A1,1,2,2-Tetrachloroethane < 10 U N/A1,1,2-Trichloroethane < 10 U N/A1,1-Dichloroethane < 10 U N/A1,1-Dichloroethene < 10 U 7001,2-Dichloroethane < 10 U 5001,2-Dichloroethene (Total) < 10 U N/A1,2-Dichloropropane < 10 U N/A2-Butanone < 10 U 200,0002-Hexanone < 10 U N/A4-Methyl-2-pentanone < 10 U N/AAcetone < 10 U N/ABenzene < 10 U 500Bromodichloromethane < 10 U N/ABromoform < 10 U N/ABromomethane < 10 U N/ACarbon Disulfide 0.7 J N/ACarbon Tetrachloride < 10 U 500Chlorobenzene < 10 U 100,000Chloroethane < 10 U N/AChloroform < 10 U 6,000Chloromethane < 10 U N/Acis-1,3-Dichloropropene < 10 U N/ADibromochloromethane < 10 U N/AEthylbenzene < 10 U N/AMethylene Chloride < 10 U N/AStyrene < 10 U N/ATetrachloroethene < 10 U 700Toluene < 10 U N/Atrans-1,3-Dichloropropene < 10 U N/ATrichloroethene < 10 U 500Vinyl chloride < 10 U 200Xylenes (Total) < 11 U N/ASEMIVOLATILE ORGANICS (μg/L)1,2,4-Trichlorobenzene < 10 U N/A1,2-Dichlorobenzene < 10 U N/A1,3-Dichlorobenzene < 10 U N/A1,4-Dichlorobenzene < 10 U 7,5002,2-oxybis(1-Chloropropane) < 10 U N/A2,4,5-Trichlorophenol < 25 U 400,0002,4,6-Tricholorphenol < 10 U 2,0002,4-Dichlorophenol < 10 U N/A2,4-Dimethylphenol < 10 U N/A2,4-Dinitrophenol < 25 U N/A2,4-Dinitrotoluene < 10 U 1302,6-Dinitrotoluene < 10 U N/A2-Chloronaphthalene < 10 U N/A2-Chlorophenol < 10 U N/A2-Methylnaphthalene < 10 U N/A2-Methylphenol < 10 U 200,0002-Nitroaniline < 25 U N/A2-Nitrophenol < 10 U N/A3,3-Dichlorobenzidine < 10 U N/AQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 1 of 34/22/02TABLE 5-1COMPARISON OF CHEMICALS DETECTED IN TCLP1 SAMPLE COLLECTEDSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0319SD05LAB SAMPLE NUMBER B093-01COLLECT DATE 2/20/96Result Reporting Limit Data Qualifier TCLP Regulatory Limit 2SEMIVOLATILE ORGANICS (μg/L) (Contd)3-Nitroaniline < 25 U N/A4,6-Dinitro-2-methylphenol < 25 U N/A4-Bromophenyl-phenylether < 10 U N/A4-Chloro-3-methylphenol < 10 U N/A4-Chloroaniline < 10 U N/A4-Chlorophenyl-phenylether < 10 U N/A4-Methylphenol < 10 U 200,0004-Nitroaniline < 25 U N/A4-Nitrophenol < 25 U N/AAcenaphthene < 10 U N/AAcenaphthylene < 10 U N/AAnthracene < 10 U N/ABenzo(a)anthracene < 10 U N/ABenzo(a)pyrene < 10 U N/ABenzo(b)fluoranthene < 10 U N/ABenzo(g,h,i)perylene < 10 U N/ABenzo(k)fluoranthene < 10 U N/Abis(2-Chloroethoxy)methane < 10 U N/Abis(2-Chloroethyl)ether < 10 U N/Abis(2-Ethylhexyl) phthalate < 10 U N/AButyl benzyl phthalate < 10 U N/ACarbazole < 10 U N/AChrysene < 10 U N/ADi-n-butyl phthalate < 10 U N/ADi-n-octyl phthalate < 10 U N/ADibenz(a,h)anthracene < 10 U N/ADibenzofuran < 10 U N/ADiethyl phthalate 1 J N/ADimethyl phthalate < 10 U N/AFluoranthene < 10 U N/AFluorene < 10 U N/AHexachlorobenzene < 10 U 130Hexachlorobutadiene < 10 U 500Hexachlorocyclopentadiene < 10 U N/AHexachloroethane < 10 U 3,000Indeno(1,2,3-cd)pyrene < 10 U N/AIsophorone < 10 U N/AN-Nitroso-di-n-propylamine < 10 U N/AN-nitrosodiphenylamine < 10 U N/ANaphthalene 0.8 J N/ANitrobenzene < 10 U 2,000Pentachlorophenol < 25 U 100,000Phenanthrene < 10 U N/APhenol < 10 U N/APyrene < 10 U 5,000PESTICIDES/PCB (μg/L)4,4-DDD < 0.1 U N/A4,4-DDE < 0.1 U N/A4,4-DDT < 0.1 U N/AAldrin < 0.05 U N/Aalpha-BHC < 0.05 U N/Aalpha-Chlordane < 0.05 U N/AAroclor-1016 < 1 U N/AQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 2 of 34/22/02TABLE 5-1COMPARISON OF CHEMICALS DETECTED IN TCLP1 SAMPLE COLLECTEDSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0319SD05LAB SAMPLE NUMBER B093-01COLLECT DATE 2/20/96Result Reporting Limit Data Qualifier TCLP Regulatory Limit 2PESTICIDES/PCB (μg/L) (Contd)Aroclor-1221 < 2 U N/AAroclor-1232 < 1 U N/AAroclor-1242 < 1 U N/AAroclor-1248 < 1 U N/AAroclor-1254 < 1 U N/AAroclor-1260 < 1 U N/Abeta-BHC < 0.09 U N/Adelta-BHC < 0.05 U N/ADieldrin < 0.1 U N/AEndosulfan I < 0.1 U N/AEndosulfan II < 0.1 U N/AEndosulfan sulfate < 0.1 U N/AEndrin < 0.1 U 20Endrin aldehyde < 0.1 U N/AEndrin ketone < 0.1 U N/Agamma-BHC (Lindane) < 0.05 U 400gamma-Chlordane < 0.05 U 30Heptachlor < 0.05 U 8Heptachlor epoxide < 0.05 U 8Methoxychlor < 0.05 U 10,000Toxaphene < 5 U 500METALS (μg/L)Aluminum < 300 U N/AAntimony < 400 U N/AArsenic < 160 U 5,000Barium 1580 J 100,000Beryllium < 20 U N/ACadmium < 40 U 1,000Calcium 362000 N/AChromium < 100 U 5,000Cobalt < 100 U N/ACopper < 50 U N/AIron 6250 U N/ALead 104 J 5,000Magnesium 20000 N/AManganese 3820 U N/AMercury < 0.2 U 200Nickel < 200 U N/APotassium < 12000 U N/ASelenium R 1,000Silver < 80 U 5,000Sodium < 1270000 U N/AThallium < 140 U N/AVanadium < 60 U N/AZinc 217 N/A1 TCLP = Toxicity Characteristic Leaching Procedure2 TCLP Regulatory Limits published in 40 CFR Part 261 Appendix IIU = NondetectJ = Estimated ValueR = Rejected DataQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 3 of 34/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0301DS00 0301DS06 0301DS07 0301SD00 0302DS00DATE COLLECTED October 30, 2000 October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53 120 40 J < 44 U < 27 U < 14 U < 39 UAcetone 530 39 / 53 530 22 < 22 U < 54 U < 14 U 210 19 JBenzene 7.9 J 4 / 53 < 10 U < 11 U < 6.8 U < 14 U < 9.7 UCarbon disulfide 44 J 12 / 53 < 10 U < 11 U < 6.8 U < 14 U < 9.7 UEthylbenzene 0.52 J 2 / 53 < 10 U < 11 U < 6.8 U < 14 U < 9.7 Um/p-xylene 1.1 J 1 / 35 < 20 U < 22 U < 14 U < 19 UMethylene Chloride 6 J 2 / 53 < 20 U < 22 U < 14 U < 14 U < 19 UTetrachloroethylene 8.7 J 3 / 53 < 10 U < 11 U < 6.8 U < 14 U 6.8 9.7 JToluene 3.5 J 5 / 53 < 10 U < 11 U < 6.8 U < 14 U < 9.7 USEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 53 < 600 U < 610 U < 450 U < 460 U < 580 U2-Chloronaphthalene 19 J 1 / 53 < 600 U < 610 U < 450 U < 460 U < 580 U2-Methylnaphthalene 930 7 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UAcenaphthene 74 J 5 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UAcenaphthylene 7 J 1 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UAnthracene 590 J 10 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UBenzo(a)anthracene 1600 14 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UBenzo(a)pyrene 1700 16 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UBenzo(b)fluoranthene 2600 16 / 53 500 600 J < 610 U < 450 U < 460 U < 580 UBenzo(g,h,i)perylene 1100 4 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UBenzo(k)fluoranthene 890 11 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UButylbenzyl phthalate 520 J 6 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UCarbazole 36 J 5 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UChrysene 2200 18 / 53 350 600 J < 610 U < 450 U < 460 U < 580 UDi-n-butyl phthalate 14000 11 / 53 < 600 U 1400 610 < 450 U < 450 U < 580 UDibenz(a,h)anthracene 450 J 1 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UDibenzofuran 380 J 7 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UFluoranthene 3100 25 / 53 440 600 J 620 610 < 450 U < 460 U < 580 UFluorene 510 J 7 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UIndeno(1,2,3-c,d)pyrene 1100 6 / 53 210 600 J < 610 U < 450 U < 460 U < 580 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 1 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0301DS00 0301DS06 0301DS07 0301SD00 0302DS00DATE COLLECTED October 30, 2000 October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualN-Nitrosodiphenylamine 2400 12 / 53 < 600 U 1100 610 < 450 U < 460 U < 580 UNaphthalene 52 J 6 / 53 < 600 U < 610 U < 450 U < 460 U < 580 UPhenanthrene 3000 16 / 53 < 600 U 500 610 J < 450 U < 460 U < 580 UPyrene 2600 21 / 53 400 600 J 590 610 J < 450 U < 460 U < 580 UPESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 35 < 7.3 U < 7.4 U < 5.4 U < 7 U4,4-DDE 7.4 J 4 / 35 < 7.3 U 2.4 7.4 J < 5.4 U < 7 U4,4-DDT 21 J 13 / 35 3.6 7.3 J 5.7 7.4 J < 5.4 U 13 7Alpha-Benzenehexachloride 7.4 5 / 35 < 3.7 U < 3.7 U < 2.7 U 1.2 3.5 Jbeta-Hexachlorocyclohexane 28 J 13 / 35 10 7.3 < 7.4 U < 5.4 U 8.3 7delta-Hexachlorocyclohexane 2.9 J 1 / 35 < 3.7 U < 3.7 U < 2.7 U < 3.5 UDieldrin 6.5 J 2 / 35 < 7.3 U < 7.4 U < 5.4 U < 7 UEndosulfan I 6.4 J 4 / 35 4 3.7 < 3.7 U < 2.7 U < 3.5 UEndosulfan II 7.8 J 1 / 35 < 7.3 U < 7.4 U < 5.4 U < 7 UEndrin 5.1 J 7 / 35 1.9 7.3 J 5.1 7.4 J < 5.4 U 2 7 JEndrin aldehyde 8.9 11 / 34 4.9 7.3 J 8.9 7.4 < 5.4 U 3.2 7 JEndrin ketone 7 J 3 / 35 < 7.3 U < 7.4 U < 5.4 U < 7 Ugamma-Chlordane 7.2 J 4 / 35 < 3.7 U < 3.7 U < 2.7 U < 3.5 UHeptachlor 5.9 J 1 / 35 < 3.7 U < 3.7 U < 2.7 U < 3.5 UHeptachlor epoxide 17 J 6 / 35 1.4 3.7 J < 3.7 U < 2.7 U < 3.5 ULindane 15 4 / 35 < 3.7 U < 3.7 U < 2.7 U < 3.5 UMethoxychlor 66 J 7 / 35 < 37 U < 37 U < 27 U < 35 UNITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53 < 400 U < 400 U < 400 U < 556 U < 400 UMETALS (mg/kg)Aluminum 25900 53 / 53 9760 36.6 12100 36.9 25900 27.2 3850 15100 35.2Antimony 25.6 7 / 53 < 18.3 U < 18.5 U < 13.6 U < 11.1 U 8.27 17.6 JArsenic 142 53 / 53 13.3 1.83 15.3 1.85 14.4 1.36 8.2 16.7 1.76Barium 960 53 / 53 179 1.83 181 1.85 169 1.36 198 143 1.76Beryllium 4.24 50 / 53 1.2 1.83 J 2 1.85 1.28 1.36 J < 0.56 U 1.49 1.76 JQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 2 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0301DS00 0301DS06 0301DS07 0301SD00 0302DS00DATE COLLECTED October 30, 2000 October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualCadmium 7 22 / 53 < 0.916 U 1.18 0.923 < 0.681 U < 1.1 U 0.732 0.88 JCalcium 111000 53 / 53 6610 183 60000 185 4020 136 12100 6460 176Chromium 121 53 / 53 17.1 1.83 16.9 1.85 32.3 1.36 8.4 19.4 1.76Cobalt 59.7 52 / 53 16.7 3.66 12 3.69 11.6 2.72 8.7 J 9.94 3.52Copper 107 53 / 53 44.7 3.66 75.9 3.69 28 2.72 9.6 55.9 3.52Iron 123000 53 / 53 31700 36.6 37000 36.9 37900 27.2 12600 40200 35.2Lead 337 53 / 53 92.9 1.83 128 1.85 20.2 1.36 11.5 136 1.76Magnesium 28000 53 / 53 1380 183 5260 185 3070 136 2230 1360 176Manganese 22200 J 53 / 53 4990 1.83 990 1.85 700 1.36 8900 J 857 1.76 JMercury 1.1 46 / 53 0.715 0.183 0.227 0.185 0.064 0.136 J < 0.12 U 0.566 0.176Nickel 125 53 / 53 28.6 3.66 25.4 3.69 31.7 2.72 10.1 J 24.3 3.52Potassium 1460 50 / 53 491 916 J 828 923 J 1320 681 518 J 1030 880Selenium 3.33 32 / 53 1.18 1.83 J 2.43 1.85 < 1.36 U < 1.4 U 2.54 1.76Silver 1.19 J 5 / 53 < 1.83 U < 1.85 U < 1.36 U < 2.2 U < 1.76 USodium 381 J 47 / 53 123 183 J 199 185 106 136 J 167 J 77.6 176 JThallium 32 37 / 53 3 3.66 J 3.36 3.69 J 2.33 2.72 J < 2.9 U 3.41 3.52 JVanadium 128 53 / 53 23.3 1.83 35.6 1.85 47.5 1.36 9.2 J 36.3 1.76Zinc 299 53 / 53 177 3.66 287 3.69 116 2.72 50.4 225 3.52OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53 0.635 0.916 J < 0.923 U < 0.681 U < 0.34 U 0.308 0.88 JTotal Organic Carbon 89.4 12 / 12 73.4 18.5Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 3 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD ID 0301DS00 0301DS06 0301DS07 0301SD00 0302DS00DATE COLLECTED October 30, 2000 October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000Maximum Frequency Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 4 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530302DS11 0302DS16 0302SD00 0303DS00 0303DS07October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000 October 30, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 110 U < 24 U < 14 U < 38 U < 24 U< 53 U 85 13 J < 14 U < 21 U 96 127.9 27 J < 5.9 U < 14 U < 9.5 U < 6 U< 27 U 6 6.3 J < 14 U < 9.5 U < 6 U< 27 U < 5.9 U < 14 U < 9.5 U < 6 U< 53 U < 12 U < 19 U < 12 U< 53 U < 12 U < 14 U < 19 U < 12 U< 27 U < 5.9 U < 14 U 8.7 9.5 J < 6 U< 27 U < 5.9 U < 14 U 3.5 9.5 J < 6 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U 25 J < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U 22 J < 630 U < 420 U540 1000 J < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U 38 J < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 5 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530302DS11 0302DS16 0302SD00 0303DS00 0303DS07October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000 October 30, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U < 460 U < 630 U < 420 U< 1000 U < 430 U 31 J < 630 U < 420 U< 12 U < 5.3 U 8 7.7 < 5 U< 12 U < 5.3 U < 7.7 U < 5 U5.6 12 J < 5.3 U 2.7 7.7 J < 5 U< 6.2 U < 2.6 U < 3.8 U < 2.5 U< 12 U < 5.3 U 7.7 7.7 < 5 U< 6.2 U < 2.6 U < 3.8 U < 2.5 U< 12 U < 5.3 U < 7.7 U < 5 U< 6.2 U < 2.6 U 6 3.8 < 2.5 U< 12 U < 5.3 U < 7.7 U < 5 U< 12 U < 5.3 U < 7.7 U < 5 U< 12 U < 5.3 U 4.7 7.7 J < 5 U< 12 U < 5.3 U < 7.7 U < 5 U< 6.2 U < 2.6 U < 3.8 U < 2.5 U< 6.2 U < 2.6 U < 3.8 U < 2.5 U< 6.2 U < 2.6 U 9.6 3.8 < 2.5 U< 6.2 U < 2.6 U < 3.8 U < 2.5 U< 62 U < 26 U < 38 U < 25 U180 400 J < 400 U < 554 U < 400 U < 400 U15100 62.5 16600 26.4 14800 18500 38.3 12900 25.2< 31.3 U 8.41 13.2 J < 11.1 U < 19.2 U 6.71 12.6 J10.3 3.12 38 1.32 25 22.3 1.92 22.5 1.26208 3.12 623 1.32 317 202 1.92 255 1.262.7 3.12 J 3.45 1.32 1.8 1.85 1.92 J 2.46 1.26Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 6 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0302DS11 0302DS16 0302SD00 0303DS00 0303DS07October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000 October 30, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual1.21 1.56 J < 0.659 U < 1.1 U 1.28 0.958 < 0.629 U111000 312 5880 132 41400 20000 192 2680 12619.1 3.12 62 1.32 44.4 21.1 1.92 28.7 1.2612.8 6.25 43.2 2.64 21.5 16.2 3.83 59.7 2.52107 6.25 49.1 2.64 20 81.7 3.83 38.4 2.5228500 62.5 73700 26.4 46900 59000 38.3 50800 25.2337 3.12 41.8 1.32 36.9 110 1.92 73.2 1.2628000 312 1640 132 2490 2710 192 718 126834 3.12 5380 1.32 3380 J 2720 1.92 3930 1.260.162 0.313 J 0.047 0.132 J < 0.12 U 0.497 0.192 0.046 0.126 J45.1 6.25 72.2 2.64 37.4 34.8 3.83 45.1 2.52876 1560 J 1020 659 1310 J 1040 958 625 629 J1.63 3.12 J 0.958 1.32 J < 1.4 U 1.65 1.92 J 0.533 1.26 J< 3.12 U < 1.32 U < 2.2 U < 1.92 U < 1.26 U228 312 J 85.6 132 J 330 J 142 192 J 55.4 126 J2.08 6.25 J 3.45 2.64 < 7.2 U 4.15 3.83 2.86 2.5234.2 3.12 92.2 1.32 65.4 46.4 1.92 57.7 1.26272 6.25 151 2.64 103 295 3.83 93 2.52< 1.56 U < 0.659 U < 0.34 U 0.595 0.958 J 0.175 0.629 J89.4 31.3 52.5 6.29Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 7 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.0302DS11 0302DS16 0302SD00 0303DS00 0303DS07October 30, 2000 October 30, 2000 January 17, 1996 October 30, 2000 October 30, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 8 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530303SD00 0304DS00 0304DS03 0304SD00 0305DS00January 17, 1996 November 2, 2000 November 2, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 28 U 27 58 J 5.3 24 J < 16 U < 33 U< 28 U 290 29 27 12 < 16 U 36 17< 28 U < 14 U 0.75 6.1 J < 16 U < 8.3 U< 28 U < 14 U 2.8 6.1 J < 16 U < 8.3 U< 28 U < 14 U 0.52 6.1 J < 16 U < 8.3 U< 29 U 1.1 12 J < 17 U< 28 U < 29 U < 12 U < 16 U < 17 U< 28 U < 14 U < 6.1 U < 16 U < 8.3 U< 28 U < 14 U 2.4 6.1 J < 16 U < 8.3 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U 49 J < 550 U< 920 U < 800 U < 440 U 36 J < 550 U< 920 U 810 800 < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U 94 J < 550 U520 J < 800 U < 440 U 85 J < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U 58 J < 550 U14000 < 800 U < 440 U 8800 360 550 J< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U 510 800 J < 440 U 130 J 320 550 J< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 9 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530303SD00 0304DS00 0304DS03 0304SD00 0305DS00January 17, 1996 November 2, 2000 November 2, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U < 540 U < 550 U< 920 U < 800 U < 440 U 72 J < 550 U< 920 U 560 800 J < 440 U 93 J < 550 U< 9.7 U < 5.4 U 34 6.7 J< 9.7 U < 5.4 U 2.2 6.7 J< 9.7 U < 5.4 U 2 6.7 J< 4.8 U < 2.7 U 3 3.3 J9.5 9.7 J < 5.4 U 25 6.7< 4.8 U < 2.7 U < 3.3 U< 9.7 U < 5.4 U 3.2 6.7 J< 4.8 U < 2.7 U < 3.3 U< 9.7 U < 5.4 U 7.8 6.7 J< 9.7 U < 5.4 U < 6.7 U< 9.7 U < 5.4 U 4.5 6.7 J< 9.7 U < 5.4 U 7 6.7 J< 4.8 U < 2.7 U < 3.3 U< 4.8 U < 2.7 U < 3.3 U< 4.8 U < 2.7 U < 3.3 U< 4.8 U < 2.7 U < 3.3 U< 48 U < 27 U < 33 U< 1100 U < 400 U < 400 U < 661 U < 400 U7020 10800 48.3 16700 26.8 13500 9740 33.3< 22 U < 24.2 U < 13.4 U < 13.2 U < 16.6 U142 12.3 2.42 12.9 1.34 17.8 14.5 1.66858 183 2.42 191 1.34 325 163 1.66< 1.1 U 0.963 2.42 J 1.17 1.34 J 1.4 J 1.31 1.66 JQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 10 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0303SD00 0304DS00 0304DS03 0304SD00 0305DS00January 17, 1996 November 2, 2000 November 2, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 2.2 U < 1.21 U 0.418 0.669 J 1.9 0.364 0.832 J18800 14900 242 56100 134 17500 10500 16612.1 15.9 2.42 23.1 1.34 31.5 16.9 1.6627.4 J 14.1 4.83 9.77 2.68 26.4 10.2 3.337.9 J 28.3 4.83 21.4 2.68 32.6 44.8 3.33123000 30700 48.3 30000 26.8 38700 34600 33.315.3 71.2 2.42 26.4 1.34 56.8 108 1.664480 1930 242 4580 134 1970 1580 16612800 J 2600 2.42 1120 1.34 3850 J 1330 1.66< 0.23 U 0.464 0.242 0.051 0.134 J < 0.14 U 0.581 0.16619.7 J 23.6 4.83 33.4 2.68 27.3 19.7 3.33785 J 275 1210 J 818 669 1240 J 737 832 J< 2.8 U 1.58 2.42 J < 1.34 U < 1.7 U 1.52 1.66 J< 4.4 U < 2.42 U < 1.34 U < 2.6 U 1.06 1.66 J313 J 61 242 J 108 134 J 204 J 98.5 166 J< 19.9 U 3.07 4.83 J 1.46 2.68 J < 9.2 U 2.64 3.33 J12.9 J 24.5 2.42 38.6 1.34 49.5 32.1 1.6656.5 160 4.83 125 2.68 153 171 3.33< 0.68 U < 1.21 U < 0.669 U < 0.4 U 0.686 0.832 J45.9 24.2Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 11 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.0303SD00 0304DS00 0304DS03 0304SD00 0305DS00January 17, 1996 November 2, 2000 November 2, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 12 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530305DS11 0305DS14 0305DS18 0305SD00 0306DS00November 1, 2000 November 1, 2000 November 1, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual13 33 J < 24 U < 33 U 73 < 33 U52 16 45 12 < 38 U 310 220 17< 8.1 U < 6.1 U < 8.1 U < 31 U < 8.3 U20 8.1 4 6.1 J < 8.1 U < 31 U < 8.3 U< 8.1 U < 6.1 U < 8.1 U < 31 U < 8.3 U< 16 U < 12 U < 16 U < 17 U< 16 U < 12 U < 16 U < 31 U < 17 U< 8.1 U < 6.1 U < 8.1 U < 31 U < 8.3 U1.5 8.1 J < 6.1 U < 8.1 U < 31 U < 8.3 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U 92 J < 550 U< 540 U < 420 U < 540 U 69 J < 550 U< 540 U < 420 U 420 540 J < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U 170 J < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U 290 540 J 100 J < 550 U< 540 U < 420 U 380 540 J < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U470 540 J < 420 U 370 540 J 180 J 260 550 J< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 13 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530305DS11 0305DS14 0305DS18 0305SD00 0306DS00November 1, 2000 November 1, 2000 November 1, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U < 540 U < 1000 U < 550 U< 540 U < 420 U 270 540 J 110 J < 550 U500 540 J < 420 U 350 540 J 140 J < 550 U< 6.6 U < 5.1 U < 6.5 U < 6.6 U< 6.6 U < 5.1 U < 6.5 U < 6.6 U5.5 6.6 J < 5.1 U 17 6.5 J 6.6 6.6< 3.3 U < 2.5 U 5.4 3.3 J 7.4 3.3< 6.6 U < 5.1 U 15 6.5 3.8 6.6 J< 3.3 U < 2.5 U < 3.3 U 2.9 3.3 J< 6.6 U < 5.1 U 6.5 6.5 J < 6.6 U< 3.3 U < 2.5 U 6.4 3.3 J < 3.3 U< 6.6 U < 5.1 U < 6.5 U < 6.6 U< 6.6 U < 5.1 U < 6.5 U < 6.6 U< 6.6 U < 5.1 U 8.2 6.5 3.7 6.6 J< 6.6 U < 5.1 U < 6.5 U 4 6.6 J1.5 3.3 J < 2.5 U < 3.3 U 3.9 3.3< 3.3 U < 2.5 U < 3.3 U < 3.3 U< 3.3 U < 2.5 U 2.1 3.3 J 15 3.3< 3.3 U < 2.5 U 10 3.3 J 15 3.3< 33 U < 25 U 32 33 J 15 33 J< 400 U < 400 U < 400 U < 1270 U < 400 U9370 32.8 8630 25.4 9320 32.5 10300 11500 33.2< 16.4 U < 12.7 U < 16.3 U < 25.3 U < 16.6 U8.98 1.64 12.8 1.27 13.1 1.63 14.6 10.9 1.66189 1.64 347 1.27 155 1.63 151 120 1.661.08 1.64 J 1.72 1.27 1.27 1.63 J 1.3 J 1.45 1.66 JQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 14 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0305DS11 0305DS14 0305DS18 0305SD00 0306DS00November 1, 2000 November 1, 2000 November 1, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 0.821 U < 0.636 U 0.456 0.813 J < 2.5 U < 0.829 U39100 164 2030 127 12600 163 34600 4750 16616.9 1.64 28 1.27 14.3 1.63 21.2 18.8 1.6613.5 3.28 22.5 2.54 10 3.25 16.8 J 12.4 3.3225.4 3.28 23 2.54 42 3.25 36.8 38 3.3220600 32.8 34200 25.4 28400 32.5 34300 32500 33.223.2 1.64 27.9 1.27 104 1.63 79.1 67.6 1.6611600 164 1230 127 1570 163 6190 1140 1661710 1.64 3380 1.27 1350 1.63 5050 J 1390 1.66< 0.164 U 0.038 0.127 J 0.619 0.163 0.48 0.241 0.16618.5 3.28 42.2 2.54 19.3 3.25 26.4 22.5 3.321080 821 1170 636 675 813 J 1080 J 884 829< 1.64 U < 1.27 U 1.62 1.63 J < 3.2 U 0.752 1.66 J0.907 1.64 J < 1.27 U 1.19 1.63 J < 5.1 U 0.948 1.66 J128 164 J 81.8 127 J 102 163 J 381 J 107 166 J< 3.28 U 0.963 2.54 J 2.52 3.25 J < 6.2 U 1.06 3.32 J26.3 1.64 31 1.27 30.7 1.63 24.9 J 34.2 1.6668.1 3.28 67.7 2.54 166 3.25 209 127 3.32< 0.821 U < 0.636 U < 0.813 U < 0.77 U < 0.829 U46.3 8.21Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 15 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.0305DS11 0305DS14 0305DS18 0305SD00 0306DS00November 1, 2000 November 1, 2000 November 1, 2000 January 17, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 16 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530306DS02 0306DS04 0306SD00 0307DS00 0307DS05November 1, 2000 November 1, 2000 January 17, 1996 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual7.9 21 J < 29 U 26 34 J 43 59 J54 11 < 29 U 290 17 230 29 J< 5.3 U < 29 U < 8.4 U < 15 U< 5.3 U < 29 U < 8.4 U < 15 U< 5.3 U < 29 U < 8.4 U < 15 U< 11 U < 17 U < 29 U< 11 U < 29 U < 17 U < 29 U< 5.3 U < 29 U < 8.4 U < 15 U< 5.3 U < 29 U < 8.4 U < 15 U< 400 U < 940 U < 1200 U < 690 U< 400 U < 940 U < 1200 U < 690 U< 400 U < 940 U < 1200 U 930 690< 400 U < 940 U < 1200 U < 690 U< 400 U < 940 U < 1200 U < 690 U< 400 U < 940 U < 1200 U 590 690 J< 400 U 88 J < 1200 U 1600 690< 400 U 66 J < 1200 U 1700 690< 400 U < 940 U 780 1200 J 2600 690< 400 U < 940 U < 1200 U 1100 690< 400 U 160 J < 1200 U 890 690< 400 U < 940 U < 1200 U < 690 U< 400 U < 940 U < 1200 U < 690 U< 400 U 93 J < 1200 U 2200 690< 400 U < 940 U < 1200 U 1900 690< 400 U < 940 U < 1200 U 450 690 J< 400 U < 940 U < 1200 U 380 690 J< 400 U 160 J 680 1200 J 3100 690< 400 U < 940 U < 1200 U 510 690 J< 400 U < 940 U < 1200 U 1100 690Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 17 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530306DS02 0306DS04 0306SD00 0307DS00 0307DS05November 1, 2000 November 1, 2000 January 17, 1996 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 400 U < 940 U < 1200 U 2400 690< 400 U < 940 U < 1200 U < 690 U< 400 U 68 J < 1200 U 3000 690< 400 U 130 J < 1200 U 2600 690< 4.8 U < 35 U < 8.4 U< 4.8 U < 35 U 7.4 8.4 J< 4.8 U 21 35 J 9.1 8.4< 2.4 U < 18 U 2.1 4.2 J< 4.8 U 20 35 J 11 8.4< 2.4 U < 18 U < 4.2 U< 4.8 U < 35 U < 8.4 U< 2.4 U < 18 U < 4.2 U< 4.8 U < 35 U < 8.4 U< 4.8 U < 35 U 3.1 8.4 J< 4.8 U < 35 U 5.1 8.4 J< 4.8 U < 35 U 5.2 8.4 J< 2.4 U 7.2 18 J < 4.2 U< 2.4 U < 18 U < 4.2 U< 2.4 U 17 18 J < 4.2 U< 2.4 U < 18 U < 4.2 U< 24 U 59 180 J < 42 U< 400 U < 1160 U < 400 U < 400 U8200 24.1 13300 12200 35.1 11600 41.8< 12.1 U < 23.2 U < 17.5 U < 20.9 U9.79 1.21 19.3 15 1.75 13.4 2.09120 1.21 622 140 1.75 187 2.091.65 1.21 < 1.2 U 1.06 1.75 J 1.42 2.09 JQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 18 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0306DS02 0306DS04 0306SD00 0307DS00 0307DS05November 1, 2000 November 1, 2000 January 17, 1996 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 0.603 U < 2.3 U < 0.877 U 0.578 1.05 J2290 121 8520 10500 175 87900 20918.9 1.21 17.6 17.3 1.75 19 2.0915.9 2.41 14.1 J 13.4 3.51 9.84 4.1829 2.41 24.2 37.2 3.51 96.9 4.1833700 24.1 38400 31500 35.1 32300 41.822.6 1.21 54.8 96.7 1.75 154 2.09555 121 1650 J 2460 175 5810 2091420 1.21 22200 J 2480 1.75 914 2.090.043 0.121 J < 0.24 U 0.92 0.175 0.993 0.20936.6 2.41 26.3 23 3.51 20.1 4.18332 603 J 1210 J 897 877 693 1050 J< 1.21 U < 2.9 U 1.96 1.75 1.98 2.09 J< 1.21 U < 4.6 U < 1.75 U < 2.09 U73.5 121 J 357 J 77.9 175 J 188 209 J1.3 2.41 J < 11 U 1.18 3.51 J 1.37 4.18 J34.5 1.21 30.3 27 1.75 30.6 2.0950.5 2.41 139 168 3.51 229 4.18< 0.603 U < 0.71 U 0.302 0.877 J < 1.05 U32.1 6.47 8.8 21 JQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 19 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.0306DS02 0306DS04 0306SD00 0307DS00 0307DS05November 1, 2000 November 1, 2000 January 17, 1996 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 20 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530307DS08 0307SD00 0308DS00 0308DS04 0308DS07October 31, 2000 January 22, 1996 October 31, 2000 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual16 26 J < 12 U 16 22 J 11 24 J 20 25 J110 13 J 37 140 11 68 11 J 130 13< 6.1 U < 12 U < 5.5 U < 5.3 U < 6.3 U7.1 6.6 J < 12 U < 5.5 U < 5.3 U < 6.3 U< 6.1 U < 12 U < 5.5 U < 5.3 U < 6.3 U< 12 U < 11 U < 11 U < 13 U< 12 U 4 J < 11 U < 11 U < 13 U< 6.1 U < 12 U < 5.5 U < 5.3 U < 6.3 U< 6.1 U < 12 U < 5.5 U < 5.3 U < 6.3 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 100 J < 420 U < 410 U < 440 U< 430 U 310 J < 420 U < 410 U < 440 U< 430 U 260 J < 420 U < 410 U < 440 U< 430 U 480 < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 110 J < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 260 J < 420 U < 410 U < 440 U960 430 < 4500 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 780 220 420 J < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 110 J < 420 U < 410 U < 440 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 21 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530307DS08 0307SD00 0308DS00 0308DS04 0308DS07October 31, 2000 January 22, 1996 October 31, 2000 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual460 430 220 J < 420 U < 410 U < 440 U< 430 U < 410 U < 420 U < 410 U < 440 U< 430 U 410 < 420 U < 410 U < 440 U< 430 U 550 < 420 U < 410 U < 440 U< 5.2 U < 5 U < 5 U < 5.3 U< 5.2 U < 5 U < 5 U < 5.3 U< 5.2 U < 5 U < 5 U < 5.3 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 5.2 U < 5 U < 5 U < 5.3 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 5.2 U < 5 U < 5 U < 5.3 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 5.2 U < 5 U < 5 U < 5.3 U< 5.2 U 2.7 5 J < 5 U < 5.3 U< 5.2 U R < 5 U < 5.3 U< 5.2 U < 5 U < 5 U < 5.3 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 2.6 U < 2.5 U < 2.5 U < 2.6 U< 26 U 17 25 J < 25 U < 26 U< 400 U < 493 U < 400 U < 400 U < 400 U14600 26.2 8400 15300 25.2 13300 24.9 22000 26.4< 13.1 U < 9.9 U 5.88 12.6 J < 12.5 U < 13.2 U32.5 1.31 28.7 9.58 1.26 13 1.25 24.3 1.32306 1.31 342 85.4 1.26 75.8 1.25 140 1.322.68 1.31 2 0.771 1.26 J 0.753 1.25 J 1.55 1.32Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 22 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0307DS08 0307SD00 0308DS00 0308DS04 0308DS07October 31, 2000 January 22, 1996 October 31, 2000 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 0.655 U 1.1 J < 0.629 U < 0.623 U < 0.66 U13200 131 14300 5790 126 J 3460 125 3590 13252.2 1.31 42.2 16.4 1.26 19.1 1.25 27.9 1.3222.7 2.62 29.8 8.67 2.52 12.2 2.49 8.57 2.6436.2 2.62 31.4 22.2 2.52 19 2.49 27.6 2.6457800 26.2 71700 24800 25.2 24400 24.9 41900 26.450.5 1.31 57.1 34.3 1.26 21.4 1.25 17.5 1.321700 131 1450 1670 126 1220 125 2130 1322410 1.31 5410 J 1070 1.26 728 1.25 2080 1.320.137 0.131 0.16 0.056 0.126 J 0.041 0.125 J 0.079 0.132 J27.6 2.62 39.6 14.2 2.52 11.5 2.49 39.5 2.64792 655 445 J 1460 629 743 623 1320 6602.16 1.31 < 1.2 U 1.07 1.26 J 1.55 1.25 0.739 1.32 J< 1.31 U < 2 U < 1.26 U < 1.25 U < 1.32 U98 131 J 191 J 55.8 126 J 55.3 125 J 58.6 132 J0.816 2.62 J 11.4 < 2.52 U < 2.49 U < 2.64 U75.6 1.31 51.9 32.4 1.26 33.1 1.25 44.6 1.32128 2.62 174 109 2.52 47.1 2.49 146 2.64< 0.655 U < 0.3 U < 0.629 U < 0.623 U 0.222 0.66 J19.7 6.23Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 23 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyThe maximum detected concentration for each analyte areunderlined and appear in boldface font.This table combines data from Phase I RI (1995-1996) withdata from the Phase II RFI (2000-2001).Blank space for a set of analytes indicates that the sample wasnot analyzed for these parameters.Analyte frequency information does not include dilutions andreanalyses.Results in the table represent the highest reportedconcentration for each analyte.Frequency indicates the number of times a given analyte wasdetected in the samples.0307DS08 0307SD00 0308DS00 0308DS04 0308DS07October 31, 2000 January 22, 1996 October 31, 2000 October 31, 2000 October 31, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL QualQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 24 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyVOLATILE ORGANICCOMPOUNDS (μg/kg)2-Butanone 120 J 22 / 53Acetone 530 39 / 53Benzene 7.9 J 4 / 53Carbon disulfide 44 J 12 / 53Ethylbenzene 0.52 J 2 / 53m/p-xylene 1.1 J 1 / 35Methylene Chloride 6 J 2 / 53Tetrachloroethylene 8.7 J 3 / 53Toluene 3.5 J 5 / 53SEMIVOLATILE ORGANICCOMPOUNDS (μg/kg)2,4-Dinitrotoluene 44 J 1 / 532-Chloronaphthalene 19 J 1 / 532-Methylnaphthalene 930 7 / 53Acenaphthene 74 J 5 / 53Acenaphthylene 7 J 1 / 53Anthracene 590 J 10 / 53Benzo(a)anthracene 1600 14 / 53Benzo(a)pyrene 1700 16 / 53Benzo(b)fluoranthene 2600 16 / 53Benzo(g,h,i)perylene 1100 4 / 53Benzo(k)fluoranthene 890 11 / 53Butylbenzyl phthalate 520 J 6 / 53Carbazole 36 J 5 / 53Chrysene 2200 18 / 53Di-n-butyl phthalate 14000 11 / 53Dibenz(a,h)anthracene 450 J 1 / 53Dibenzofuran 380 J 7 / 53Fluoranthene 3100 25 / 53Fluorene 510 J 7 / 53Indeno(1,2,3-c,d)pyrene 1100 6 / 530308SD00 0309DS00 0309DS04 0309SD00 0310DS00January 22, 1996 October 31, 2000 October 31, 2000 January 22, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 13 U 32 38 J 5.6 21 J < 12 U 21 25 J20 190 19 J 58 10 66 150 12< 13 U < 9.4 U < 5.2 U < 12 U < 6.2 U< 13 U 44 9.4 J < 5.2 U < 12 U 1.7 6.2 J< 13 U < 9.4 U < 5.2 U < 12 U < 6.2 U< 19 U < 10 U < 12 U< 13 U < 19 U < 10 U < 12 U < 12 U< 13 U < 9.4 U < 5.2 U < 12 U < 6.2 U< 13 U < 9.4 U < 5.2 U < 12 U 1.1 6.2 J< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U100 J < 720 U < 400 U 55 J < 460 U220 J 340 720 J < 400 U 150 J < 460 U210 J 370 720 J < 400 U 150 J < 460 U370 J 550 720 J < 400 U 260 J < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U100 J < 720 U < 400 U 80 J < 460 U< 420 U < 720 U < 400 U 95 J < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U210 J 430 720 J < 400 U 170 J < 460 U< 420 U < 720 U < 400 U < 4700 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U580 590 720 J < 400 U 440 < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 UQ:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 25 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyN-Nitrosodiphenylamine 2400 12 / 53Naphthalene 52 J 6 / 53Phenanthrene 3000 16 / 53Pyrene 2600 21 / 53PESTICIDES(ORGANOCHLORINE) (μg/kg)4,4-DDD 34 J 2 / 354,4-DDE 7.4 J 4 / 354,4-DDT 21 J 13 / 35Alpha-Benzenehexachloride 7.4 5 / 35beta-Hexachlorocyclohexane 28 J 13 / 35delta-Hexachlorocyclohexane 2.9 J 1 / 35Dieldrin 6.5 J 2 / 35Endosulfan I 6.4 J 4 / 35Endosulfan II 7.8 J 1 / 35Endrin 5.1 J 7 / 35Endrin aldehyde 8.9 11 / 34Endrin ketone 7 J 3 / 35gamma-Chlordane 7.2 J 4 / 35Heptachlor 5.9 J 1 / 35Heptachlor epoxide 17 J 6 / 35Lindane 15 4 / 35Methoxychlor 66 J 7 / 35NITROAROMATICS /NITRAMINES (μg/kg)HMX 180 J 1 / 53METALS (mg/kg)Aluminum 25900 53 / 53Antimony 25.6 7 / 53Arsenic 142 53 / 53Barium 960 53 / 53Beryllium 4.24 50 / 530308SD00 0309DS00 0309DS04 0309SD00 0310DS00January 22, 1996 October 31, 2000 October 31, 2000 January 22, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 420 U < 720 U < 400 U < 410 U < 460 U< 420 U < 720 U < 400 U < 410 U < 460 U550 < 720 U < 400 U 350 J < 460 U390 J 530 720 J < 400 U 310 J < 460 U< 8.7 U < 4.9 U < 5.6 U< 8.7 U < 4.9 U < 5.6 U< 8.7 U < 4.9 U 5 5.6 J< 4.3 U < 2.5 U < 2.8 U20 8.7 J < 4.9 U 3.1 5.6 J< 4.3 U < 2.5 U < 2.8 U< 8.7 U < 4.9 U < 5.6 U< 4.3 U < 2.5 U 2.1 2.8 J< 8.7 U < 4.9 U < 5.6 U< 8.7 U < 4.9 U 2.5 5.6 J< 8.7 U < 4.9 U 3.1 5.6 J< 8.7 U < 4.9 U < 5.6 U< 4.3 U < 2.5 U 1.4 2.8 J< 4.3 U < 2.5 U < 2.8 U< 4.3 U < 2.5 U 5.8 2.8< 4.3 U < 2.5 U 2.2 2.8 J< 43 U < 25 U < 28 U< 508 U < 400 U < 400 U < 500 U < 400 U6340 12700 43.4 24500 24.5 6260 12200 28< 10.2 U < 21.7 U 10.6 12.3 J < 10 U < 14 U44.1 13.9 2.17 79.3 1.23 44.8 16.2 1.4107 137 2.17 960 1.23 89.2 154 1.41.5 1.03 2.17 J 4.24 1.23 1.2 J 1.46 1.4Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 26 of 44 4/22/02TABLE 5-2SUMMARY OF CHEMICALS DETECTED IN SOIL AND SEDIMENT SAMPLESSITE 3 - NORTH ASH SETTLING BASINFIELD IDDATE COLLECTEDMaximum FrequencyCadmium 7 22 / 53Calcium 111000 53 / 53Chromium 121 53 / 53Cobalt 59.7 52 / 53Copper 107 53 / 53Iron 123000 53 / 53Lead 337 53 / 53Magnesium 28000 53 / 53Manganese 22200 J 53 / 53Mercury 1.1 46 / 53Nickel 125 53 / 53Potassium 1460 50 / 53Selenium 3.33 32 / 53Silver 1.19 J 5 / 53Sodium 381 J 47 / 53Thallium 32 37 / 53Vanadium 128 53 / 53Zinc 299 53 / 53OTHER PARAMETERS (mg/kg)Cyanide 1.36 J 11 / 53Total Organic Carbon 89.4 12 / 12Notes:* = Sample Collected on Multiple DaysND = Not DetectedRL = Reporting LimitQual = QualifierJ = EstimatedR = RejectedUJ = Estimated NondetectU = Nondetectmg/kg = milligram per kilogramμg/kg = microgram per kilogramE = Value exceeds linear range.0308SD00 0309DS00 0309DS04 0309SD00 0310DS00January 22, 1996 October 31, 2000 October 31, 2000 January 22, 1996 November 1, 2000Result RL Qual Result RL Qual Result RL Qual Result RL Qual Result RL Qual< 1 U < 1.08 U 1.16 0.613 7 0.309 0.699 J27200 6830 217 3380 123 15900 6670 14068.9 17.2 2.17 69.1 1.23 32.3 61.5 1.422.9 10.5 4.34 43.5 2.45 44.6 32.3 2.823.3 26.2 4.34 63.9 2.45 26.4 39.5 2.890000 24000 43.4 115000 245 108000 39000 2844.1 34.8 2.17 47.5 1.23 69.9 56.3 1.43050 1940 217 1770 123 1360 1500 1402910 J 1120 2.17 J 8760 12.3 1110 J 3840 1.40.2 0.094 0.217 J 0.05 0.123 J 0.17 0.145 0.1435.6 11.6 4.34 125 2.45 46.1 30.8 2.8529 J 1180 1080 1070 613 < 300 U 761 699< 1.3 U 1.97 2.17 J 2.63 1.23 2.6 1.83 1.4< 2 U 0.945 2.17 J < 1.23 U < 2 U < 1.4 U200 J 96.3 217 J 54.4 123 J 281 J 75.7 140 J14.9 < 4.34 U 1.31 2.45 J 32 1.77 2.8 J78.3 30.3 2.17 128 1.23 30.8 41 1.4143 80.8 4.34 256 2.45 125 158 2.8< 0.31 U < 1.08 U < 0.613 U < 0.3 U 0.195 0.699 J19.2 6.13Q:\4599\fl010d00\Site 3\Draft\Sections 1-10\Site 3 Tables_Rev1 Page 27 of 44 4/22/02TABLE 5-2SUMMARY OF C
Origin:	2002-09-25
Source:	http://indianamemory.contentdm.oclc.org/cdm/ref/collection/p15078coll17/id/33753
Collection:	Clark County Collections
Rights:	http://rightsstatements.org/vocab/NoC-US/1.0/
Copyright:	Charlestown-Clark County Public Library provides access to these materials for educational and research purposes and makes no warranty with regard to their use for other purposes. The written permission of the copyright owners and/or holders of other rights such as publicity and/or privacy rights is required for distribution, reproduction, or other use of protected items beyond that allowed by fair use or other statutory exemptions. There may be content that is protected as works for hire copyright held by the party that commissioned the original work and/or under the copyright or neighboring-rights laws of other nations. Responsibility for making an independent legal assessment of an item and securing any necessary permissions ultimately rests with persons desiring to use the item.
Geography:	Charlestown, Clark County, Indiana 38.4357546,-85.6577676
Subjects:	Maps Indiana Ordnance Works (U.S.) Hoosier Ordnance Plant Indiana Arsenal Indiana Army Ammunition Plant Explosives Industry--Indiana Gunpowder, Smokeless Ordnance manufacture Black powder manufacture Facility One ICI Americas Inc Clark County (Ind.) Charlestown (Ind.) United States. Army Ordnance and Ordnance Stores INAAP

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